Updated on 2026/03/20

写真a

 
FURUKAWA Ko
 
Organization
. Center for Coordination of Research Facilities Associate Professor
Title
Associate Professor
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Degree

  • Doctor(Science) ( 2001.3   Osaka City University )

  • 修士(理学) ( 1998.3   大阪市立大学 )

Research Interests

  • and relaxations mossbeuer effects

  • Magnetic resonances

  • Functional Materials

  • Physical Chemistry

  • 磁気緩和

  • 磁気共鳴

  • Electron Spin Resonance

Research Areas

  • Nanotechnology/Materials / Functional solid state chemistry

  • Nanotechnology/Materials / Fundamental physical chemistry

  • Nanotechnology/Materials / Energy chemistry

Research History (researchmap)

  • Institute for Molecular Science   Division of Materials Molecular Science   Visiting Associate Professor

    2019.4 - 2022.3

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  • Niigata University   Institute for Research Promotion, Center for Coordination of Research Facilities   Associate Professor

    2017.2

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  • Kyoto University   Institute for Chemical Research

    2016.4 - 2017.3

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  • Niigata University   Center for Instrumental Analysis   Associate Professor

    2012.12 - 2017.1

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  • Institute for Molecular Science

    2004.4 - 2007.3

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  • 総合研究大学院大学 数物科学研究科 助手 (併任)

    2002.8 - 2004.3

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  • Institute for Molecular Science

    2001.4 - 2004.3

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  • 日本学術振興会 特別研究員(DC2)

    1999.1 - 2001.3

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Research History

  • Niigata University   Institute for Research Promotion Center for Coordination of Research Facilities   Associate Professor

    2017.2

  • Niigata University   Center for Instrumental Analysis   Associate Professor

    2012.12 - 2017.1

Education

  • Osaka City University   Graduate School of Science   物質分子系専攻

    1998.4 - 2001.3

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    Country: Japan

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  • Osaka City University   Graduate School of Science   化学専攻

    1997.4 - 1998.3

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    Country: Japan

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  • Osaka City University   Faculty of Science   Department of Material Science

    1993.4 - 1997.3

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    Country: Japan

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Professional Memberships

Committee Memberships

  • 日本化学会関東支部新潟地域懇談会   新潟地域事務局  

    2021.4   

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  • 電子スピンサイエンス学会   代議員(編集担当)  

    2018.1 - 2019.12   

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    Committee type:Academic society

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  • 電子スピンサイエンス学会   会誌編集委員  

    2011.8 - 2019.12   

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    Committee type:Academic society

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Papers

  • Air‐Stable Radical Ion Pairs Formed from 20π‐Electron 5,15‐Diazaporphyrinoids and Tetracyanoquinodimethane Derivatives

    Sae Ohtani, Momo Kaneko, Yuki Shimizu, Mao Minoura, Ko Furukawa, Yoshihiro Matano

    Asian Journal of Organic Chemistry   2025.4

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    With the aim of exploring 5,15‐diazaporphyrinoids with four meso substituents (R<sub>4</sub>DAP) as a new class of π‐electron donors, the generation of air‐stable π‐radical ion pairs formed from R<sub>4</sub>DAP and 7,7,8,8‐tetracyanoquinodimethane (TCNQ) derivatives has been demonstrated. Nickel(II) and copper(II) complexes of the 20π‐electron antiaromatic R<sub>4</sub>DAP (R<sub>4</sub>DAPM; M = Ni, Cu) were prepared via a metal‐templated cyclization method and used for the reaction with TCNQ. Single electron transfer from R<sub>4</sub>DAPM to TCNQ spontaneously occurred in CH<sub>2</sub>Cl<sub>2</sub> at room temperature to afford the corresponding radical ion pair, [R<sub>4</sub>DAPM<sup>•+</sup>][TCNQ<sup>•−</sup>]. Similarly, R<sub>4</sub>DAPNi reacted with 2,3,5,6‐tetrafluoro‐TCNQ (F<sub>4</sub>TCNQ) to afford [R<sub>4</sub>DAPNi<sup>•+</sup>][F<sub>4</sub>TCNQ<sup>•−</sup>]. The absorption spectra of [R<sub>4</sub>DAPM<sup>•+</sup>][TCNQ<sup>•−</sup>] in the visible–near IR region were almost identical to the superposed spectra of the independently prepared cation‐ and anion‐radical references, indicating negligible π─π orbital interaction between the two radical ions in solution. However, the electron paramagnetic resonance spectrum of [R<sub>4</sub>DAPNi<sup>•+</sup>][F<sub>4</sub>TCNQ<sup>•−</sup>] in CH<sub>2</sub>Cl<sub>2</sub> showed a broad signal attributable to the coupled spin state, suggesting the definite contribution of spin–spin interaction between the two ion‐paired radicals. The results of this study provide valuable information for understanding the fundamental properties of π‐radical ion pairs.

    DOI: 10.1002/ajoc.202500312

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  • Si(IV) complexes of 10,20-diaryl-5,15-diazaporphyrin and 5,10,20-triaryl-5,15-diazaporphyrinoids: Evaluation of charge effect on the optical, redox, and magnetic properties

    Kanta Sasaki, Yui Murata, Hiroya Suzuki, Mao Minoura, Rio Kitakado, Yoshifumi Kimura, Ko Furukawa, Haruyuki Nakano, Yoshihiro Matano

    Journal of Porphyrins and Phthalocyanines   29 ( 03n04 )   467 - 477   2025.4

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    Publishing type:Research paper (scientific journal)   Publisher:World Scientific Pub Co Pte Ltd  

    The central metals in group 14 metalloporphyrins significantly influence the optical, redox, and magnetic properties of the porphyrin [Formula: see text]-electron systems. This study reports the first examples of Si(IV) complexes of 10,20-diaryl-5,15-diazaporphyrin (Ar<sub>2</sub>DAP) and 5,10,20-triaryl-5,15-diazaporphyrin (Ar<sub>3</sub>DAP), designed to explore the effects of meso-nitrogen atoms and net charge on these fundamental properties of the porphyrin ring. Reacting the free base of Ar<sub>2</sub>DAP with HSiCl<sub>3</sub>, followed by metathesis of axial ligands, yielded the corresponding Si(IV) complexes (Ar<sub>2</sub>DAPSiX<sub>2</sub>; X [Formula: see text] OH, F). Copper-catalyzed [Formula: see text]-phenylation of Ar<sub>2</sub>DAPSiF<sub>2</sub> and subsequent redox reactions produced 18[Formula: see text]- and 19[Formula: see text]-electron derivatives of Ar<sub>3</sub>DAPSiF<sub>2</sub>. Nuclear magnetic resonance spectroscopy, cyclic voltammetry, and density functional theory calculations revealed that the diatropic ring-current effects derived from the aromatic 18[Formula: see text]-electron systems of Ar<sub>2</sub>DAPSiX<sub>2</sub> and Ar<sub>3</sub>DAPSiF<sub>2</sub> strongly depend on the net charge and dipole moment of the DAP ligand. All Si(IV) complexes exhibited fluorescence, with Stokes shifts of 120–310 cm[Formula: see text]. Measurements of fluorescence quantum yields and lifetimes indicated that [Formula: see text]-phenylation primarily reduced the nonradiative decay rate constant. These findings provided insights into the influence of net charge on the aromatic character, as well as the optical and redox properties, of six-coordinate Si(IV) complexes of DAP derivatives.

    DOI: 10.1142/s1088424625500397

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  • Intermolecular Toroidal Conjugation: Circularly Stacked 16 π-Planes Formed by Supramolecular Assembly Enabling Cyclic Charge and Energy Delocalization

    Daisuke Sakamaki, Koki Tsubono, Minami Nakamura, Daiki Shimizu, Yasunori Matsui, Hiroshi Ikeda, Ko Furukawa, Hideki Fujiwara

    2025.2

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    Publisher:American Chemical Society (ACS)  

    Toroidal conjugation is a unique way of charge and exciton delocalization via through-space overlap among circularly stacked π-orbitals, but the examples have been limited to intramolecular phenomena where π-planes are arranged around a hub molecule. In this study, we extend this concept to intermolecular phenomena and demonstrate the first example of intermolecular toroidal conjugation in designed systems, in which a circular π-stacked array is formed by molecular self-assembly. X-ray single-crystal analysis unequivocally revealed a toroidal array of 16 π-planes formed by the supramolecular dimerization of phthalocyanines substituted with eight pillar-like diazapentacenes interdigitating their π-pillars. The experimentally determined interplanar distances in the toroidal π-stacking array were close enough to realize through-space conjugation. We investigated the existence of charge and exciton delocalization in the toroidal π-stacking array using various steady-state and time-resolved spectroscopies and found that the positive charge migrated in the toroidal π-stacking array in the cationic and photoexcited states.

    DOI: 10.26434/chemrxiv-2025-hnn6b-v2

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  • Two Approaches to the Synthesis of Redox‐Switchable 5,10,20‐Triaryl‐5,15‐diazaporphyrinoids

    Yui Murata, Keisuke Sudoh, Ko Furukawa, Haruyuki Nakano, Yoshihiro Matano

    Chemistry – An Asian Journal   2025.2

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    DOI: 10.1002/asia.202401370

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  • Sn(IV) Complexes of 5,10,15,20‐Tetraaryl‐5,15‐diazaporphyrinoids: A Promising Platform for Evaluating the 20π‐Electron Antiaromaticity

    Hiroya Suzuki, Mao Minoura, Ko Furukawa, Haruyuki Nakano, Yoshihiro Matano

    Chemistry – A European Journal   31 ( 9 )   2024.12

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    Publishing type:Research paper (scientific journal)   Publisher:Wiley  

    Abstract

    Porphyrinoids in the 20π‐electron state have been extensively studied from the fundamental viewpoint of investigating their structure–antiaromaticity relationships. However, most of the 20π porphyrinoids are highly distorted and unstable in air, which hinder the comprehensive analysis of paratropic ring‐current effects derived from planar π‐electron systems. Herein, we present the first examples of antiaromatic Sn(IV) complexes of 5,10,15,20‐tetraaryl‐5,15‐diazaporphyrinoids (SnX<sub>2</sub>TADAPs), prepared by the complexation of the corresponding freebases with Sn(II) chloride under aerobic conditions and subsequent metathesis of the axial ligands, that show paratropic ring‐current effects. Notably, both neutral 20π‐electron derivatives and 19π‐electron radical cations of SnX<sub>2</sub>TADAP are extremely stable in air owing to the intrinsic electronic effects of the central Sn(IV) unit and meso nitrogen atoms. NMR spectroscopy, cyclic voltammetry, and density functional theory calculations were performed to assess the ring‐current effects and orbital energies of a series of the 20π‐electron SnX<sub>2</sub>TADAPs, and the results reveal that the paratropic ring‐current effects arising from the planar 20π‐electron DAP ring increases with a decrease in the HOMO–LUMO energy gap.

