2021/11/27 更新

写真a

マツオカ シロウ
松岡 史郎
MATSUOKA Shiro
所属
教育研究院 自然科学系 地球・生物科学系列 教授
自然科学研究科 環境科学専攻 教授
理学部 理学科 教授
職名
教授
▶ researchmapのプロフィールを表示
外部リンク

学位

  • 博士(理学) ( 1998年2月   九州大学 )

研究分野

  • ナノテク・材料 / 分析化学

経歴(researchmap)

  • 新潟大学   理学部 理学科   教授

    2017年4月 - 現在

      詳細を見る

  • 新潟大学   自然科学研究科 環境科学専攻   教授

    2012年4月 - 現在

      詳細を見る

  • 新潟大学   自然科学研究科 環境科学専攻   教授

    2012年4月 - 現在

      詳細を見る

  • 新潟大学   理学部 自然環境科学科   教授

    2012年4月 - 2017年3月

      詳細を見る

  • 新潟大学   理学部 自然環境科学科   准教授

    2004年4月 - 2012年3月

      詳細を見る

  • 九州大学高等教育総合開発研究センター   助手

    2003年4月 - 2004年3月

      詳細を見る

  • 米国ユタ大学医学部麻酔科(VAメディカルセンター)   研究員

    2001年4月 - 2002年3月

      詳細を見る

  • 九州大学大学教育研究センター   助手

    1999年4月 - 2003年3月

      詳細を見る

  • 九州大学大学院理学研究科   助手

    1994年4月 - 1999年3月

      詳細を見る

  • 九州大学教養部化学教室   助手

    1989年4月 - 1994年3月

      詳細を見る

▶ 全件表示

経歴

  • 新潟大学   理学部 理学科   教授

    2017年4月 - 現在

  • 新潟大学   自然科学研究科 環境科学専攻   教授

    2012年4月 - 現在

  • 新潟大学   自然科学研究科 環境科学専攻   教授

    2012年4月 - 現在

  • 新潟大学   自然環境科学科   教授

    2012年4月 - 2017年3月

  • 新潟大学   自然環境科学科   准教授

    2004年4月 - 2012年3月

学歴

  • 九州大学   理学部   化学科

    - 1988年3月

      詳細を見る

    国名: 日本国

    researchmap

所属学協会

 

論文

  • 浄水過程における PAC(ポリ塩化アルミニウム)の 凝集に及ぼすイオン状シリカの影響 査読

    広城吉成, 森山 晃, 井辺弘貴, 重松 藍, 松岡史郎

    水道協会雑誌   87 ( 10 )   11 - 16   2018年10月

     詳細を見る

    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

    researchmap

  • Interaction of borate and phenylboronate with the cross-linked dextran gel matrix 査読

    Yoshinobu Miyazaki, Shiro Matsuoka, Kei Asada, Yuma Kawasaki, Kazuhisa Yoshimura

    Polyhedron   151   233 - 242   2018年9月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier Ltd  

    The interaction of borate and phenylboronate with dextran gels having different degrees of cross-linking was investigated to clarify the structures of the adsorbed boron species, binding sites of the gel matrix, and the adsorption properties. The main adsorbed species of the phenylboronate was the five-membered mono-chelate complex. In addition to this, the five-membered bis-chelate complex, and the five- and six-membered bis-chelate complex were also the main species for the borate. The boron adsorption was not produced by the glucopyranoside units that were the major constituents of the dextran gel, but by the gluconate residues and various forms of the glycerol residues, which had been generated during the cross-linking process of the dextran. The adsorption behavior was reproduced by the calculation taking the complexation of boron with the gel matrix and the Gibbs–Donnan relation into consideration.

    DOI: 10.1016/j.poly.2018.05.051

    Scopus

    researchmap

  • Coordination properties of aqueous vanadate complexes with nitrogen- and oxygen-containing multidentate ligands 査読

    Yoshinobu Miyazaki, Shiro Matsuoka, Takao Fujimori, Yoshitaka Kai, Kazuhisa Yoshimura

    POLYHEDRON   134   79 - 87   2017年9月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:PERGAMON-ELSEVIER SCIENCE LTD  

    The complexation properties of aqueous vanadate with diethanolamine (DEA) and iminodiacetate (IDA) derivatives were elucidated by NMR spectroscopy and DFT calculations. The coordination geometries of vanadium in 1:1 complexes of the DEA derivatives were confirmed to be trigonal-bipyramidal with a tridentate binding mode. The trigonal-bipyramidal complexes of N,N-bis(2-hydroxyethyl)glycinate (Bicine) and N-(2-hydroxyethyl)iminodiacetate (HIDA) binding through the nitrogen atom, hydroxyethyl and carboxymethyl groups, were also formed at lower and higher pHs, respectively. Vanadate binds with IDA through the nitrogen atom and one of two carboxymethyl groups to form a trigonal-bipyramidal complex, in addition to the trigonal-bipyramidal complex binding through the nitrogen atom and both of the carboxymethyl groups. The latter five-coordinate complex has an open space suitable for additional coordination at the apical position of the central vanadium, which is the same side of the hydrogen atom on the coordinating nitrogen. When an appropriate functional group, such as a carboxymethyl group, acetamido group or hydroxyethyl group, exists instead of the hydrogen atom on the nitrogen, these groups can coordinate to the central vanadium to form a highly stable octahedral complex with a tetradentate binding mode. These findings made it possible to provide an integrated and comprehensive interpretation about the complexation properties of the aqueous vanadate. (c) 2017 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.poly.2017.05.056

    Web of Science

    researchmap

  • Speciation of dissolved chromium and the mechanisms controlling its concentration in natural water 査読

    Sulistyo Saputro, Kazuhisa Yoshimura, Shiro Matsuoka, Ko Takehara, Narsito, Jun Aizawa, Yoshika Tennichi

    CHEMICAL GEOLOGY   364   33 - 41   2014年1月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE BV  

    The circulation of chromiumat naturally occurring concentration levels (i.e., 1 mu g dm(-3) or lower) was examined using solid-phase spectrophotometry and inductively coupled plasma-mass spectrophotometry (ICP-MS) to determine the Cr(VI) and Cr(Total) concentrations, respectively. Natural water and stream sediments were collected from areas with various types of geologic features, such as metamorphic rocks, volcanic rocks and limestone in Japan and Indonesia. Cr(VI) was predominant in weakly alkaline natural waters, and the Cr(III) concentrationwas less than 1 mu g dm(-3), whichwas considerably lower than that expected based on the solubility of Cr(OH)(3). The dissolution of chromium in natural water was described by the leaching of Cr(VI) from Cr(III)containing minerals under oxic conditions. The Cr(VI) concentration in a solution that was in contact with chromite, FeCr2O4, linearly increased with the reaction time. The results indicated that under oxic conditions at P-O2 = 0.21 atm, the leaching rate of Cr(VI) was pseudo zero-order at a fixed pH and was higher in alkaline than in acidic solutions. The removal of Cr from natural waters was due to the reduction of Cr(VI) to Cr(III) by organic matter, such as humic substances, as well as to the adsorption of Cr(III) onto suspended matter and river sediments. The reduction of Cr(VI) to Cr(III) followed the equation -d[Cr(VI)]/dt = [H+](a)[ Cr(VI)][DOC] with a = 0 at pH b 4 and a = -1 at pH N 4.5. The removal of Cr(III) by river sediments and/or suspended particulate matter was rapid and the adsorbability of Cr(III) was dependent on pH, which suggests that the active species were Cr(OH)(2)(+) and Cr(OH)(3). Schematic models of the circulation of dissolved chromium in natural water were proposed under acidic and alkaline conditions. (C) 2013 Elsevier B. V. All rights reserved.