    DOI: 10.1002/chem.202404092

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  • π‐Expansion on a Polycyclic Stable Neutral Radical: Synthesis and Physical Properties of a Benz‐Annulated Trioxotriangulene

    Tsuyoshi Murata, Satsuki Doi, Rina Ishikawa, Ko Furukawa, Yasushi Morita

    Asian Journal of Organic Chemistry   14 ( 3 )   2024.12

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    Abstract

    We report the synthesis of a benz‐annulated derivative of trioxotriangulene (TOT), a fused polycyclic organic neutral radical, and also the investigation on the electronic effects of π‐expansion. The neutral radical species was highly stable under air in both solution and solid states. Quantum chemical calculation suggested that the molecule has a completely planar molecular structure, and the electronic spin is widely delocalized throughout the π‐skeleton while maintaining three‐fold symmetry, which was experimentally supported by electronic spin resonance spectrum. The neutral radical also showed a strong π‐association ability comparable to that of TOT neutral radical derivatives.

    DOI: 10.1002/ajoc.202400690

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  • Spin–spin interaction in a highly stable neutral diradical: σ-boned dimer of trioxotriangulene

    Tsuyoshi Murata, Shusaku Ukai, Sawa Yamaguchi, Ko Furukawa, Yasushi Morita

    Chemistry Letters   53 ( 2 )   2024.2

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    Publishing type:Research paper (scientific journal)   Publisher:Oxford University Press (OUP)  

    Abstract

    A σ-bonded dimer of 4,8,10-trioxotriangulene (TOT) was newly synthesized and its electronic spin structure was characterized. The neutral diradical had a singlet ground state due to the strong antiferromagnetic interaction through the σ-bond. The strong intramolecular interaction within the σ-dimer caused a near-infrared photoabsorption of around 700–1,000 nm, which is close to that of the π-stacked dimer of TOT monoradical.

    DOI: 10.1093/chemle/upae030

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    Other Link: https://academic.oup.com/chemlett/article-pdf/53/2/upae030/56760582/upae030.pdf

  • Improved Synthesis of Free Bases of 5,10,15,20-Tetraaryl-5,15-diazaporphyrinoid for Conversion to Silicon(IV) Complexes

    Hiroya Suzuki, Ko Furukawa, Mao Minoura, Haruyuki Nakano, Yoshihiro Matano

    Bulletin of the Chemical Society of Japan   2023.12

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    <jats:title>Abstract</jats:title>
    <jats:p>We report herein an improved method for the quantitative preparation of free bases of 5,10,15,20-tetraaryl-5,15-diazaporphyrinoid (TADAP) using Me3SiBr–MeOH to treat the corresponding zinc(II) complexes. Metallation of the free base with HSiCl3 followed by Si–X metathesis with SbF3 and redox reactions afforded difluorosilicon(IV) complexes of TADAP.</jats:p>

    DOI: 10.1093/bulcsj/uoad022

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  • Selective hetero-bis-metalation of a <i>cisoid</i> isomer of doubly N-confused dioxohexaphyrin

    Keito Shimomura, Yuma Nakamura, Hiroto Kai, Kyosuke Saito, Ko Furukawa, Shigeki Mori, Masatoshi Ishida, Hiroyuki Furuta

    Journal of Porphyrins and Phthalocyanines   26 ( 12 )   A - H   2022.10

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    Publishing type:Research paper (scientific journal)   Publisher:World Scientific Pub Co Pte Ltd  

    Novel site-selective hetero-copper(II)/zinc(II) complexes of a cisoid-configured doubly N-confused dioxohexaphyrin analog (c-ZnCu-2 and c-CuZn-2) were synthesized and characterized. The resulting heterometal complexes exhibited a unique near-infrared (NIR) absorption feature, and the facile redox-active properties originated from the large 26[Formula: see text]-conjugated structure. The distinct difference between the site-dependent c-ZnCu-2 and c-CuZn-2appeared in the specific structural parameters of the d<sup>9</sup> copper centers in the electron paramagnetic resonance spectra and the Lewis acidity of the zinc centers upon the base-titrations. These complexes have potential for the hetero-metal-containing [Formula: see text]-material applications that respond to the NIR light.

    DOI: 10.1142/s1088424622500456

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  • Synthesis, Electrochemical Behavior, and Catalytic Activity of Cobalt Complexes of 5,10,15,20-Tetraaryl-5,15-diazaporphyrinoids

    Yuna Satoh, Yuta Kudoh, Ko Furukawa, Yoshihiro Matano

    Organic Letters   24 ( 21 )   3839 - 3843   2022.6

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    Publishing type:Research paper (scientific journal)   Publisher:American Chemical Society (ACS)  

    DOI: 10.1021/acs.orglett.2c01411

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  • Synthesis, Optical Properties, and Electrochemical Behavior of 5,10,15,20-Tetraaryl-5,15-diazaporphyrin-Amine Hybrids

    Yuna Satoh, Yutaro Fujita, Naoya Muramatsu, Ko Furukawa, Tadaaki Ikoma, Mao Minoura, Haruyuki Nakano, Yoshihiro Matano

    CHEMPLUSCHEM   86 ( 10 )   1476 - 1486   2021.10

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    DOI: 10.1002/cplu.202100429

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  • Chiral Interlocked Corrole Dimers Directly Linked at Inner Carbon Atoms of Confused Pyrrole Rings

    Yogesh Kumar Maurya, Pingchun Wei, Takahide Shimada, Kazuhisa Yamasumi, Shigeki Mori, Ko Furukawa, Hajime Kusaba, Tatsumi Ishihara, Yongshu Xie, Masatoshi Ishida, Hiroyuki Furuta

    Chemistry – An Asian Journal   16 ( 7 )   743 - 747   2021.4

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    DOI: 10.1002/asia.202100083

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    Other Link: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/asia.202100083

  • A Robust Porphyrin‐Stabilized Triplet Carbon Diradical

    Kaisheng Wang, Pingting Liu, Fenni Zhang, Ling Xu, Mingbo Zhou, Akito Nakai, Kenichi Kato, Ko Furukawa, Takayuki Tanaka, Atsuhiro Osuka, Jianxin Song

    Angewandte Chemie International Edition   60 ( 13 )   7002 - 7006   2021.3

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    DOI: 10.1002/anie.202015356

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    Other Link: https://onlinelibrary.wiley.com/doi/full-xml/10.1002/anie.202015356

  • p-Nitroterphenyl units for near-infrared two-photon uncaging of calcium ions

    Thuy Thi Thu Pham, Satish Jakkampudi, Ko Furukawa, Fung Yu Cheng, Tzu Chau Lin, Yoki Nakamura, Norimitsu Morioka, Manabu Abe

    Journal of Photochemistry and Photobiology A: Chemistry   409   2021.3

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    DOI: 10.1016/j.jphotochem.2021.113154

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  • Doubly Strapped Redox-Switchable 5,10,15,20-Tetraaryl-5,15-diazaporphyrinoids: Promising Platforms for the Evaluation of Paratropic and Diatropic Ring-Current Effects

    Hikari Ochiai, Ko Furukawa, Haruyuki Nakano, Yoshihiro Matano

    Journal of Organic Chemistry   86 ( 3 )   2283 - 2296   2021.2

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    Publishing type:Research paper (scientific journal)  

    DOI: 10.1021/acs.joc.0c02433

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  • TTF-Annulated Silicon Phthalocyanine Oligomers and Their External-Stimuli-Responsive Orientational Ordering

    Yuta Shiina, Yuto Kage, Ko Furukawa, Heng Wang, Hirofumi Yoshikawa, Hiroyuki Furuta, Nagao Kobayashi, Soji Shimizu

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   59 ( 50 )   22721 - 22730   2020.12

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    DOI: 10.1002/anie.202011025

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  • Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds Reviewed

    Chenting Yan, Masato Takeshita, Jun-ya Nakatsuji, Akihiro Kurosaki, Kaoko Sato, Rong Shang, Masaaki Nakamoto, Yohsuke Yamamoto, Yohei Adachi, Ko Furukawa, Ryohei Kishi, Masayoshi Nakano

    CHEMICAL SCIENCE   11 ( 19 )   5082 - 5088   2020.5

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    DOI: 10.1039/d0sc00002g

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  • Cyclophane-Type Chlorin Dimers from Dynamic Covalent Chemistry of 2,18-Porphyrinyl Dicyanomethyl Diradicals

    B. Adinarayana, Kenichi Kato, Daiki Shimizu, Takayuki Tanaka, Ko Furukawa, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   59 ( 11 )   4320 - 4323   2020.3

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    DOI: 10.1002/anie.201914480

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  • Synthesis and optical, magnetic, and electrochemical properties of 5,10,15,20-tetraaryl-5,15-diazaporphyrin - tertiary amine conjugates Reviewed

    Keisuke Sudoh, Yuna Satoh, Ko Furukawa, Haruyuki Nakano, Yoshihiro Matano

    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES   24 ( 1-3 )   286 - 297   2020.1

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    DOI: 10.1142/S1088424619500822

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  • Stable radical versus reversible sigma-bond formation of (porphyrinyl)dicyanomethyl radicals Reviewed

    Adinarayana B, Shimizu Daiki, Furukawa Ko, Osuka Atsuhiro

    CHEMICAL SCIENCE   10 ( 23 )   6007 - 6012   2019.6

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    DOI: 10.1039/c9sc01631g

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  • Synthesis of Redox-switchable 5,15-Dialkyl-10,20-diaryl-5,15-diazaporphyrins and Diversification of their N-Alkyl Groups Reviewed

    Mutoh Mai, Sudoh Keisuke, Furukawa Ko, Minoura Mao, Nakano Haruyuki, Matano Yoshihiro

    ASIAN JOURNAL OF ORGANIC CHEMISTRY   8 ( 3 )   352 - 355   2019.3

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    DOI: 10.1002/ajoc.201900085

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  • Synthesis and properties of redox-switchable zinc complexes of 10,15,20-triaryl-15-aza-5-oxaporphyrin Reviewed

    Sudoh Keisuke, Furukawa Ko, Nakano Haruyuki, Shimizu Soji, Matano Yoshihiro

    HETEROATOM CHEMISTRY   29 ( 5-6 )   2018.12

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    DOI: 10.1002/hc.21456

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  • Stable Face-to-Face Singlet Diradicaloids: Triply Linked Corrole Dimer Gallium(III) Complexes with Two mu-Hydroxo-Bridges Reviewed

    Ooi Shota, Shimizu Daiki, Furukawa Ko, Tanaka Takayuki, Osuka Atsuhiro

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   57 ( 45 )   14916 - 14920   2018.11

  • Stable Face-to-Face Singlet Diradicaloids: Triply Linked Corrole Dimer Gallium(III) Complexes with Two μ -Hydroxo-Bridges Reviewed

    Shota Ooi, Daiki Shimizu, Ko Furukawa, Takayuki Tanaka, Atsuhiro Osuka

    Angewandte Chemie   130 ( 45 )   15132   2018.11

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    DOI: 10.1002/ange.201810200

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  • Mixed valence salts based on carbon-centered neutral radical crystals Reviewed

    T. Murata, C. Yamada, K. Furukawa, Y. Morita

    Commun. Chem.   1   47   2018.9

  • Crystalline functionalized endohedral C-60 metallofullerides Reviewed

    Ayano Nakagawa, Makiko Nishino, Hiroyuki Niwa, Katsuma Ishino, Zhiyong Wang, Haruka Omachi, Ko Furukawa, Takahisa Yamaguchi, Tatsuhisa Kato, Shunji Bandow, Jeremy Rio, Chris Ewels, Shinobu Aoyagi, Hisanori Shinohara

    NATURE COMMUNICATIONS   9   3073   2018.8

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    DOI: 10.1038/s41467-018-05496-8

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  • Rational Synthesis of Antiaromatic 5,15-Dioxaporphyrin and Oxidation into β,β-Linked Dimers Reviewed

    Akihide Nishiyama, Masaya Fukuda, Shigeki Mori, Ko Furukawa, Heike Fliegl, Hiroyuki Furuta, Soji Shimizu

    Angewandte Chemie - International Edition   57 ( 31 )   9728 - 9733   2018.7

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    DOI: 10.1002/anie.201804648

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  • A Stable Trimethylenemethane Triplet Diradical Based on a Trimeric Porphyrin Fused pi-System Reviewed

    K. Kato, K. Furukawa, A. Osuka

    Angew. Chem. Int. Ed.   57 ( 30 )   9491 - 9494   2018.7

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    DOI: 10.1002/anie.201804644

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  • Redox switchable 19 pi and 18 pi 5,10,20-triaryl-5,15-diazaporphyrinoid-nickel(II) complexes Reviewed

    K. Sudoh, T. Hatakeyama, K. Furukawa, H. Nakano, Y. Matano

    J. Porphyrins and Phthalocyanines   22 ( 7 )   542 - 551   2018.7

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    DOI: 10.1142/S1088424618500529

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  • Metalation Control of Open-Shell Character in meso-meso Linked Porphyrin meso-Oxy Radical Dimers Reviewed

    Yuta Jun-i, Norihito Fukui, Ko Furukawa, Atsuhiro Osuka

    Chemistry - A European Journal   24 ( 7 )   1528 - 1532   2018.2

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Wiley-VCH Verlag  

    DOI: 10.1002/chem.201705769

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  • Porphyrin-Based Air-Stable Helical Radicals Reviewed

    Kenichi Kato, Ko Furukawa, Tadashi Mori, Atsuhiro Osuka

    Chemistry - A European Journal   24 ( 3 )   572 - 575   2018.1

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    DOI: 10.1002/chem.201705291

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  • Programmable arrangement of metal ions in a cofacially stacked assembly of porphyrinoids toward molecular tags Reviewed

    Nozomi Mihara, Yasuyuki Yamada, Ko Furukawa, Tatsuhisa Kato, Kentaro Tanaka

    Dalton Transactions   47 ( 20 )   7044 - 7049   2018

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    DOI: 10.1039/c8dt01334a

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  • Bis-Copper(II)/π-Radical Multi-Heterospin System with Non-innocent Doubly N-Confused Dioxohexaphyrin(1.1.1.1.1.0) Ligand Reviewed

    Kazuhisa Yamasumi, Keiichi Nishimura, Yutaka Hisamune, Yusuke Nagae, Tomoki Uchiyama, Kazutaka Kamitani, Tomoyasu Hirai, Maiko Nishibori, Shigeki Mori, Satoru Karasawa, Tatsuhisa Kato, Ko Furukawa, Masatoshi Ishida, Hiroyuki Furuta

    Chemistry - A European Journal   23 ( 61 )   15322 - 15326   2017.11

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    DOI: 10.1002/chem.201704321

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  • Syntheses, Properties, and Catalytic Activities of Metal(II) Complexes and Free Bases of Redox-Switchable 20 pi, 19 pi, and 18 pi 5,10,15,20-Tetraaryl-5,15-diazaporphyrinoids Reviewed

    Keisuke Sudoh, Takaharu Satoh, Toru Amaya, Ko Furukawa, Mao Minoura, Haruyuki Nakano, Yoshihiro Matano

    CHEMISTRY-A EUROPEAN JOURNAL   23 ( 64 )   16364 - 16373   2017.11

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  • Thienylquinonoidal Porphyrins and Hexaphyrins with Singlet Diradical Ground States Reviewed

    Koji Naoda, Daiki Shimizu, Jun Oh Kim, Ko Furukawa, Dongho Kim, Atsuhiro Osuka

    CHEMISTRY-A EUROPEAN JOURNAL   23 ( 37 )   8969 - 8979   2017.7

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    DOI: 10.1002/chem.201701355

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  • Stable Subporphyrin meso-Aminyl Radicals without Resonance Stabilization by a Neighboring Heteroatom Reviewed

    Daiki Shimizu, Ko Furukawa, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   56 ( 26 )   7435 - 7439   2017.6

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    DOI: 10.1002/anie.201703097

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  • Fullerene C-70 as a Nanoflask that Reveals the Chemical Reactivity of Atomic Nitrogen Reviewed

    Yuta Morinaka, Rui Zhang, Satoru Sato, Hidefumi Nikawa, Tatsuhisa Kato, Ko Furukawa, Michio Yamada, Yutaka Maeda, Michihisa Murata, Atsushi Wakamiya, Shigeru Nagase, Takeshi Akasaka, Yasujiro Murata

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   56 ( 23 )   6488 - 6491   2017.6

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    DOI: 10.1002/anie.201701158

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  • Stable Ni-II Porphyrin meso-Oxy Radical with a Quartet Ground State Reviewed

    Cosima Staehler, Daiki Shimizu, Kota Yoshida, Ko Furukawa, Rainer Herges, Atsuhiro Osuka

    CHEMISTRY-A EUROPEAN JOURNAL   23 ( 30 )   7217 - 7220   2017.5

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    DOI: 10.1002/chem.201701354

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  • Design and Synthesis of a Caged Carboxylic Acid with a Donor-pi-Donor Coumarin Structure: One-photon and Two-photon Uncaging Reactions Using Visible and Near-Infrared Lights Reviewed

    Youhei Chitose, Manabu Abe, Ko Furukawa, Jhe-Yi Ling, Tzu-Chau Lin, Claudine Katan

    ORGANIC LETTERS   19 ( 10 )   2622 - 2625   2017.5

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    DOI: 10.1021/acs.orglett.7b00957

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  • Oxidation of allenes bearing 1,8-diphenoxy or diaryloxyacridene moieties Reviewed

    Shin-ichi Fuku-en, Junki Yamamoto, Ko Furukawa, Daisuke Hashizume, Naomi Kawata, Yohsuke Yamamoto

    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY   30 ( 4 )   e3665   2017.4

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    DOI: 10.1002/poc.3665

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  • Nitrogen-Bridged Metallodiazaporphyrin Dimers: Synergistic Effects of Nitrogen Bridges and meso-Nitrogen Atoms on Structure and Properties Reviewed

    Masahiro Kawamata, Takuma Sugai, Mao Minoura, Yasuhisa Maruyama, Ko Furukawa, Cole Holstrom, Victor N. Nemykin, Haruyuki Nakano, Yoshihiro Matano

    CHEMISTRY-AN ASIAN JOURNAL   12 ( 7 )   816 - 821   2017.4

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    DOI: 10.1002/asia.201700204

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  • Highly planar diarylamine-fused porphyrins and their remarkably stable radical cations Reviewed

    Norihito Fukui, Wonhee Cha, Daiki Shimizu, Juwon Oh, Ko Furukawa, Hideki Yorimitsu, Dongho Kim, Atsuhiro Osuka

    CHEMICAL SCIENCE   8 ( 1 )   189 - 199   2017.1

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    DOI: 10.1039/c6sc02721k

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  • Syntheses, Properties, and Catalytic Activities of Metal(II) Complexes and Free Bases of Redox-Switchable 20π, 19π, and 18π 5,10,15,20-Tetraaryl-5,15-diazaporphyrinoids Reviewed International journal

    Keisuke Sudoh, Takaharu Satoh, Toru Amaya, Ko Furukawa, Mao Minoura, Haruyuki Nakano, Yoshihiro Matano

    Chemistry-A European Journal   23 ( 64 )   16364 - 16373   2017

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    In spite of significant advances in redox-active porphyrin-based materials and catalysts, little attention has been paid to 20π and 19π porphyrins because of their instability in air. Here we report the meso-modification of 5,10,15,20-tetraarylporphyrin with two nitrogen atoms, which led to redox-switchable 20π, 19π, and 18π 5,10,15,20-tetraaryl-5,15-diazaporphyrinoids (TADAPs). Three kinds of metal(II) complexes and free bases of TADAP were prepared by the metal-templated annulation of the corresponding metal-bis(dipyrrin) complexes. The inductive and resonance effects of the meso-nitrogen atoms on the aromatic, optical, electrochemical, and magnetic properties of the entire TADAP π-systems were assessed by using various spectroscopic measurements and density functional theory calculations. The aromaticity and π-π* electronic transition energies of the TADAPs varied considerably, and were shown to be dependent on the oxidation states of the π-systems. In contrast to the isoelectronic 5,10,15,20-tetraarylporphyrin derivatives, the 20π and 19π TADAPs were chemically stable under air. In particular, the 19π TADAP radical cations were extremely stable towards dioxygen, moisture, and silica gel. This reflected the low-lying singly occupied molecular orbitals of their π-systems and the efficient delocalization of their unshared electron spin. The capability of MgTADAP to catalyze aerobic biaryl formation from aryl Grignard reagents was demonstrated, which presumably involved a 19π/20π redox cycle.

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  • Nitrogen-Bridged Metallodiazaporphyrin Dimers: Synergistic Effects of Nitrogen Bridges and meso-Nitrogen Atoms on Structure and Properties Reviewed International journal

    Masahiro Kawamata, Takuma Sugai, Mao Minoura, Yasuhisa Maruyama, Ko Furukawa, Cole Holstrom, Victor N. Nemykin, Haruyuki Nakano, Yoshihiro Matano

    Chemistry-An Asian Journal   12 ( 7 )   816 - 821   2017

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    NH-bridged and pyrazine-fused metallodiazaporphyrin dimers have been prepared from nickel(II) and copper(II) complexes of 3-amino-5,15-diazaporphyrin by Pd-catalyzed C-N cross-coupling and oxidative dimerization reactions, respectively. The synergistic effects of the nitrogen bridges and meso-nitrogen atoms play major roles in enhancing the light-harvesting properties and delocalization of an electron spin over the entire π-skeletons of the metallodiazaporphyrin dimers.