    DOI: 10.1016/j.chemgeo.2013.11.024

    Web of Science

    researchmap

  • Mineralogical and geomicrobial examination of soil contamination by radioactive Cs due to 2011 Fukushima Daiichi Nuclear Power Plant accident 査読

    Junji Akai, Nao Nomura, Shin Matsushita, Hisaaki Kudo, Haruo Fukuhara, Shiro Matsuoka, Jinko Matsumoto

    PHYSICS AND CHEMISTRY OF THE EARTH   58-60   57 - 67   2013年

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:PERGAMON-ELSEVIER SCIENCE LTD  

    Soil contamination by radioactive Cs from Fukushima Daiichi Nuclear Power Plant accident was investigated. Absorption and desorption experiments of Cs were conducted for several phyllosillicates (kaolinite, sericite, montmorillonite, vermiculite, chrysotile and biotite), zeolite and solid organic matter (dead and green leaves). The results confirmed the characteristic sorption and desorption of Cs by these materials. The 2:1 type phyllosilicate, especially, vermiculite and montmorillonite absorbed Cs well. Heated vermiculite for agricultural use and weathered montmorillonite also adsorbed Cs. Leaves also absorbed Cs considerably but easily desorbed it. In summary, the relative capacity and strength of different materials for sorption of Cs followed the order: zeolite (clinoptilolite) > 2:1 type clay mineral > 1:1 type clay mineral > dead and green leaves. Culture experiments using bacteria of both naturally living on dead leaves in litate village, Fukushima Pref. and bacterial strains of Bacillus subtillis, Rhodococus erythropolis, Streptomyces aomiensis and Actinomycetospora chlora were carried out. Non-radioactive 1% Cs solution (CsCl) was added to the culture media. Two types of strong or considerable bacterial uptakes of Cs were found in bacterial cells. One is that Cs was contained mainly as globules inside bacteria and the other is that Cs was absorbed in the whole bacterial cells. The globules consisted mainly of Cs and P. Based on all these results, future diffusion and re-circulation behavior of Cs in the surface environment was discussed. (C) 2013 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.pce.2013.04.010

    Web of Science

    researchmap

  • Solid-phase spectrophotometry for on-site analysis of trace elements in natural water 査読

    Sarenqiqige, Sulistyo Saputro, Satsuki Kai, Makoto Satoda, Shiro Matsuoka, Kazuhisa Yoshimura

    Analytical Sciences   29 ( 6 )   677 - 680   2013年

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    A new, simple and sensitive solid-phase spectrometry (SPS) that is easily applicable to the on-site analysis of targeted chemical components in water at μg dm-3 or sub-μg dm-3 levels is proposed in this study. The main features of the SPS are the simplicity of operation, high sensitivity and applicability to real samples without the need for any pretreatment procedures. A portable spectrophotometer, consisting of an LED light source, a grating and a CCD, was used for the solid-phase light measurements. The universal applicability of the proposed system to on-site analysis was evaluated by determining phosphate, chromium(VI) and iron(II) in natural water. © 2013 The Japan Society for Analytical Chemistry.

    DOI: 10.2116/analsci.29.677

    Scopus

    researchmap

  • Development and Validation of a Sensitive and Fast Solid-phase Spectrophotometric Procedure for Phenol Determination in Pharmaceuticals 査読

    Jadranka Vukovic, Shiro Matsuoka, Kazuhisa Yoshimura, Renata Jurisic Grubesic, Dario Kremer, Natasa Santic

    ANALYTICAL SCIENCES   28 ( 4 )   397 - 402   2012年4月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:JAPAN SOC ANALYTICAL CHEMISTRY  

    A very sensitive, simple, and fast solid-phase spectrophotometric procedure for the determination of phenol using the p-nitrobenzenediazonium reagent (DAR reagent) was developed. This procedure is based on the simultaneous concentration of the orange product on a Dowex 1-X2 anion exchanger within 15 min, and a direct absorbance measurement of the sorbed species at both 530 nm (the absorption maximum of the phenol-DAR in the resin phase) and 700 nm (the range where only the resin absorbs light). Quality control and evaluation of the analytical parameters was carried out using a comprehensive prevalidation strategy. The linearity of the method was confirmed within an analyte working range from 0.01 to 0.10 mu mol (0.2 to 2.0 nmol mL(-1)). The precision ranged from +/- 1.17 to +/- 9.61%; the accuracy ranged from -17.50 to +17.81%. The evaluated limiting values were L-D = 0.0013 mu mol and L-Q = 0.0082 mu mol. The DAR-SPS method was successfully applied to the determination of phenol in a pharmaceutical sample of salicylic acid (98.0 - 100.0%) and vaccines (98.0 - 103.4%).

    DOI: 10.2116/analsci.28.397

    Web of Science

    researchmap

  • Selective Determination of Trace Iron in Different Oxidation States in Natural Water by Flow Injection–Solid Phase Spectrometry 査読

    S. MATSUOKA, Y. TENNICHI, T. ITO, K. HORI, K. YOSHIMURA

    Analytical Sciences   28 ( 3 )   225 - 230   2012年3月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.2116/analsci.28.225

    Web of Science

    researchmap

  • Simple spectrophotometer for solid phase spectrometry applicable to on-site analysis of phosphate in natural water 査読

    Sarenqiqige, M. Koga, M. Satoda, S. Matsuoka, K. Yoshimura

    Kyushu University Global-COE “Science for Future Molecular Systems” Journal   ( 5 )   106 - 109   2012年3月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    researchmap

  • 酸性ポリオール-ホウ酸錯体の化学とそのホウ素分析への応用 査読

    邵 超英, 宮崎 義信, 松岡 史郎, 竹原 公, 藤森 崇夫, 吉村 和久

    分析化学   61 ( 3 )   177 - 184   2012年3月

     詳細を見る

    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.2116/bunsekikagaku.61.177

    Web of Science

    researchmap

  • Chromium(III) oxidation by free chlorine in tap water during chlorination process studied by an improved solid phase spectrometry 査読

    S. Saputro, K. Yoshimura, K. Takehara, S. Matsuoka, Narsito

    Anal. Sci   27 ( 6 )   649 - 652   2011年6月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.2116/analsci.27.649

    Web of Science

    researchmap

  • Differential Pulse Voltammetric Determination of Free Chlorine for Water Disinfection Process 査読

    Sulistyo Saputro, Ko Takehara, Kazuhisa Yoshimura, Shiro Matsuoka, Narsito

    ELECTROANALYSIS   22 ( 23 )   2765 - 2768   2010年12月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:WILEY-V C H VERLAG GMBH  

    The electrochemical detection of free chlorine based on the reduction at a gold electrode has been studied. The differential pulse voltammetric curves exhibited well-defined cathodic peaks. Investigations with this system suggested that the active species in the cathodic reaction is HClO. Excellent reproducibility was demonstrated at pH 5. The peak height could be used for accurate and rapid determination of free chlorine in a sample water. A linear relationship (r(2) = 0.99) was found for the concentration range of 1-5 mgCldm(-3) and the detection limit was estimated to be 0.04 mgCldm(-3).