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  • Design, Synthesis, and Reaction of pi-Extended Coumarin-based New Caged Compounds with Two-photon Absorption Character in the Near-IR Region Reviewed

    Youhei Chitose, Manabu Abe, Ko Furukawa, Claudine Katan

    CHEMISTRY LETTERS   45 ( 10 )   1186 - 1188   2016.10

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    DOI: 10.1246/cl.160586

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  • Design and Synthesis of a 4-Nitrobromobenzene Derivative Bearing an Ethylene Glycol Tetraacetic Acid Unit for a New Generation of Caged Calcium Compounds with Two-Photon Absorption Properties in the Near-IR Region and Their Application in Vivo Reviewed

    Satish Jakkampudi, Manabu Abe, Naomitsu Komori, Ryukichi Takagi, Ko Furukawa, Claudine Katan, Wakako Sawada, Noriko Takahashi, Haruo Kasai

    ACS Omega   1 ( 2 )   193 - 201   2016.8

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    DOI: 10.1021/acsomega.6b00119

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  • Spontaneous Formation of an Air-Stable Radical upon the Direct Fusion of Diphenylmethane to a Triarylporphyrin Reviewed

    Kenichi Kato, Wonhee Cha, Juwon Oh, Ko Furukawa, Hideki Yorimitsu, Dongho Kim, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   55 ( 30 )   8711 - 8714   2016.7

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    DOI: 10.1002/anie.201602683

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  • meso-to-meso Sulfide- and Disulfide-Bridged Subporphyrin Dimers Reviewed

    Graeme Copley, Daiki Shimizu, Juwon Oh, Jooyoung Sung, Ko Furukawa, Dongho Kim, Atsuhiro Osuka

    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY   0 ( 11 )   1977 - 1981   2016.4

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    DOI: 10.1002/ejoc.201600285

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  • Redox-Switchable 20-, 19-, and 18-Electron 5,10,15,20-Tetraaryl-5,15-diazaporphyrinoid Nickel(II) Complexes Reviewed

    Takaharu Satoh, Mao Minoura, Haruyuki Nakano, Ko Furukawa, Yoshihiro Matano

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   55 ( 6 )   2235 - 2238   2016.2

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    DOI: 10.1002/anie.201510734

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  • Isolation of Hypervalent Group-16 Radicals and Their Application in Organic-Radical Batteries Reviewed

    Yasuyuki Imada, Hideyuki Nakano, Ko Furukawa, Ryohei Kishi, Masayoshi Nakano, Hitoshi Maruyama, Masaaki Nakamoto, Akira Sekiguchi, Masahiro Ogawa, Toshiaki Ohta, Yohsuke Yamamoto

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   138 ( 2 )   479 - 482   2016.1

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    DOI: 10.1021/jacs.5b10774

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  • Design and synthesis of a new chromophore, 2-(4-nitrophenyl)benzofuran, for two-photon uncaging using near-IR light Reviewed

    Naomitsu Komori, Satish Jakkampudi, Ryusei Motoishi, Manabu Abe, Kenji Kamada, Ko Furukawa, Claudine Katan, Wakako Sawada, Noriko Takahashi, Haruo Kasai, Bing Xue, Takayoshi Kobayashi

    CHEMICAL COMMUNICATIONS   52 ( 2 )   331 - 334   2016

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    DOI: 10.1039/c5cc07664a

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  • Triarylporphyrin meso-Oxy Radicals: Remarkable Chemical Stabilities and Oxidation to Oxophlorin pi-Cations Reviewed

    Daiki Shimizu, Juwon Oh, Ko Furukawa, Dongho Kim, Atsuhiro Osuka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   137 ( 49 )   15584 - 15594   2015.12

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    DOI: 10.1021/jacs.5b11223

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  • Microscopic evidence of a metallic state in the one-pot organic conductor ammonium tetrathiapentalene carboxylate Reviewed

    Toshikazu Nakamura, Ko Furukawa, Takeshi Terauchi, Yuka Kobayashi

    PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS   9 ( 8 )   480 - 484   2015.8

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    DOI: 10.1002/pssr.201510206

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  • Comparison of electronic effects of beta-aryl substituents on optical and electrochemical properties of 5,15-diazaporphyrin pi-systems Reviewed

    Satoshi Omomo, Ko Furukawa, Haruyuki Nakano, Yoshihiro Matano

    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES   19 ( 6 )   775 - 785   2015.6

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    DOI: 10.1142/S1088424615500509

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  • Creation of Superheterojunction Polymers via Direct Polycondensation: Segregated and Bicontinuous Donor-Acceptor pi-Columnar Arrays in Covalent Organic Frameworks for Long-Lived Charge Separation Reviewed

    Shangbin Jin, Mustafa Supur, Matthew Addicoat, Ko Furukawa, Long Chen, Toshikazu Nakamura, Shunichi Fukuzumi, Stephan Irle, Donglin Jiang

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   137 ( 24 )   7817 - 7827   2015.6

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    DOI: 10.1021/jacs.5b03553

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  • meso-Hydroxysubporphyrins: A Cyclic Trimeric Assembly and a Stable meso-Oxy Radical Reviewed

    Daiki Shimizu, Juwon Oh, Ko Furukawa, Dongho Kim, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   54 ( 22 )   6613 - 6617   2015.5

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    DOI: 10.1002/anie.201501592

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  • Lowering the Reduction Potential of a Boron Compound by Means of the Substituent Effect of the Boryl Group: One-Electron Reduction of an Unsymmetrical Diborane(4) Reviewed

    Hiroki Asakawa, Ka-Ho Lee, Ko Furukawa, Zhenyang Lin, Makoto Yamashita

    CHEMISTRY-A EUROPEAN JOURNAL   21 ( 11 )   4267 - 4271   2015.3

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    DOI: 10.1002/chem.201406609

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  • Oxidation of an allene compound bearing 1,8-dichloroacridene moieties and photolysis of the halogenated allene compound for the generation of triplet carbenes Reviewed

    Shin-ichi Fuku-en, Ko Furukawa, Takahiro Sasamori, Norihiro Tokitoh, Manabu Abe, Yohsuke Yamamoto

    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY   28 ( 2 )   79 - 87   2015.2

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    DOI: 10.1002/poc.3398

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  • Optical, Electrochemical, and Magnetic Properties of Pyrrole- and Thiophene-Bridged 5,15-Diazaporphyrin Dimers Reviewed

    Satoshi Omomo, Yasuhisa Maruyama, Ko Furukawa, Taniyuki Furuyama, Haruyuki Nakano, Nagao Kobayashi, Yoshihiro Matano

    CHEMISTRY-A EUROPEAN JOURNAL   21 ( 5 )   2003 - 2010   2015.1

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    DOI: 10.1002/chem.201405482

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  • A Stable Organic π-Radical of a Zinc(II)-Copper(I)-Zinc(II) Complex of Decaphyrin Reviewed

    Tanaka, Y., Yoneda, T., Furukawa, K., Koide, T., Mori, H., Tanaka, T., Shinokubo, H., Osuka, A.

    Angewandte Chemie - International Edition   54 ( 37 )   10908 - 10911   2015

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    DOI: 10.1002/anie.201505130

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  • Phenalenyl-fused porphyrins with different ground states Reviewed

    Wangdong Zeng, Sangsu Lee, Minjung Son, Masatoshi Ishida, Ko Furukawa, Pan Hu, Zhe Sun, Dongho Kim, Jishan Wu

    CHEMICAL SCIENCE   6 ( 4 )   2427 - 2433   2015

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    DOI: 10.1039/c4sc03866e

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  • Acid/base-regulated reversible electron transfer disproportionation of N-N linked bicarbazole and biacridine derivatives Reviewed

    Palash Pandit, Koji Yamamoto, Toshikazu Nakamura, Katsuyuki Nishimura, Yuki Kurashige, Takeshi Yanai, Go Nakamura, Shigeyuki Masaoka, Ko Furukawa, Yumi Yakiyama, Masaki Kawano, Shuhei Higashibayashi

    CHEMICAL SCIENCE   6 ( 7 )   4160 - 4173   2015

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    DOI: 10.1039/c5sc00946d

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  • Persistent antimony- and bismuth-centered radicals in solution Reviewed

    Shintaro Ishida, Fumiya Hirakawa, Ko Furukawa, Kenji Yoza, Takeaki Iwamoto

    Angewandte Chemie International Edition   53 ( 42 )   11172 - 11176   2014.7

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    DOI: 10.1002/anie.201405509

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  • Photoelectric Covalent Organic Frameworks: Converting Open Lattices into Ordered Donor-Acceptor Heterojunctions Reviewed

    Long Chen, Ko Furukawa, Jia Gao, Atsushi Nagai, Toshikazu Nakamura, Yuping Dong, Donglin Jiang

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   136 ( 28 )   9806 - 9809   2014.7

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    DOI: 10.1021/ja502692w

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  • Covalently Linked 5,15-Diazaporphyrin Dimers: Promising Scaffolds for a Highly Conjugated Azaporphyrin pi System Reviewed

    Yoshihiro Matano, Daisuke Fujii, Tarou Shibano, Ko Furukawa, Tomohiro Higashino, Haruyuki Nakano, Hiroshi Imahori

    CHEMISTRY-A EUROPEAN JOURNAL   20 ( 12 )   3342 - 3349   2014.3

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    DOI: 10.1002/chem.201304626

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  • Indolo[2,3-b]carbazoles with tunable ground states: how Clar's aromatic sextet determines the singlet biradical character Reviewed

    Ding Luo, Sangsu Lee, Bin Zheng, Zhe Sun, Wangdong Zeng, Kuo-Wei Huang, Ko Furukawa, Dongho Kim, Richard D. Webster, Jishan Wu

    CHEMICAL SCIENCE   5 ( 12 )   4944 - 4952   2014

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    DOI: 10.1039/c4sc01843e

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  • Near-IR absorbing nickel(II) porphyrinoids prepared by regioselective insertion of silylenes into antiaromatic nickel(II) norcorrole Reviewed

    Fukuoka, T., Uchida, K., Sung, Y.M., Shin, J.-Y., Ishida, S., Lim, J.M., Hiroto, S., Furukawa, K., Kim, D., Iwamoto, T., Shinokubo, H.