    DOI: 10.1002/elan.201000322

    Web of Science

    researchmap

  • Improved Solid-phase Spectrometry for the Microdetermination of Total and Dissolved Phosphate 査読

    Masaaki KOGA, Shiro MATSUOKA, Kazuhisa YOSHIMURA

    Analytical Sciences   26 ( 9 )   963 - 968   2010年9月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.2116/analsci.26.963

    Web of Science

    researchmap

  • Recent trends in solid phase spectrometry: 2003-2009. A Review 招待 査読

    Shiro Matsuoka, Kazuhisa Yoshimura

    ANALYTICA CHIMICA ACTA   664 ( 1 )   1 - 18   2010年4月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE BV  

    Around 100 papers published from 2003 to the present are reviewed concerning analytical methods for the direct light measurement of a solid phase in which a target colored or fluorescent analyte is concentrated. Recent attention has been paid to the development of flow injection-solid phase spectrometry as a simple and inexpensive tool for routine analysis of organic compounds or pharmaceuticals. Due to some improvements in flow injection analysis, such as sequential injection and lab-on-a-valve, it is possible not only to reduce the reagent consumption but also to devise fully automatic and miniaturized systems with minimal maintenance needs. This may have the potential of becoming one of the green analytical methods. Flow injection-solid phase spectrometry is expected to be applied to the speciation of trace chemical components (e.g., specific determination of trace metal ions in different existent oxidation states) in real samples in the environment. (C) 2010 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.aca.2010.01.041

    Web of Science

    researchmap

  • Improved Solid-phase Spectrophotometry for the Microdetermination of Chromium(VI) in 査読

    S. SAPUTRO, K. YOSHIMURA, S. MATSUOKA, K. TAKEHARA Narsito

    Anal. Sci.   25 ( 12 )   1445 - 1450   2009年12月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.2116/analsci.25.1445

    Web of Science

    researchmap

  • Interaction of boric acid with salicyl derivatives as an anchor group of boron-selective adsorbents 査読

    Yoshinobu Miyazaki, Hidenobu Matsuo, Takao Fujimori, Hiroyuki Takemura, Shiro Matsuoka, Tadashi Okobira, Kazuya Uezu, Kazuhisa Yoshimura

    POLYHEDRON   27 ( 13 )   2785 - 2790   2008年9月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:PERGAMON-ELSEVIER SCIENCE LTD  

    The complexation ofboricacid with salicylic acid, salicyl alcohol and bis(hydroxymethyl)phenol derivatives has been investigated in detail using B-11 NMR spectroscopy. Boric acid accepts an electron pair through the nucleophilic attack of the ligand, followed by a condensation reaction, to form the 1: 1 monochelate complex. The monochelate complex then reacts with the ligand through the condensation reaction to give the 1:2 bischelate complex. Bis(hydroxymethyl)phenol derivatives formed quite stable chelate complexes among the examined salicyl derivatives. it was clarified by molecular modeling calculations that the complexation with bis(hydroxymethyl)phenol derivatives was highly favorable from an enthalpy viewpoint. An anion-exchange resin presorbed with 3,5-bis(hydroxymethyl)-4-hydroxybenzoate had a strong adsorbability of boron over a wide pH range. The adsorbent quantitatively removed boron up to approximately a half amount of the loaded ligand, which indicated that the boron species adsorbed onto the resin was predominantly present as the -3 charged 1:2 bischelate complex. The formation constant of the 1:2 bischelate complex with 3,5-bis(hydroxymethyl)-4-hydroxybenzoate in the resin phase was estimated to be log (beta) over bar (f(BLAc2)) = 5.0, which almost agreed with those of the salicyl alcohol derivatives in aqueous solutions. (C) 2008 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.poly.2008.06.007

    Web of Science

    researchmap

  • Electrochemical control of the bioluminescence by bacterial luciferase using platinum-mesh electrode 査読

    Ko Takehara, Shinya Nakashima, Shinya Yamasaki, Shiro Matsuoka

    CHEMISTRY LETTERS   36 ( 11 )   1358 - 1359   2007年11月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:CHEMICAL SOC JAPAN  

    Bioluminescence reaction by bacterial luciferase has been successfully controlled by a controlled-potential electrolysis using platinum-mesh electrode to regenerate the reduced form of flavin mononucleotide (FMNH2), which is one of the substrates of the reaction. It was found that the regeneration of FMNH2 is facilitated by the adsorbed hydrogen atoms formed on a platinum electrode surface in the presence of phosphate ions.

    DOI: 10.1246/cl.2007.1358

    Web of Science

    researchmap

  • Kinetic study on Cr(VI) reduction in natural water by means of flow injection-solid phase spectrometry (FI-SPS) 査読

    T. Tsuruhara, K. Takehara, K. Yoshimura, S. Matsuoka, Sulistyo Saputro, J. Aizawa

    J. Ion Exchange   18 ( 4 )   524 - 528   2007年9月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.5182/jaie.18.524

    researchmap

  • Development and prevalidation of a method for phenol determination by solid-phase spectrophotometry 査読

    Jadranka Vukovic, Shiro Matsuoka, Kazuhisa Yoshimura, Vladimir Grdinic, Renata Jurisic Grubesic

    MICROCHIMICA ACTA   159 ( 3-4 )   277 - 285   2007年7月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:SPRINGER WIEN  

    A simple, sensitive and rapid solid-phase spectrophotometric procedure was developed for the determination of traces of phenol with 4-aminoantipyrine as a reagent (AAP-SPS), and the optimal experimental conditions were established. This method was performed by sorption and direct absorbance measurements of the product phenol-AAP sorbed on the anion-exchanger Dowex 1-X4 (0.2 g) at 495 nm (absorption maximum) and 700 nm (non-absorption wavelength). The sensitivity offered by the AAP-SPS procedure was higher by a factor of 40 compared with the respective conventional spectrophotometric method. Metrological characteristics were established using a prevalidation strategy. The AAP-SPS procedure is characterized by a linear calibration function in the working range of 0.05-0.50 mu mol, low standard deviation of procedure (+/- 0.012), low limit of determination (0.021 mu mol), and favorable random (+/- 0.85 to +/- 11.27%) and systematic deviations (-4.55 to +/- 11.50%). Moreover, the accuracy of the system investigated by the recovery test is acceptable (99-102%). Favorable working and performance characteristics make the new SPS method ideal for phenol monitoring in pharmaceutical preparations as well as other matrices.