    Angewandte Chemie - International Edition   53 ( 6 )   1506 - 1509   2014

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    DOI: 10.1002/anie.201309921

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  • A kinetically blocked 1,14:11,12-dibenzopentacene: a persistent triplet diradical of a non-Kekule polycyclic benzenoid hydrocarbon Reviewed

    Yuan Li, Kuo-Wei Huang, Zhe Sun, Richard D. Webster, Zebing Zeng, Wangdong Zeng, Chunyan Chi, Ko Furukawa, Jishan Wu

    CHEMICAL SCIENCE   5 ( 5 )   1908 - 1914   2014

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    DOI: 10.1039/c3sc53015a

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  • A stable metallic state of (TTPCOO)(2)NH4 with a mobile dopant Reviewed

    Takeshi Terauchi, Satoshi Sumi, Yuka Kobayashi, Toshikazu Nakamura, Ko Furukawa, Yohji Misaki

    CHEMICAL COMMUNICATIONS   50 ( 54 )   7111 - 7113   2014

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    DOI: 10.1039/c4cc00678j

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  • Redox Modulation of para-Phenylenediamine by Substituted Nitronyl Nitroxide Groups and Their Spin States Reviewed

    Akihiro Ito, Ryohei Kurata, Daisuke Sakamaki, Soichiro Yano, Yosuke Kono, Yoshiaki Nakano, Ko Furukawa, Tatsuhisa Kato, Kazuyoshi Tanaka

    JOURNAL OF PHYSICAL CHEMISTRY A   117 ( 48 )   12858 - 12867   2013.12

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    DOI: 10.1021/jp4095613

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  • Meta - Para -linked octaaza[18]cyclophanes and their polycationic states Reviewed

    Daisuke Sakamaki, Akihiro Ito, Ko Furukawa, Tatsuhisa Kato, Kazuyoshi Tanaka

    Journal of Organic Chemistry   78 ( 7 )   2947 - 2956   2013.4

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    DOI: 10.1021/jo3026884

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  • X-ray observation of a helium atom and placing a nitrogen atom inside He@C-60 and He@C-70 Reviewed

    Yuta Morinaka, Satoru Sato, Atsushi Wakamiya, Hidefumi Nikawa, Naomi Mizorogi, Fumiyuki Tanabe, Michihisa Murata, Koichi Komatsu, Ko Furukawa, Tatsuhisa Kato, Shigeru Nagase, Takeshi Akasaka, Yasujiro Murata

    NATURE COMMUNICATIONS   4   1554   2013.3

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    DOI: 10.1038/ncomms2574

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  • Charge Dynamics in A Donor-Acceptor Covalent Organic Framework with Periodically Ordered Bicontinuous Heterojunctions Reviewed

    Shangbin Jin, Xuesong Ding, Xiao Feng, Mustafa Supur, Ko Furukawa, Seiya Takahashi, Matthew Addicoat, Mohamed E. El-Khouly, Toshikazu Nakamura, Stephan Irle, Shunichi Fukuzumi, Atsushi Nagai, Donglin Jiang

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   52 ( 7 )   2017 - 2021   2013

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    DOI: 10.1002/anie.201209513

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  • Organometallic ionic liquids from alkyloctamethylferrocenium cations: thermal properties, crystal structures, and magnetic properties Reviewed

    Yusuke Funasako, Takashi Inagaki, Tomoyuki Mochida, Toshihiro Sakurai, Hitoshi Ohta, Ko Furukawa, Toshikazu Nakamura

    DALTON TRANSACTIONS   42 ( 23 )   8317 - 8327   2013

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    DOI: 10.1039/c3dt00084b

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  • Large pore donor-acceptor covalent organic frameworks Reviewed

    Shangbin Jin, Ko Furukawa, Matthew Addicoat, Long Chen, Seiya Takahashi, Stephan Irle, Toshikazu Nakamura, Donglin Jiang

    CHEMICAL SCIENCE   4 ( 12 )   4505 - 4511   2013

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    DOI: 10.1039/c3sc52034j

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  • Simultaneous Control of Carriers and Localized Spins with Light in Organic Materials Reviewed

    Toshio Naito, Tomoaki Karasudani, Keishi Ohara, Takahiro Takano, Yukihiro Takahashi, Tamotsu Inabe, Ko Furukawa, Toshikazu Nakamura

    ADVANCED MATERIALS   24 ( 46 )   6153 - 6157   2012.12

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    DOI: 10.1002/adma.201203153

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  • Switchable Intermolecular Communication in a Four-Fold Rotaxane Reviewed

    Y. Yamada, M. Okamoto, K. Furukawa, T. Kato, K. Tanaka

    Angew. Chem. Int. Ed.   51   709 - 713   2012.1

  • A Polymacrocyclic Oligoarylamine with a Pseudobeltane Motif: Towards a Cylindrical Multispin System Reviewed

    Daisuke Sakamaki, Akihiro Ito, Ko Furukawa, Tatsuhisa Kato, Motoo Shiro, Kazuyoshi Tanaka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   51 ( 51 )   12776 - 12781   2012

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    DOI: 10.1002/anie.201206831

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  • Physical properties of a molecular conductor (BEDT-TTF)(2)I-3 nanohybridized with silica nanoparticles by dry grinding Reviewed

    Akira Funabiki, Hiroki Sugiyama, Tomoyuki Mochida, Kunihiro Ichimura, Takashi Okubo, Ko Furukawa, Toshikazu Nakamura

    RSC ADVANCES   2 ( 3 )   1055 - 1060   2012

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    DOI: 10.1039/c1ra00590a

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  • 1,3,5-Benzenetriamine Double- and Triple-Decker Molecules Reviewed

    Daisuke Sakamaki, Akihiro Ito, Kazuyoshi Tanaka, Ko Furukawa, Tatsuhisa Kato, Motoo Shiro

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   51 ( 33 )   8281 - 8285   2012

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    DOI: 10.1002/anie.201203451

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  • 13C NMR study of the magnetic properties of the quasi-one-dimensional conductor (TMTTF)2SbF6 Reviewed

    F. Iwase, K. Sugiura, K. Furukawa, T. Nakamura

    Physical Review B - Condensed Matter and Materials Physics   84 ( 11 )   2011.9

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    DOI: 10.1103/PhysRevB.84.115140

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  • C-13 NMR study of the magnetic properties of the quasi-one-dimensional conductor (TMTTF)(2)SbF6 Reviewed

    F. Iwase, K. Sugiura, K. Furukawa, T. Nakamura

    PHYSICAL REVIEW B   84 ( 11 )   115140   2011.9

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    DOI: 10.1103/PhysRevB.84.115140

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  • Gd-2@C79N: Isolation, Characterization, and Monoadduct Formation of a Very Stable Heterofullerene with a Magnetic Spin State of S=15/2 Reviewed

    Wujun Fu, Jianyuan Zhang, Tim Fuhrer, Hunter Champion, Ko Furukawa, Tatsuhisa Kato, James E. Mahaney, Brian G. Burke, Keith A. Williams, Kenneth Walker, Caitlyn Dixon, Jiechao Ge, Chunying Shu, Kim Harich, Harry C. Dorn

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   133 ( 25 )   9741 - 9750   2011.6

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    DOI: 10.1021/ja202011u

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  • Ferromagnetic Spin Coupling between Endohedral Metallofullerene La@C-82 and a Cyclodimeric Copper Porphyrin upon Inclusion Reviewed

    Fatin Hajjaj, Kentaro Tashiro, Hidefumi Nikawa, Naomi Mizorogi, Takeshi Akasaka, Shigeru Nagase, Ko Furukawa, Tatsuhisa Kato, Takuzo Aida

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   133 ( 24 )   9290 - 9292   2011.6

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    DOI: 10.1021/ja203491s

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  • Structural investigation of the spin-singlet phase in (TMTTF)2I Reviewed

    Ko Furukawa, Koichi Sugiura, Fumitatsu Iwase, Toshikazu Nakamura

    Physical Review B - Condensed Matter and Materials Physics   83 ( 18 )   2011.5

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    DOI: 10.1103/PhysRevB.83.184419

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  • Structural investigation of the spin-singlet phase in (TMTTF)(2)I Reviewed

    Ko Furukawa, Koichi Sugiura, Fumitatsu Iwase, Toshikazu Nakamura

    PHYSICAL REVIEW B   83 ( 18 )   184419   2011.5

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    DOI: 10.1103/PhysRevB.83.184419

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  • Photoinduced Triplet States of Photoconductive TTF Derivatives Including a Fluorescent Group Reviewed

    Ko Furukawa, Yasuo Sugishima, Hideki Fujiwara, Toshikazu Nakamura

    CHEMISTRY LETTERS   40 ( 3 )   292 - 294   2011.3

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    DOI: 10.1246/cl.2011.292

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  • Magnetic memory based on magnetic alignment of a paramagnetic ionic liquid near room temperature Reviewed

    Yusuke Funasako, Tomoyuki Mochida, Takashi Inagaki, Takahiro Sakurai, Hitoshi Ohta, Ko Furukawa, Toshikazu Nakamura

    CHEMICAL COMMUNICATIONS   47 ( 15 )   4475 - 4477   2011

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    DOI: 10.1039/c0cc05820c

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  • Novel Type of Career Generated System: Magnetic Investigations of TTF-Based Self-Doped Hydrogen-Bonding Conductor Reviewed

    Ko Furukawa, Toshikazu Nakamura, Yuka Kobayashi, Takashi Ogura

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   79 ( 5 )   053701   2010.5

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    DOI: 10.1143/JPSJ.79.053701

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  • Spin-Dynamics in Vicinity of Spin-Gap Phase Transition for Organic Conductor (TMTTF)(2)X Reviewed

    Ko Furukawa, Toshifumi Hara, Toshikazu Nakamura

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   79 ( 4 )   043702   2010.4

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    DOI: 10.1143/JPSJ.79.043702

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  • Submillimeter and millimeter wave ESR measurements of frustrated triangular lattice substance InMnO3 Reviewed

    N. Matsumi, S. Okubo, M. Fujisawa, T. Sakurai, H. Ohta, K. Furukawa, T. Nakamura, H. Kikuchi

    2009 34TH INTERNATIONAL CONFERENCE ON INFRARED, MILLIMETER, AND TERAHERTZ WAVES, VOLS 1 AND 2   574 - +   2009

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  • The Molecular Solid from a Viewpoint of Photo-Induced Phase Transition and Related Phenomena

    NAKAMURA Toshikazu, FURUKAWA Ko

    rle   36 ( 6 )   339 - 342   2008.6

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    In this paper, we introduce the electronic states and electronic properties of molecular solid especially charge transfer salts and radical salts in the aspect of photo-induced phase transition and related phenomena. The characteristic features of molecular solid, which deeply related to photo-induced phase transition, are as following:(1) low-dimensional electronic states originated from anisotropic interaction,(2) strong electronic correlation induced by low carrier concentration,(3) lattice softness which causes competition of electronic phases with pressure and thermal contraction,(4) internal-freedom, namely, molecular motions. We propose strategies for exploring possible candidates for forthcoming materials with photo-induced phase transition.

    DOI: 10.2184/lsj.36.339

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    Other Link: https://jlc.jst.go.jp/DN/JALC/00315542851?from=CiNii

  • Possible one-dimensional helical conductor: Hexa-peri-hexabenzocoronene nanotube Reviewed

    Toshifumi Hara, Ko Furukawa, Toshikazu Nakamura, Yohei Yamamoto, Atsuko Kosaka, Wusong Jin, Takanori Fukushima, Takuzo Aida

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   77 ( 3 )   034710   2008.3

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    DOI: 10.1143/JPSJ.77.034710

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  • Redistribution of charge in the proximity of the spin-Peierls transition: C-13 NMR investigation of (TMTTF)(2)PF6 Reviewed

    Toshikazu Nakamura, Ko Furukawa, Toshifumi Hara

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   76 ( 6 )   064715   2007.6

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    DOI: 10.1143/JPSJ.76.064715

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  • AF-like ground state of Mn-DNA and charge transfer from Fe to base-pi-band in Fe-DNA Reviewed

    Kenji Mizoguchi, Shunsuke Tanaka, Masaya Ojima, Sayaka Sano, Mai Nagatori, Hirokazu Sakamoto, Yuki Yonezawa, Yuji Aoki, Hideyuki Sato, Kou Furukawa, Toshikazu Nakamura

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   76 ( 4 )   043801   2007.4

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    DOI: 10.1143/JPSJ.76.043801

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  • C-13 NMR analyses of successive charge ordering in (TMTTF)(2)ReO4 Reviewed

    T Nakamura, K Furukawa, T Hara

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   75 ( 1 )   13707   2006.1

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    DOI: 10.1143/JPSJ.75.013707

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  • Ferromagnetic resonance studies on Ni80Fe20 wire arrays Reviewed

    A. Maeda, M. Susaki, K. Furukawa, T. Takui

    INTERMAG 2006 - IEEE International Magnetics Conference   934   2006

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    DOI: 10.1109/INTMAG.2006.374965

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  • Deuteration effect and possible origin of the charge-ordering transition of (TMTTF)(2)X Reviewed

    K Furukawa, T Hara, T Nakamura

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   74 ( 12 )   3288 - 3294   2005.12

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    DOI: 10.1143/JPSJ.74.3288

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  • The effect of deuteration on the transition into a charge ordered state of (TMTTF)(2)X salts Reviewed

    F Nad, P Monceau, T Nakamura, K Furukawa

    JOURNAL OF PHYSICS-CONDENSED MATTER   17 ( 41 )   L399 - L406   2005.10

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    DOI: 10.1088/0953-8984/17/41/L01

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  • High frequency EPR of the Mn-cluster in single crystals of cyanobacterial photosystem II Reviewed

    Asako Kawamori, Jian-Ren Shen, Hiroyuki Mino, Ko Furukawa, Hideto Matsuoka, Tatsuhisa Kato

    Photosynthesis: Fundamental Aspects to Global Perspectives   406 - 408   2005

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  • Electrochemical polymerization of terthiophene-fullerene derivative and its optical property for organic solar cells Reviewed

    M Morita, K Furukawa, Y Murata, T Yamazaki, K Komatsu, N Maruyama, T Yamao, S Fujita

    2005 PACIFIC RIM CONFERENCE ON LASERS AND ELECTRO-OPTICS   516 - 517   2005

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  • Importance of fourth-order zero-field splitting terms in random-orientation EPR spectra of Eu(II)-doped strontium aluminate Reviewed

    H Matsuoka, K Furukawa, K Sato, D Shiomi, Y Kojima, K Hirotsu, N Furuno, T Kato, T Takui

    JOURNAL OF PHYSICAL CHEMISTRY A   107 ( 51 )   11539 - 11546   2003.12

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    DOI: 10.1021/jp030819

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  • Pseudo-octahedral high-spin Co(II) complexes with orbitally degenerate ground states as studied by SQUID and ESR spectroscopy

    H Matsuoka, T Yoshida, K Kubono, K Sato, D Shiomi, K Furukawa, T Kato, K Yokoi, T Takui

    SYNTHETIC METALS   137 ( 1-3 )   1213 - 1214   2003.4

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    DOI: 10.1016/S0379-6779(02)01047-0

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  • Oxidative direct coupling of metalloporphyrins

    Y Nakamura, N Aratani, A Tsuda, A Osuka, K Furukawa, T Kato

    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES   7 ( 4-5 )   264 - 269   2003

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  • Low-dimensional molecule-based magnets with hydrogen-bonded network

    M Sakai, J Toyoda, M Mitsumi, K Nakasuji, K Furukawa, D Shiomi, K Sato, T Takui

    SYNTHETIC METALS   121 ( 1-3 )   1776 - 1777   2001.3

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    DOI: 10.1016/S0379-6779(00)00742-6

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  • A Novel Spin Wave from Low-Dimensional Superlatticce of Microstructured Ferromagnetic Thin Films

    K. Furukawa, D. Shiomi, K. Sato, T. Takui, K. Itoh, A. Maeda, M. Kume, K. Shibata, I. Nakatani

    Mol. Cryst. Liq. Cryst.   335   163 - 172   1999

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Books

  • EPR of Radicals in Solids: Trends in Methods and Applications

    Kluwer Academic Publishers  2003  ( ISBN:1402012497

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  • EPR of Radicals in Solids: Trends in Methods and Applications

    Kluwer Academic Publishers  2003  ( ISBN:1402012497

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MISC

  • Clarification of Mechanism of Fuel Cell using Titanium Oxide Catalyst for ESR Spectroscopy

    遠藤夏実, 石原顕光, 太田健一郎, 村瀬典子, LEE Kunchan, 古川貢

    電子スピンサイエンス学会年会講演要旨集   56th   2017

  • Gd, Y金属が2個内包されたフラーレン類のESRスペクトル

    山口貴久, 中鳥なつみ, 三谷拓示, 菊地耕一, 兒玉健, 古川貢, 加藤立久

    第50回フラーレン・ナノチューブ・グラフェン総合シンポジウム   2016

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  • ジアザポルフィリン二量体の磁気特性

    丸山裕久, 大桃理志, 川俣昌弘, 古川貢, 俣野善博

    電子スピンサイエンス学会年会講演要旨集   55th   2016

  • 時間分解ESRによるドナー・アクセプター型COFのスピンダイナミクス解明研究 Invited

    古川 貢

    機器センターたより   7   80 - 83   2015.4

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  • Gd,Y金属が2個内包されたフラーレン類のESR測定

    山口貴久, 中鳥なつみ, 三谷拓示, 菊地耕一, 兒玉健, 古川貢, 加藤立久, 加藤立久

    電子スピンサイエンス学会年会講演要旨集   54th   2015

  • ベンズイミダゾリウム塩の微結晶薄膜における光キャリアダイナミクス

    内田賢, 脇川祐介, 三浦智明, 古川貢, 根本一輝, 長谷川英悦, 生駒忠昭, 生駒忠昭, 生駒忠昭

    電子スピンサイエンス学会年会講演要旨集   54th   2015

  • 磁性イオンを使用した共有結合性有機骨格構造(COF)のスピンダイナミクス

    渡邉聖也, 小野健太, 古川貢, 古川貢, JIN Shanbin, JIANG Donling, JIANG Donling

    電子スピンサイエンス学会年会講演要旨集   54th   2015

  • ヘテロール架橋ジアザポルフィリン二量体の磁気特性

    丸山裕久, 大桃理志, 川俣昌弘, 古川貢, 俣野善弘

    電子スピンサイエンス学会年会講演要旨集   54th   2015

  • トリアンギュレン骨格に二個のジシアノメチレン部位を組み込んだ電子スピン非局在型安定中性ラジカルの構造と物性

    安藤沙也伽, 西田辰介, 西田辰介, 村田剛志, 村田剛志, 古川貢, 森田靖, 森田靖

    電子スピンサイエンス学会年会講演要旨集   54th   2015

  • Photoconduction Mechanism Investigation of Covalent Organic Framework (COF) Materials by Time-Resolved ESR Spectroscopy

    Furukawa K., Takahashi S., Nakamura T., Jin Shangbin, Jiang Donglin

    Meeting abstracts of the Physical Society of Japan   68 ( 2 )   749 - 749   2013.8

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    DOI: 10.11316/jpsgaiyo.68.2.4.0_749_1

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  • 有機固体のアドバンスドESRによる機能性解明の研究 Invited

    古川 貢

    電子スピンサイエンス   11   18 - 23   2013.4

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    J-GLOBAL

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  • 27pXF-5 Magnetic Resonance Investigation of ^1H Dynamics in TTFCOONH_4 and Its Analogs

    Nakamura T., Furukawa K., Terauchi T., Kobayashi Y., Misaki Y.

    Meeting abstracts of the Physical Society of Japan   68 ( 1 )   937 - 937   2013.3

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    DOI: 10.11316/jpsgaiyo.68.1.4.0_937_1

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  • 受賞者の声(電子スピンサイエンス学会奨励賞) Invited

    古川 貢

    分子研レターズ   67   11   2013

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  • ドナー・アクセプター型COFのスピンダイナミクス

    古川貢, JIN Shanbin, CHEN Long, JIANG Donglin, JIANG Donglin, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   52nd   2013

  • プリオンタンパク質凝集体のQバンド電子スピン二重共鳴法(Q-band DEER)による構造解析

    稲波修, 山盛徹, 安井博宣, 堀内基広, 平岡和佳子, 古川貢, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   52nd   2013

  • 自己ドープ型有機導体TTFCOONH4塩及び類縁体の物性研究

    中村敏和, 中村敏和, 古川貢, 古川貢, 古川貢, 寺内毅, 小林由佳, 御崎洋二

    電子スピンサイエンス学会年会講演要旨集   52nd   2013

  • 21aEB-7 Magnetic Resonance Investigation of Electronic States in TTPCOO Derivatives

    Furukawa K., Nakamura T., Terauchi T., Kobayashi Y., Misaki Y.