    DOI: 10.1007/s00604-007-0748-5

    Web of Science

    researchmap

  • Simultaneous determination of traces of heavy metals by solid-phase spectrophotometry 査読

    J. Vukovic, S. Matsuoka, K. Yoshimura, V. Grdinic, R. Jurisic Grubesic, O. Zupanic

    TALANTA   71 ( 5 )   2085 - 2091   2007年3月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCIENCE BV  

    A coupling sensitive solid phase spectrophotometric (SPS) procedure for determination of traces of heavy metals (Me-SPS) and multicomponent analysis by multiple linear regressions (MA), a simple methodology for simultaneous determination of metals in mixtures was inaugurated. The Me-SPS procedure is based on sorption of heavy metals on PAN-resin and direct absorbance measurements of colour product Me-PAN sorbed on a solid carrier in a 1-mm cell. This methodology (Me-SPS-MA) was checked by simultaneous determination of metals in synthetic mixtures with different compositions and contents of metals important in pharmaceutical practice: Zn, Pb, Cd, Cu, Co, and Ni. Good agreement between experimental and theoretical amounts of heavy metals is obtained from the recovery test (78.3-110.0%). The proposed method enables determination of particular metal ion at the ng mL(-1) level and it was successfully applied to the determination impurities from heavy metal traces in pharmaceutical substances (Cu in ascorbic acid, Pb in glucose, and Zn in insulin). The proposed procedure could be possible contribution to the development of pharmacopoeial methodology for a heavy metals test. (c) 2006 Elsevier B.V. All rights reserved.

    DOI: 10.1016/j.talanta.2006.09.036

    Web of Science

    researchmap

  • Classification of the binding modes in bovine serum albumin using terminally substituted alkane analogues 査読

    Ko Takehara, Yuki Morinaga, Shinya Nakashima, Shiro Matsuoka, Hiroshi Kamaya, Issaku Ueda

    ANALYTICAL SCIENCES   22 ( 12 )   1571 - 1575   2006年12月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:JAPAN SOC ANALYTICAL CHEMISTRY  

    With the fluorescence probe of 8-anilino-1-naphthalenesulfonate (ANS), the binding modes of terminally substituted alkane analogues (CnX; X = COOH, OH, CHO, NH3, CONH2) to bovine serum albumin (BSA) were investigated using a competitive binding technique. The Scatchard plot of the fluorometric titration of BSA with ANS showed that the maximum binding number of ANS, n(max), was 3.81, with the binding constant, K-bnd, of 1.42 x 10(6) mol(-1) dm(3). The binding modes of CnX to BSA were analyzed based on the fluorometric titration of the ANS and BSA mixture with CnX. CnCOOH completely displaced the ANS bound to BSA, whereas CnOH and CnCHO displaced only about 40% of the ANS bound to BSA. In contrast, CnNH2 and CnCONH2 displaced very little bound ANS. By comparing these results, we classified the binding modes of CnX to BSA into three types. Two of them are detectable with the ANS fluorescence and the remaining one is not detectable with the fluorescence.

    DOI: 10.2116/analsci.22.1571

    Web of Science

    researchmap

  • On-lime Electrochemical Oxidation of Cr(III) for the determination of Total Cr by Flow Injection-Solid Phase Spectrometry 査読

    S. Matsuoka, Y. Nakatsu, K. Takehara, K. Yoshimura

    Analytical Sciences   22 ( 12 )   1519 - 1524   2006年12月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.2116/analsci.22.1519

    Web of Science

    researchmap

  • Determination of trace amounts of cobalt(II) by flow injection-solid phase spectrometry (FI-SPS) with 5-Br-PADAB 査読

    S Matsuoka, N Shiota, K Yoshimura

    ANALYTICAL SCIENCES   22 ( 1 )   177 - 181   2006年1月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:JAPAN SOC ANALYTICAL CHEMISTRY  

    kFlow injection-solid phase spectrometry (FI-SPS) has been applied to the determination of cobalt(II) in water samples. The complex formed between cobalt and 5-Br-PADAB was on-line protonated and concentrated on an AG 50W-X2 cation-exchanger in a flow-through cell. The increase in absorbance caused by the accumulation of the complex in the resin was continuously measured. The interference by copper could be effectively eliminated by using EDDP as a masking agent. The detection limit was 40 ng dm(-3) with a 4.0 cm(3) sample solution.

    DOI: 10.2116/analsci.22.177

    Web of Science

    researchmap

  • 固相分光法とその流れ分析への応用 査読

    松岡史郎, 吉村和久

    分析化学   54 ( 12 )   1137 - 1147   2005年12月

     詳細を見る

    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.2116/bunsekikagaku.54.1137

    Web of Science

    researchmap

  • Complexation of vanadium(V) oxoanion with ethanolamine derivatives in solution and in a cross-linked polymer 査読

    Y Miyazaki, S Matsuoka, Y Miura, H Sakashita, K Yoshimura

    POLYHEDRON   24 ( 9 )   985 - 994   2005年6月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:PERGAMON-ELSEVIER SCIENCE LTD  

    Complex formation between vanadate and various ethanolamine derivatives (ethanolamine, diethanolamine, methyldiethanolamine, triethanolamine and ECTEOLA-Cellulose) has been examined in detail by using V-51 NMR spectroscopy. Vanadate binds with ethanolamine to form 1:1 (O)-monodentate and (N,O)-bidentate complexes which are protonated and deprotonated forms, respectively. Ethanolamine undergoes a comparatively weak interaction with vanadate relative to the other ligands. V-51 NMR spectra clearly show that vanadate reacts with the functional group of ECTEOLA-Cellulose, as well as diethanolamine, methyldiethanolamine and triethanolamine, which are analogues of the functional groups of ECTEOLA-Cellulose, to form the -1 charged 1:1 (N,O,O)-tridentate complex. In addition to anion exchange interaction of monovanadate and isopolyvanadate anions with the protonated functional group, in the alkaline region the adsorbability of vanadium(V) onto ECTEOLA-Cellulose is a consequence of the complexation of vanadate with the functional group. The formation constant of the (N,0,0) complex with ECTEOLA-Cellulose was estimated to be log beta((N,O,O)) = 3.6, which was almost the same as those with the analogues of the functional group. (c) 2005 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.poly.2004.12.021

    Web of Science

    researchmap

  • B-11 NMR study on the interaction of boric acid with Azomethine H 査読

    H Matsuo, Y Miyazaki, H Takemura, S Matsuoka, H Sakashita, K Yoshimura

    POLYHEDRON   23 ( 6 )   955 - 961   2004年3月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:PERGAMON-ELSEVIER SCIENCE LTD  

    B-11 NMR spectroscopy provided direct evidence that boric acid reacts with Azomethine H to form a 1: 1 bischelate complex. A new peak with a -17.9 ppm chemical shift is due to the chelate complex containing tetrahedral boron. It has been quantitatively confirmed that the reaction includes two chemical equilibria;, one is related to the ligand formation and the other to the complex formation. The formation constant for the ligand is small, less than 10, whereas that for the complex is relatively large, greater than 10(5). Azomethine H is hydrolyzed in aqueous solution because of its low stability, and the ligand formation is responsible for the nature of its complexation with boric acid. (C) 2004 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.poly.2003.12.016