    Meeting abstracts of the Physical Society of Japan   67 ( 2 )   801 - 801   2012.8

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  • 光化学系IIにおける酸素発生中心Mnクラスターの多周波EPR研究

    松岡秀人, SHEN Jian-Ren, 伊東信哉, 古川貢, 中村敏和, 山内清語

    電子スピンサイエンス学会年会講演要旨集   51st   2012

  • 時間分解ESR法による共有結合性有機骨格構造の光伝導性解明

    高橋誠弥, 高橋誠弥, JIN Shangbin, 古川貢, 古川貢, JIANG Donglin, JIANG Donglin, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   51st   2012

  • 拡張した光誘起伝導性物質(EDT-TTF)BTAのスピンダイナミクス

    古川貢, 古川貢, 辻本啓次郎, 藤原秀紀, 高橋誠弥, 高橋誠弥, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   51st   2012

  • イオン液体中におけるニトロキシドのg値と超微細結合定数のWバンドEPR測定

    荒牧龍太, 三宅祐輔, 河合明雄, 古川貢, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   51st   2012

  • 新規三重項カルベンの合成の試みとESR測定

    福圓真一, 山本陽介, 古川貢

    電子スピンサイエンス学会年会講演要旨集   51st   2012

  • 23pTG-3 Structural Study on spin-Peierls Phases in (TMTTF)_2PF_6 by Synchrotron X-ray Diffraction

    Maki Sachiko, Nishibori Eiji, Mizoguchi Yuji, Oku Kenta, Satake Ryuta, Sawa Hiroshi, Furukawa Ko, Nakamura Toshikazu

    Meeting abstracts of the Physical Society of Japan   66 ( 2 )   884 - 884   2011.8

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    DOI: 10.11316/jpsgaiyo.66.2.4.0_884_1

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  • 23pTG-4 Investigation for Magnetic property and crystla structural of (TMTTF)_2SCN

    Sugiura Koichi, Furukawa Ko, Nakamura Toshikazu

    Meeting abstracts of the Physical Society of Japan   66 ( 2 )   884 - 884   2011.8

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    DOI: 10.11316/jpsgaiyo.66.2.4.0_884_2

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  • 26pTB-3 Electronic property and magnetic network in (TMTTF)_2SCN : Structural investigation of re-entrant antiferromagnetic phases

    Sugiura Koichi, Furukawa Ko, Nakamura Toshikazu

    Meeting abstracts of the Physical Society of Japan   66 ( 1 )   869 - 869   2011.3

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    DOI: 10.11316/jpsgaiyo.66.1.4.0_869_3

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  • 光誘起伝導性TTF誘導体の時間分解ESR研究

    古川貢, 古川貢, 辻本啓二郎, 藤原秀紀, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   50th   2011

  • パルスQ-bandシステムを利用した生体系物質のPELDORによる距離測定の試み

    古川貢, 古川貢, 平岡和佳子, 稲波修, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   50th   2011

  • Preparation and Characterization of spirobi(triarylamine)s containing localized spin units

    Kohigashi Sho, Sakamaki Daisuke, Ito Akihiro, Tanaka Kazuyoshi, Furukawa Ko, Kato Tatsuhisa

    Abstracts of Symposium on Physical Organic Chemistry   2011   164 - 164   2011

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    In this study, we have prepared spirobi(triarylamine)s containing nitroxide groups as localized spin units. In the oxidized states for the spiro molecules, we expected intramolecular ferromagnetic interaction between the localized spins and the delocalized spins. There exists the possibility that the radical cation and di(radical cation) of the spiro molecules are in spin quartet and quintet states, respectively, as a consequence of the intramolecular ferromagnetic interaction. We will report in detail on the electronic structures of the oxidized species on the basis of spectroscopic measurements.

    DOI: 10.11494/kisoyuki.2011.0.164.0

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  • Spin Coupling between Endohedral Metallofullerene La@C82 and a Cyclodimeric Copper Porphyrin

    Tashiro Kentaro, Hajjaj Fatin, Nikawa Hidefumi, Mizorogi Naomi, Akasaka Takeshi, Nagase Shigeru, Furukawa Ko, Kato Tatsuhisa, Aida Takuzo

    Abstracts of Symposium on Physical Organic Chemistry   2011   66 - 66   2011

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    The cyclic host cyclo-[PCu]2 carrying two covalently connected Cu(II) porphyrin units can accommodate La@C82, a paramagnetic endohedral metallofullerene, in its cavity to form the inclusion complex, which can be transformed into the caged complex by ring-closing olefin metathesis of its side-chain olefinic termini. On the basis of electron spin resonance (ESR) and electron spin transient nutation (ESTN) studies, the former complex is the first ferromagnetically coupled inclusion complex featuring La@C82, whereas the latter is ferrimagnetic.

    DOI: 10.11494/kisoyuki.2011.0.66.0

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  • Preparation and Characterization of Hexaazaparacyclophane with Anthracene Units

    Kinoshita Mariko, Sakamaki Daisuke, Ito Akihiro, Tanaka Kazuyoshi, Furukawa Ko, Kato Tatsuhisa

    Abstracts of Symposium on Physical Organic Chemistry   2011   349 - 349   2011

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    Molecular nano-devices are regarded as one of the next-generation electronic devices, and therefore, many kinds of molecular parts have been prepared to realize desired functionalities. Especially, it is interesting to control the electronic spin in molecular parts, because it will lead to spintronic devices. Here, we report the preparation of a novel hexaazaparacyclophane, in which three para-phenylenediamine units and three anthracene moieties are alternately connected, and moreover, the electronic structure has been clarified on the basis of several spectroscopic measurements. As a result, it has been suggested that intramolecular ferromagnetic interactions occur in the tricationic species of this molecule.

    DOI: 10.11494/kisoyuki.2011.0.349.0

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  • Non-Kekulé Singlet Biradicaloid form meso-Free Hexaphyrin

    Koide Taro, Furukawa Ko, Shinokubo Hiroshi, Takui Takeji, Osuka Atsuhiro

    Abstracts of Symposium on Physical Organic Chemistry   2011   372 - 372   2011

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    We reported a stable meso-unsubstituted hexaphyrin, meso-free hexaphyrin, and its metal complexes. meso-Diketo hexaphyrin which is remarkably stable and can be manipulated like usual organic molecules was synthesized by the demetalation of the Ni complex. Its structure was determined by X-ray diffraction analysis to be meso,meso-diketo, non-Kekulé biradicaloid hexaphyrin. Singlet ground-state with non-Kekulé structure was revealed by ESR and SQUID measurements. The optical and electrochemical properties will be also reported.

    DOI: 10.11494/kisoyuki.2011.0.372.0

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  • Synthesis and electronic properties of aromatic amines stacked through m-phenylene pillars

    SAKAMAKI DAISUKE, ITO AKIHIRO, TANAKA KAZUYOSHI, FURUKAWA KOU, KATO TATSUHISA

    Abstracts of Symposium on Physical Organic Chemistry   2011   457 - 457   2011

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    We prepared novel multi-layered aromatic amines. These molecules are the first examples of layered cyclophanes that consist only of aromatic amines. The electronic properties of these molecules were investigated by using cyclic voltammetry, UV-Vis-NIR absorption, and ESR method.

    DOI: 10.11494/kisoyuki.2011.0.457.0

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  • Electronic Properties of One-dimensional Organic Conductors, (TMTTF)_2X in P-T Phase Diagram

    NAKAMURA Toshikazu, IWASE Fumitatsu, FURUKAWA Ko, SUGIURA Koich

    51   209 - 209   2010.10

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  • 24aRB-3 Charge Density Study on Charge Ordering Phases in (TMTTF)_2PF_6 by Synchrotron X-ray Diffraction

    Maki Sachiko, Nishibori Eiji, Aoyagi Shinobu, Sawa Hiroshi, Furukawa Ko, Nakamura Toshikazu

    Meeting abstracts of the Physical Society of Japan   65 ( 2 )   792 - 792   2010.8

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    DOI: 10.11316/jpsgaiyo.65.2.4.0_792_3

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  • 24aRB-2 Crystal structural study of modified generalized phase diagram of TMT CF family

    Furukawa Ko, Sugiura Koichi, Nakamura Toshikazu

    Meeting abstracts of the Physical Society of Japan   65 ( 2 )   792 - 792   2010.8

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    DOI: 10.11316/jpsgaiyo.65.2.4.0_792_2

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  • X-ray irradiation effect on magnetic properties of Dimer-Mott insulators: kappa-(BEDT-TTF)(2)Cu[N(CN)(2)]Cl and beta &apos;-(BEDT-TTF)(2)ICl2

    Naoki Yoneyama, Takahiko Sasaki, Norio Kobayashi, Ko Furukawa, Toshikazu Nakamura

    PHYSICA B-CONDENSED MATTER   405 ( 11 )   S244 - S246   2010.6

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  • A Stable Non-Kekule Singlet Biradicaloid from meso-Free 5,10,20,25-Tetrakis(Pentafluorophenyl)-Substituted [26]Hexaphyrin(1.1.1.1.1.1)

    Taro Koide, Ko Furukawa, Hiroshi Shinokubo, Jae-Yoon Shin, Kil Suk Kim, Dongho Kim, Atsuhiro Osuka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 21 )   7246 - +   2010.6

  • Ground states and the critical behavior in the quasi-one-dimensional complexes (TMTTF)(2)[(AsF6)(x)(SbF6)(1-x)]

    F. Iwase, K. Sugiura, K. Furukawa, T. Nakamura

    PHYSICAL REVIEW B   81 ( 24 )   245126   2010.6

  • Novel Type of Career Generated System: Magnetic Investigations of TTF-Based Self-Doped Hydrogen-Bonding Conductor

    Ko Furukawa, Toshikazu Nakamura, Yuka Kobayashi, Takashi Ogura

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   79 ( 5 )   053701/1-4   2010.5

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  • Spin-Dynamics in Vicinity of Spin-Gap Phase Transition for Organic Conductor (TMTTF)(2)X

    Ko Furukawa, Toshifumi Hara, Toshikazu Nakamura

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   79 ( 4 )   043702/1-4   2010.4

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  • 20pGT-7 ^<13>C NMR study on (TMTTF)_2SbF_6 under high pressures

    Iwase F., Sugiura K., Furukawa K., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   65 ( 1 )   862 - 862   2010.3

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    DOI: 10.11316/jpsgaiyo.65.1.4.0_862_2

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  • 20pGT-6 Relationship between crystal structure and electronic phase for organic conductors, (TMTTF)_2X

    Furukawa Ko, Iwase Fumitatsu, Sugiura Koichi, Nakamura Toshikazu

    Meeting abstracts of the Physical Society of Japan   65 ( 1 )   862 - 862   2010.3

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    DOI: 10.11316/jpsgaiyo.65.1.4.0_862_1

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  • Fully pi-Conjugated Helices from Oxidative Cleavage of meso-Aryl-Substituted Expanded Porphyrins

    Shohei Saito, Ko Furukawa, Atsuhiro Osuka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   132 ( 7 )   2128 - +   2010.2

  • C-13 NMR Investigation of Low-temperature States in One-dimensional Organic Cation Radical Salt, (TMTTF)(2)SbF6, under High Pressures

    Fumitatsu Iwase, Ko Furukawa, Toshikazu Nakamura

    INTERNATIONAL CONFERENCE ON HIGH PRESSURE SCIENCE AND TECHNOLOGY, JOINT AIRAPT-22 AND HPCJ-50   215   012063/1-4   2010

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  • Bithiophene Porphyrin Hybrid Nanorings

    Kenta Osawa, Jianxin Song, Ko Furukawa, Hiroshi Shinokubo, Naoki Aratani, Atsuhiro Osuka