    Web of Science

    researchmap

  • Speciation of Boron Species Adsorbed onto Polysaccharide Gel by 11B NMR Spectroscopy 査読

    Y. Miyazaki, C. Shao, S. Matsuoka, K. Yoshimura

    J. Ion Exchange   14 (Supplement)   33 - 36   2003年7月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.5182/jaie.14.Supplement_33

    researchmap

  • Fundamental studies on ion-exchanger phase absorptiometry 査読

    S. Matsuoka, Y. Tennichi, K. Yoshimura

    J. Ion Exchange   14 (Supplement)   313 - 316   2003年7月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.5182/jaie.14.Supplement_313

    researchmap

  • Anion exchanger as a reaction/separation medium - absorptiometric determination of trace amounts of boron in waters by on-line complexation with chromotropic acid presorbed on the anion-exchange column 査読

    CY Shao, S Matsuoka, Y Miyazaki, K Yoshimura

    ANALYST   127 ( 12 )   1614 - 1620   2002年

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ROYAL SOC CHEMISTRY  

    A novel method of on-line absorptiometric determination for trace amounts of boron was developed based on the complexation with chromotropic acid presorbed on an anion-exchange column. On-line reaction and separation were achieved by controlling pH conditions in solutions to accelerate the 1:2 complex formation in the concentration process at pH 3 and to stabilize the complex in the separation process at pH 8. About 75% of the boron introduced into the stream was kinetically collected as the 1:2 complex on the column under the experimental conditions. The 1:2 complex was satisfactorily separated from excess reagent and matrix components by changing the concentration of NaClO4 in the eluent and its peak height on the chromatogram monitored at 350 nm was used for calibration. The sensitivity could be enhanced by increasing the sample amount introduced and the detection limits (3sigma) were 162 ng dm(-3) and 45 ng dm(-3) of boron, when 5.0 cm(3) and 13.4 cm(3) of the samples were used, respectively. The method has been successfully applied to the determination of boron in samples of river water, tap water and ion-exchanged water.

    DOI: 10.1039/b207869d

    Web of Science

    researchmap

  • Studies on the complexation of boric acid with polyhydroxyl compounds 査読

    C. Shao, S. Matsuoka, Y. Miyazaki, K. Yoshimura

    Anal. Sci.   17   i1475 - i1478   2001年8月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)  

    researchmap

  • Simultaneous determination of trace metals by solid phase absorptiometry: 査読

    Y. Tennichi, S. Matsuoka, K. Yoshimura

    Fresenius journal of Analitical Chemistry   368 ( 5 )   443 - 448   2000年11月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1007/s002160000515

    Web of Science

    researchmap

  • Complexation of borate with cross-linked polysaccharide anion exchanger: 11B NMR and adsorption properties studies 査読

    Chaoying Shao, Yoshinobu Miyazaki, Shiro Matsuoka, Kazuhisa Yoshimura, Hirofumi Sakashita

    Macromolecules   33 ( 1 )   19 - 25   2000年1月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ACS  

    Boron adsorption behavior on cross-linked polysaccharide anion exchangers, QAE-Sephadex and QA cellulose, was examined in detail by 11B NMR measurements and distribution studies. For the QAE-Sephadex system, two signals of 1:1 borate complexes with α,β and α,γ-diol moieties of the glucopyranoside residues were observed, showing identical chemical shift values with those for the Sephadex gel system. Only the 1:1 complex of borate with α,β-diol moiety of the gel matrix was formed for QA cellulose. The formation constants of the borate complexes, estimated by the signal intensities of 11B NMR, were almost the same in the anion exchangers and Sephadex gel. The adsorbability of boric acid/borate was not enhanced as much by the presence of charged functional groups, because both the ion-exchange selectivity toward borate and formation constants of borate complexes with the gel matrix are not so high. The pH in the anion exchanger phase is higher than that in the external equilibrated solution, however, is slightly lower than the value expected from the Donnan relation, as a result of the fixation of anionic borate onto the gel matrix by the complexation: -log[H+]̄ = -a log[H+]+b(α≤1 and b&gt
    O). Boron adsorption behaviors on the polysaccharide anion exchangers, such as pH dependence, boron concentration dependence, and background electrolyte effect, can be explained satisfactorily on the basis of such properties.

    DOI: 10.1021/ma991257o

    Scopus

    researchmap

  • Equilibrium and kinetic studies on the complexation of boric acid with chromotropic acid 査読

    CY Shao, S Matsuoka, Y Miyazaki, K Yoshimura, TM Suzuki, DAP Tanaka

    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS   18 ( 18 )   3136 - 3142   2000年

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ROYAL SOC CHEMISTRY  

    The complexation of boric acid with chromotropic acid in aqueous solution was examined thoroughly by B-11 NMR measurements. Two peaks with chemical shift values of delta -17.7 and -18.0 were observed besides the free boric acid/borate peak and ascribed to the 1:1 and the 1:2 complexes, respectively. The 1:2 complex is formed in acidic solution, while the 1:1 complex prevails in a higher pH range. The formation constants for these complexes were evaluated based on the signal intensities of B-11 NMR spectra to be log beta(1)=-1.57 and log beta(2)=2.35, which are well consistent with those reported previously as well as that (beta(2)) obtained kinetically in this work. The chromatographic separation of the 1:2 complex from the other species enabled a kinetic study of the reaction which revealed that the reaction for 1:1 complex formation takes place much faster than that for 1:2 complex formation. The pH dependences of the rate constants of the forward and backward reactions of the 1:2 complexation could be interpreted by the catalytic role of hydrogen ions in the reactions. Plausible mechanisms for both the reactions of 1:2 complex formation and decomposition were proposed. On the basis of the equilibrium and kinetic information on the complexation, the optimum conditions for practical applications of the ligand so far reported could be well understood.

    DOI: 10.1039/b004399k

    Web of Science

    researchmap

  • 固相分光法の開発とその超微量成分流れ分析への応用 査読

    松岡史郎

    分析化学   48 ( 11 )   1027 - 1028   1999年11月

     詳細を見る

    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

    Web of Science

    researchmap

  • Flow analysis of micro amounts of chromium(III) and (VI) in natural water by solid phase spectrophotometry using diphenylcarbazide 査読

    S Matsuoka, Y Tennichi, K Takehara, K Yoshimura

    ANALYST   124 ( 5 )   787 - 791   1999年5月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ROYAL SOC CHEMISTRY  

    Specific determination of chromium(III) and chromium(VI) in natural water samples was performed without mutual separation. The chromium in sample solution was concentrated on cation-exchange resin packed in a flow-through cell as a reaction product of chromium(VI) with diphenylcarbazide. The absorbance increase caused by the accumulation of the complex on cation-exchange resin was continuously measured. By using peroxodisulfate as an oxidizing agent, the chromium(III) in sample solution was completely oxidized to chromium(VI). The chromium(III) concentration was calculated by the difference between the values of the total chromium and chromium(VI). The detection limit for chromium(VI) and total chromium was 70 pg and 120 pg, respectively. This method was applied to the specific determination of chromium in several natural water samples. The results of the total chromium obtained by the proposed method show moderate agreement with that obtained with ICP-MS. Unlike the previous results reported in chromium speciation studies, the predominant chromium species in natural water was chromium(VI).

    DOI: 10.1039/a900493i

    Web of Science

    researchmap

  • 固相分光法の顕微分光法への応用 査読

    松岡史郎, 吉村和久, 立田清朗, 進野 勇

    分析化学   47 ( 6 )   335 - 340   1998年6月

     詳細を見る

    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.2116/bunsekikagaku.47.335

    Web of Science

    researchmap

  • Complexation of boric acid with the N-methyl-D-glucamine group in solution and in crosslinked polymer 査読

    Kazuhisa Yoshimura, Yoshinobu Miyazaki, Fumio Ota, Shiro Matsuoka, Hirofumi Sakashita

    Journal of the Chemical Society - Faraday Transactions   94 ( 5 )   683 - 689   1998年3月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry  

    N-Methylglucamine resin has been shown to be a good adsorbent for borate or boric acid. Above ca. pH 6, the boron adsorbability of this resin increased with a maximum around pH 9. The maximum distribution ratio was higher than 106, however, further increase in pH resulted in a decrease in the distribution ratio. The combination of distribution and 11B MAS NMR measurements revealed the formation of a 1:1 tetradentate complex of B(OH)4 - with the N-methylglucamine group. The calculated pH-dependence of boron adsorption agreed well with the experimental results with respect to the -log [H+] values in the resin phase (not in the external solution) estimated by 31P NMR measurements. The maximum adsorption around pH 9 of the equilibrated solution is due to the fact that the pH in the resin phase remains higher than that in the external solution. Therefore, B(OH)3/B(OH)4 - is selectively concentrated into the resin phase and by the dehydration condensation B(OH)4 - forms the 1:1 tetradentate complex with the anchor group. The overall formation constant of the complex was estimated to be 104.0±0.1, which was almost the same magnitude as that of the 1:1 monochelate complex with an α,β-diol site of N-methyl-D-glucamine (which is an analogue of the functional group of the resin) in aqueous solutions of pH 5.1-7.4. However, the binding structures of each 1:1 complex with the N-methyl-D-glucamine group are quite different in the aqueous solution and in the crosslinked polymer.

    DOI: 10.1039/a707790d

    Scopus

    researchmap

  • 山口県秋芳洞洞口のトゥファ形成におけるシアノバクテリアの役割 査読

    吉村 和久, 井上 真理, 染谷 孝, 松浦 健太郎, 橋口 美保子, 原 友子, 大坪 久記, 松岡 史郎

    洞窟学雑誌   20   27 - 37   1996年3月

     詳細を見る

    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

    researchmap

  • Application of Ion-exchanger Phase Visible Light Absorption to Flow Analysis- Determination of Vanadium in Natural Water and Rock 査読

    S. Matsuoka, K. Yoshimura, A. Tateda

    Anal. Chim. Acta   317 ( 1-3 )   207 - 213   1995年12月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/0003-2670(95)00412-2

    Web of Science

    researchmap

  • 固相分光法の流れ分析への応用 査読

    松岡史郎, 吉村和久

    J. Flow Injection Anal.   12 ( 1 )   8 - 22   1995年1月

     詳細を見る

    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

    researchmap

  • Recent Progress in Solid-phase Spectrometry: Its Application to Flow Analysis 招待 査読

    K. Yoahimura, S. Matsuoka

    Laboratory Robotics and Automation   5   231 - 244   1993年2月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    researchmap

  • Flow Analysis of Copper by Ion-exchanger Phase Absorptiometry with 4,7-Diphenyl- 2,9-dimethyl-1,10-phenanthroline disulfonate and Its Application to the Study of Karst Groundwater Storm Runoff 査読

    K. Yoshimura, S. Matsuoka, Y. Inokura, U. Hase

    Anal. Chim. Acta   268 ( 2 )   225 - 233   1992年10月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1016/0003-2670(92)85216-S

    Web of Science

    researchmap

  • Determination of Aluminium in High Purity Water by Ion-exchanger Phase Spectrofluorometry Combined with Flow Analysis

    S. Matsuoka, K. Yoshimura, A. Tateda

    Mem. Fac. Sci., Ser. C, Kyushu Univ.   18 ( 2 )   169 - 178   1992年9月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(大学,研究機関等紀要)  

    researchmap

  • Application of Ion-exchanger Phase Spectrofluorometry to Flow Analysis-Determination of Micro Amounts of Some Rare Earths 査読

    K. Yoshimura, S. Matsuoka, T. Tabuchi, H. Waki

    Analyst (London)   117 ( 2 )   189 - 193   1992年

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    DOI: 10.1039/an9921700189

    Scopus

    researchmap

  • FLOW-ANALYSIS METHOD FOR TRACE-ELEMENTS BY ION-EXCHANGER PHASE ABSORPTIOMETRY 査読

    K YOSHIMURA, S MATSUOKA

    ION EXCHANGE ADVANCES   183 - 190   1992年

     詳細を見る

    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:ELSEVIER APPL SCI PUBL LTD  

    Web of Science

    researchmap

  • Flow Injection Analysis of Phosphate Ion with the Liquid Chloranilate Selective Membrane Electrode as a Detector

    S. Matsuoka, A. Tateda

    Mem. Fac. Sci., Kyushu Univ., Ser.C   18 ( 1 )   49 - 54   1991年9月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(大学,研究機関等紀要)   出版者・発行元:Kyushu Univ.  

    researchmap

  • Application of Ion-exchanger Phase Absorptiometry to Flow Analysis-Determination of Vanadium(V) in Natural Water

    S. Matsuoka, J. Yoshimura, H. Waki

    Mem. Fac. Sci., Ser. C, Kyushu Univ.   18 ( 1 )   55 - 62   1991年9月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(大学,研究機関等紀要)   出版者・発行元:Kyushu Univ.  

    researchmap

  • Spectrophotometric Application of Ion-exchanger--Flow Analysis of 査読

    K. Yoshimura, S. Matsuoka

    New Developments in Ion Exchange: Materials, Fundamentals, and   377 - 382   1991年

     詳細を見る

    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)  

    Web of Science

    researchmap

  • The Property of the Liquid Chloranilate Selective Membrane Electrode Based on Cadmium-(1,10-penanthroline) Ion and the Indirect Determination of Phosphate Ion

    A. Tateda, S. Matsuoka

    Mem. Fac. Sci., Kyushu Univ., Ser. C   17 ( 2 )   207 - 212   1990年9月

     詳細を見る

    記述言語:英語   掲載種別:研究論文(大学,研究機関等紀要)   出版者・発行元:Kyushu Univ.  

    researchmap

  • Determination of molybdenum(VI) in natural water and rock by ion-exchange absorptiometry combined with flow analysis 査読

    Kazuhisa Yoshimura, Shiro Matsuoka, Hirohiko Waki

    Analytica Chimica Acta   225 ( C )   313 - 321   1989年

     詳細を見る

    記述言語:英語   掲載種別:研究論文(学術雑誌)  

    Ion-exchange absorptiometry combined with flow analysis has been applied to the determination of trace amounts of molybdenum(VI) in natural water and rock. By using a pretreatment column packed with Sephadex G-25 gel, molybdenum(VI) in a sample solution can be sorbed selectively on the gel at pH 3.5. The molybdenum(VI) in the column was desorbed with EDTA as the molybdenum(VI)-EDTA complex, and the solution was introduced into a Tiron solution stream. The yellow complex formed between molybdenum(VI) and Tiron in the flow system was then concentrated on a QAE-Sephadex A-25 anion exchanger packed in a flow-through silica micro-cell. The attenuation of incident light by the molybdenum(VI)-Tiron complex on the anion exchanger in the cell was continuously recorded with a spectrophotometer at 410 nm. The complex on the anion exchanger was easily desorbed with sodium nitrate, so the flow-through cell could be used repeatedly. The minimum amount that could be detected corresponded to 15 ng of molybdenum(VI). Molybdenum(VI) in three or four sample solutions could be determined within 1 h. © 1989.

    DOI: 10.1016/S0003-2670(00)84620-6

    Scopus

    researchmap

▶ 全件表示

書籍等出版物

  • 製品中に含まれる (超)微量成分・不純物の同定・定量ノウハウ

    松岡史郎, Sarenqiqige, 吉村和久( 担当: 共著 ,  範囲: 第1章第7節 固相分光法による超微量成分分析 -水中の溶存微量成分の簡易高感度分析法、溶存クロムなどの分析事例)

    株式会社 技術情報協会  2014年2月 

     詳細を見る

    記述言語:日本語 著書種別:学術書

    researchmap

  • Chlorine: Properties, Applications and Health Effects, Chapter 8: "Analytical methods of chlorine and the substances produced by the chlorine treatments"

    S. Saputro, K. Yoshimura, K. Takehara, S. Matsuoka, Narsito (Roger Mangione, Dana Carlile( 担当: 共著)

    Nova Science Publishers Inc.  2011年10月 

     詳細を見る

    記述言語:英語 著書種別:学術書

    researchmap

  • 分析化学便覧(改訂第6版)

    日本分析化学会編( 担当: 共著 ,  範囲: 吸光光度法(8.4.3 項),イオン交換(8.7.1))

    丸善出版  2011年9月  ( ISBN:4621084097

     詳細を見る

    記述言語:日本語 著書種別:事典・辞書

    researchmap

  • Handbook of Inorganic Chemistry Research, Chapter 8: "Complexation of Boric Acid with Polyhydroxy Compounds and its Relevance to Practical Aspects "

    K. Yoshimura, Y. Miyazaki, S. Matsuoka, K. Takehara, T. Fujimori, Desiree A. Morrison( 担当: 共著)

    Nova Science Pub Inc,  2010年9月 

     詳細を見る

    記述言語:英語 著書種別:学術書

    researchmap

  • 理系のための基礎化学

    増田芳男, 澤田 清, 編著, 増田芳男, 徳江郁雄, 島倉紀之, 工藤久昭, 佐藤敬一, 丸山健二, 湯川靖彦, 松岡史郎, 澤田 清, 後藤真一( 担当: 共著 ,  範囲: 6・1節,6.2節)

    化学同人  2006年4月  ( ISBN:4759810552

     詳細を見る

    記述言語:日本語 著書種別:学術書

    researchmap

MISC

  • ホウ酸-アゾメチンH錯生成系の化学とホウ酸の電気化学的定量への応用

    竹原 公, 宮崎 義信, 藤森 崇夫

    九州大学中央分析センター報告   ( 30 )   10 - 20   2012年

     詳細を見る

    記述言語:日本語   掲載種別:記事・総説・解説・論説等(その他)   出版者・発行元:九州大学中央分析センター  

    CiNii Article

    CiNii Books

    researchmap

  • Complexation of boric acid with polyhydroxy compounds and its relevance to practical aspects

    K. Yoshimura, Y. Miyazaki, S. Matsuoka, K. Takehara, T. Fujimori

    Handbook of Inorganic Chemistry Research   174 - 209   2011年12月

     詳細を見る

    Complexes of boric acid/borate and polyols play an important role in many fields because of the biological significance in organism metabolism and the practical significance in the electronic industry and agriculture of removing boric acid/borate from water. To thoroughly understand the boron chemistry of the polyols concerned, many studies have been done. Here, an experimental approach to the interaction and its recent progress are first mentioned. 11B NMR spectroscopy is one of the excellent tools for elucidating the nature of the interaction between boric acid/borate and polyols. Its combination with other methods enables basic understanding of the chemical reactions. The complexation is then discussed on a thermodynamic and kinetic basis. Reaction paths for 1:1 complexation are in general divided into two: neutral polyols react directly with tetrahedral borate, whereas acidic polyols can react with trigonal boric acid in a 1:1 complexation. Both of the reactions produce tetrahedral anionic complexes, followed by a condensation reaction between the 1:1 monochelate complex and the undissociated diols to yield the 1:2 bischelate complex. A basic understanding of the complexation makes it possible to clarify the principles on the practical aspects of the complexation, which is finally reviewed. © 2010 Nova Science Publishers, Inc. All rights reserved.

    Scopus

    researchmap

  • 固相分光法とその微量溶存成分のスペシエーション分析への応用

    松岡史郎, Sarenqiqige, 吉村和久

    ぶんせき   444 ( 12 )   713 - 719   2011年12月

     詳細を見る

    記述言語:日本語   掲載種別:記事・総説・解説・論説等(その他)   出版者・発行元:日本分析化学会  

    researchmap

  • 化学発光を用いたCrの酸化状態別分析法

    松岡史郎

    ぶんせき   369 ( 12 )   671 - 671   2007年12月

     詳細を見る

    記述言語:日本語   掲載種別:記事・総説・解説・論説等(その他)   出版者・発行元:日本分析化学会  

    researchmap

  • 天然水中に存在する微量元素のスペシエーション--無機イオンの酸化状態別定量法を中心に

    松岡史郎, 吉村和久

    ぶんせき   2   87 - 93   2007年2月

     詳細を見る

    記述言語:日本語   掲載種別:記事・総説・解説・論説等(その他)   出版者・発行元:日本分析化学会  

    researchmap

  • 11B NMRによるホウ素選択性高分子の機能性に関する研究

    吉村和久, 邵 超英, 松岡史郎, 宮崎義信, 坂下寛文

    九州大学中央分析センター報告   20   2 - 11   2002年12月

     詳細を見る

    記述言語:日本語   掲載種別:記事・総説・解説・論説等(その他)   出版者・発行元:九州大学中央分析センター  

    researchmap

  • ミニファイル 分離 イオン交換

    松岡史郎, 吉村和久

    ぶんせき   317 ( 5 )   247 - 248   2001年5月

     詳細を見る

    記述言語:日本語   掲載種別:記事・総説・解説・論説等(その他)   出版者・発行元:日本分析化学会  

    researchmap

  • イオン交換分離:無機成分の分離・濃縮を中心に

    吉村 和久, 松岡 史郎, 天日 美薫

    ぶんせき   282 ( 6 )   430 - 436   1998年6月

     詳細を見る

    記述言語:日本語   掲載種別:記事・総説・解説・論説等(その他)   出版者・発行元:日本分析化学会  

    researchmap

  • 入門講座 分離・分取法の基礎知識:イオン交換

    松岡史郎, 吉村和久

    ぶんせき   275 ( 11 )   28 - 36   1997年11月

     詳細を見る

    記述言語:日本語   掲載種別:記事・総説・解説・論説等(その他)   出版者・発行元:日本分析化学会  

    researchmap

  • イオン交換体相吸光光度流れ分析法による微量成分定量法の開発

    松岡史郎, 吉村和久

    九州大学中央分析センターセンターニュース   12 ( 3 )   6 - 9   1995年1月

     詳細を見る

    記述言語:日本語   掲載種別:記事・総説・解説・論説等(その他)   出版者・発行元:九州大学中央分析センター  

    researchmap

  • ミニファイル ベリリウム、カルシウム

    松岡史郎, 吉村和久

    ぶんせき   254 ( 12 )   964 - 965   1993年12月

     詳細を見る

    記述言語:日本語   掲載種別:記事・総説・解説・論説等(その他)   出版者・発行元:日本分析化学会  

    researchmap

▶ 全件表示

共同研究・競争的資金等の研究

  • 河川水中に存在するマンガンの溶存状態

    2015年4月 - 2017年3月

    日本学術振興会  科学研究費助成事業  基盤研究(C)

      詳細を見る

    資金種別:競争的資金

    researchmap

  • 藻場の磯焼けと沿岸海水中に存在する鉄化学種濃度との関連

    2012年4月 - 2014年3月

    日本学術振興会  科学研究費助成事業  基盤研究(C)

      詳細を見る

    資金種別:競争的資金

    researchmap

  • 磯焼けの原因究明を目的とした沿岸海水中の溶存超微量鉄のスペシエーション

    2006年4月 - 2008年3月

    日本学術振興会  科学研究費助成事業  基盤研究(C)

      詳細を見る

    資金種別:競争的資金

    配分額:1600000円 ( 直接経費:1600000円 )

    researchmap

  • 受光部に光ファイバ−を装着した分光器を用いた低光量領域における固相の透過光測定

    1998年4月 - 2000年3月

    科学研究費助成事業  奨励研究(A)

      詳細を見る

    資金種別:競争的資金

    配分額:2100000円 ( 直接経費:2100000円 )

    researchmap

  • 固相分光法の顕微分光法への応用

    1996年4月 - 1997年3月

    科学研究費助成事業  奨励研究(A)

      詳細を見る

    資金種別:競争的資金

    配分額:900000円 ( 直接経費:900000円 )

    researchmap

  • クロラニル酸の難溶性塩を用いたリン酸塩類の分別定量法の開発

    1992年4月 - 1993年3月

    科学研究費助成事業  奨励研究(A)

      詳細を見る

    資金種別:競争的資金

    配分額:9000000円 ( 直接経費:9000000円 )

    researchmap

▶ 全件表示

 

担当経験のある授業科目

  • 分析化学I

    2021年
    -
    現在
    機関名:新潟大学

  • 安全教育

    2020年
    -
    現在
    機関名:新潟大学

  • 卒業論文Ⅱ

    2020年
    -
    現在
    機関名:新潟大学

  • 卒業論文

    2020年
    -
    現在
    機関名:新潟大学

  • 卒業論文Ⅰ

    2020年
    -
    現在
    機関名:新潟大学

  • 課題研究

    2020年
    -
    現在
    機関名:新潟大学

  • 課題研究(自然環境)A

    2020年
    -
    現在
    機関名:新潟大学

  • 環境経済システム論Ⅰ

    2019年
    -
    現在
    機関名:新潟大学

  • 自然環境科学総論

    2018年
    -
    現在
    機関名:新潟大学

  • 理学スタディ・スキルズ

    2017年
    -
    現在
    機関名:新潟大学

  • 自然環境科学実験C1

    2017年
    -
    現在
    機関名:新潟大学

  • 課題研究A

    2017年
    -
    現在
    機関名:新潟大学

  • 自然環境科学実験C2

    2017年
    -
    現在
    機関名:新潟大学

  • 課題研究B

    2017年
    -
    2019年
    機関名:新潟大学

  • 課題研究C

    2017年
    -
    2019年
    機関名:新潟大学

  • 専門力アクティブ・ラーニング

    2017年
    機関名:新潟大学

  • 日本事情自然系A

    2016年
    機関名:新潟大学

  • 環境科学スタディスキルズ

    2016年
    機関名:新潟大学

  • 課題研究(自然環境)

    2015年
    -
    2016年
    機関名:新潟大学

  • 化学入門

    2014年
    -
    現在
    機関名:新潟大学

  • 自然科学実験法

    2014年
    -
    2017年
    機関名:新潟大学

  • 研究発表演習Ⅰ(学外発表)

    2014年
    機関名:新潟大学

  • 環境科学特定演習Ⅰ

    2014年
    機関名:新潟大学

  • 自然科学総論Ⅴ

    2014年
    機関名:新潟大学

  • グリーンケミストリー入門

    2013年
    -
    現在
    機関名:新潟大学

  • 化学基礎B

    2013年
    -
    現在
    機関名:新潟大学

  • 研究発表演習Ⅰ(中間発表)

    2012年
    -
    2015年
    機関名:新潟大学

  • 環境科学総合演習Ⅰ

    2012年
    -
    2015年
    機関名:新潟大学

  • 環境科学セミナーⅠ

    2012年
    -
    2015年
    機関名:新潟大学

  • 環境科学特定研究Ⅰ

    2012年
    -
    2014年
    機関名:新潟大学

  • チームインターンシップ Ⅰ

    2012年
    -
    2013年
    機関名:新潟大学

  • チームインターンシップ Ⅱ

    2012年
    -
    2013年
    機関名:新潟大学

  • 環境科学演習Ⅰ

    2012年
    機関名:新潟大学

  • 環境科学特定研究

    2012年
    機関名:新潟大学

  • 地球環境化学

    2011年
    -
    現在
    機関名:新潟大学

  • グリーンケミストリー概説

    2010年
    -
    2013年
    機関名:新潟大学

  • 環境化学特論Ⅱ

    2008年
    -
    現在
    機関名:新潟大学

  • 基礎化学実験

    2008年
    -
    2016年
    機関名:新潟大学

  • 環境分析化学

    2007年
    -
    現在
    機関名:新潟大学

  • 環境化学要論I

    2007年
    -
    現在
    機関名:新潟大学

  • 自然環境科学実験C

    2007年
    -
    2016年
    機関名:新潟大学

  • 自然環境科学概論C

    2007年
    -
    2016年
    機関名:新潟大学

  • 地球科学

    2007年
    -
    2011年
    機関名:新潟大学

  • 化学実験

    2007年
    -
    2010年
    機関名:新潟大学

  • 環境化学特論II

    2007年
    機関名:新潟大学

▶ 全件表示