    CHEMISTRY-AN ASIAN JOURNAL   5 ( 4 )   764 - 767   2010

  • Magnetic Properties of X-ray Irradiated Organic Mott Insulator κ-(BEDT-TTF)2Cu[N(CN)2]Cl

    N. Yoneyama, K. Furukawa, T. Nakamura, T. Sasaki, N. Kobayashi

    J. Phys. Soc. Jpn.   79   063706/1-4   2010

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  • para-Phenylene-Bridged Spirobi(triarylamine) Dimer with Four Perpendicularly Linked Redox-Active pi Systems

    Akihiro Ito, Kazuhira Hata, Kensuke Kawamoto, Yasukazu Hirao, Kazuyoshi Tanaka, Motoo Shiro, Ko Furukawa, Tatsuhisa Kato

    CHEMISTRY-A EUROPEAN JOURNAL   16 ( 35 )   10866 - 10878   2010

  • Spin-Gap Observation in the Triangular Lattice Antiferromagnet InMnO(3) by High-Field ESR

    H. Ohta, N. Matsumi, S. Okubo, M. Fujisawa, T. Sakurai, H. Kikuchi, K. Furukawa, T. Nakamura

    INTERNATIONAL CONFERENCE ON MAGNETISM (ICM 2009)   200   022041/1-4   2010

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  • A Stable Organic Radical Delocalized on a Highly Twisted pi System Formed Upon Palladium Metalation of a Mobius Aromatic Hexaphyrin

    Harapriya Rath, Sumito Tokuji, Naoki Aratani, Ko Furukawa, Jong Min Lim, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   49 ( 8 )   1489 - 1491   2010

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  • 有機導体に対する先端ESR研究

    古川貢, 古川貢, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   49th   2010

  • 非対称アニオンをもつ有機導体(TMTTF)<sub>2</sub>SCNの電子状態と結晶構造

    杉浦晃一, 古川貢, 中村敏和, 古川貢, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   49th   2010

  • 光誘起伝導性TTF誘導体のスピンダイナミクス研究

    古川貢, 古川貢, 辻本啓次郎, 杉島泰雄, 藤原秀紀, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   49th   2010

  • Anomalous Temperature Dependence of g-Tensor in Organic Conductor, (TMTTF)(2)X (X = Br, PF6, and SbF6)

    Ko Furukawa, Toshifumi Hara, Toshikazu Nakamura

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   78 ( 10 )   104713/1-6   2009.10

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  • Electronic Properties of a TMTTF-Family Salt, (TMTTF)(2)TaF6: New Member Located on the Modified Generalized Phase-Diagram

    Fumitatsu Iwase, Koichi Sugiura, Ko Furukawa, Toshikazu Nakamura

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   78 ( 10 )   104717/1-7   2009.10

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  • 27aYC-7 ^<13>C-NMR study on (TMTTF)_2SbF_6 under high pressures

    Iwase F., Sugiura K., Furukawa K., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   64 ( 2 )   768 - 768   2009.8

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  • 27aYC-8 ^1H-NMR studies of (TMTTF)_2SbF_6 under high pressure

    Satsukawa H., Hiraki K., Takahashi T., Furukawa K., Nakumura T., Matsumoto T., Kimata M., Terashima T., Uji S.

    Meeting abstracts of the Physical Society of Japan   64 ( 2 )   768 - 768   2009.8

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  • 27aYC-4 Investigation for Electronic Property of Quasi-one-dimensional Organic Conductor, (TMTTF)_2I

    Sugiura K., Furukawa K., Iwase F., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   64 ( 2 )   767 - 767   2009.8

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  • Homo- and Heterobismetal Complexes of 5-Hydroxy-10,15,25,30-tetrakis(pentafluorophenyl)-Substituted [26]Hexaphyrin(1.1.1.1.1.1)

    Taro Koide, Gengo Kashiwazaki, Ko Furukawa, Atsuhiro Osuka

    INORGANIC CHEMISTRY   48 ( 11 )   4595 - 4597   2009.6

  • 28pTF-3 Submillimeter wave ESR measurements of Kagome lattice antiferromagnet Cu_3V_2O_7(OH)_2・2H_2O II

    Kondo K., Zhang W., Okubo S., Ohta H., Fujisawa M., Sakurai T., Furukawa M., Nakamura T., Yoshida H., Hiroi Z.

    Meeting abstracts of the Physical Society of Japan   64 ( 1 )   493 - 493   2009.3

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  • 28pYF-12 NMR Investigation for (TMTTF)_2TaF_6

    Iwase F., Sugiura K., Furukawa K., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   64 ( 1 )   835 - 835   2009.3

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  • 28pYF-11 Electronic property of (TMTTF)_2SbF_6 under high pressures

    Iwase F., Sugiura K., Furukawa K., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   64 ( 1 )   835 - 835   2009.3

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  • 27pTG-15 High field ESR measurements of the triangular lattice antiferromagnet InMnO_3 II

    Matsumi N., Okubo S., Fujisawa M., Ohta H., Furukawa M., Nakamura T., Kikuchi H.

    Meeting abstracts of the Physical Society of Japan   64 ( 1 )   457 - 457   2009.3

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  • High-spin polycationic states of an alternate meta-para-linked oligoarylamine incorporating two macrocycles

    Daisuke Sakamaki, Akihiro Ito, Ko Furukawa, Tatsuhisa Kato, Kazuyoshi Tanaka

    CHEMICAL COMMUNICATIONS   ( 30 )   4524 - 4526   2009

  • 機能性材料のスピンダイナミクス研究

    古川 貢, 中村敏和

    機器センターたより   2   50 - 54   2009

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  • 有機導体・分子性固体の多彩な競合電子相-多周波数・パルス磁気共鳴による物性研究

    中村敏和, 古川貢, 岩瀬文達

    まぐね   5   224 - 228   2009

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  • C-13 NMR Investigation of Re-entrant Antiferromagnetic States of (TMTTF)(2)SbF6

    Toshikazu Nakamura, Fumitatsu Iwase, Hidetaka Satsukawa, Ko Furukawa, Toshihiro Takahashi

    25TH INTERNATIONAL CONFERENCE ON LOW TEMPERATURE PHYSICS (LT25), PART 4   150   042137/1-4   2009

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  • T-Shaped Three-Coordinate Copper(II) Heptaphyrin Complexes

    Shohei Saito, Ko Furukawa, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   48 ( 43 )   8086 - 8089   2009

  • アルキルオクタメチルフェロセニウム塩の相変化に基づく磁性転換現象

    舟浴佑典, 稲垣尭, 持田智行, 櫻井敬博, 太田仁, 古川貢, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   48th   2009

  • 施錠可能なホストに包摂されるフラーレンゲストの電子スピンスイッチング

    HAJJAJ Fatin, 田代健太郎, 二川秀史, 赤阪健, 古川貢, 加藤立久, 相田卓三

    電子スピンサイエンス学会年会講演要旨集   48th   2009

  • テトララジカルのスピン整列に及ぼす置換基効果

    安倍学, 中村岳史, 前田倫, 古川貢, 加藤立久

    電子スピンサイエンス学会年会講演要旨集   48th   2009

  • 一次元電子系における競合反強磁性相の微視的研究

    杉浦晃一, 岩瀬文達, 古川貢, 古川貢, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   48th   2009

  • 強磁場ESRによる三角格子反強磁性体InMnO<sub>3</sub>のスピンギャップ観測

    太田仁, 太田仁, 松見成朗, 大久保晋, 藤澤真士, 櫻井敬博, 菊池彦光, 古川貢, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   48th   2009

  • 光誘起伝導性物質TTF誘導体のスピンダイナミクス研究

    古川貢, 古川貢, 杉島泰雄, 藤原秀紀, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   48th   2009

  • カゴメ格子反強磁性体の多周波数ESR測定によるスピンフラストレーションとスピン液体の研究

    大久保晋, ZHANG W., 友尾水樹, 近藤健太, 藤澤真士, 櫻井敬博, 太田仁, 太田仁, 太田仁, 古川貢, 中村敏和, 木俣基, 宇治進也, 竹端寛治, 今中康貴, 高増正, 菊池彦光, 岡本佳比古, 吉田紘行, 廣井善二

    電子スピンサイエンス学会年会講演要旨集   48th   2009

  • S=1/2カゴメ格子反強磁性体Cu<sub>3</sub>V<sub>2</sub>O<sub>7</sub>(OH)<sub>2</sub>・2H<sub>2</sub>Oの低周波ESR測定

    近藤健太, 友尾水樹, ZHANG W., 櫻井敬博, 藤澤真士, 大久保晋, 太田仁, 古川貢, 中村敏和, 木俣基, 竹端寛治, 今中康貴, 高増正, 宇治進也, 吉田紘行, 岡本佳比古, 廣井善二

    電子スピンサイエンス学会年会講演要旨集   48th   2009

  • 単結晶光化学系II複合体の高周波CW/パルスESR研究

    松岡秀人, SHEN Jian-Ren, 西山圭, 大庭裕範, 山内清語, 古川貢, 中村敏和, 河盛阿佐子

    電子スピンサイエンス学会年会講演要旨集   48th   2009

  • Synthesis and characterizations of free base and Cu(II) complex of a porphyrin sheet

    Yasuyuki Nakamura, Naoki Aratani, Ko Furukawa, Atsuhiro Osuka

    Tetrahedron   64 ( 50 )   11433 - 11439   2008.12

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  • 21pTC-9 ^<13>C NMR studies of the electronic state in the proximity of the phase boundary between antiferromagnetic and spin-Peierls in (TMTTF)_2X

    Iwase F., Sugiura K., Furukawa K., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   63 ( 2 )   756 - 756   2008.8

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  • 21pTC-2 Electronic Properties of 1D 1/3-filled system, (TMTTF)_3Ta_2F_<11>

    Sugiura K., Furukawa K., Iwase F., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   63 ( 2 )   755 - 755   2008.8

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  • 20aTB-10 Electronic States of (TTF-Cl_y)Au_x II

    Sakamoto H., Mizoguchi K., Naka K., Nakamura T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   63 ( 2 )   730 - 730   2008.8

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  • 21aTC-13 Electronic and Magnetic Properties of 1D self-assembled Cu-complex

    Nakamura Toshikazu, Furukawa Ko, Chen Long, Ishizuka Tomoya, Jiang Donglin

    Meeting abstracts of the Physical Society of Japan   63 ( 2 )   746 - 746   2008.8

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  • Possible one-dimensional helical conductor: Hexa-peri-hexabenzocoronene nanotube

    Toshifumi Hara, Ko Furukawa, Toshikazu Nakamura, Yohei Yamamoto, Atsuko Kosaka, Wusong Jin, Takanori Fukushima, Takuzo Aida

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   77 ( 3 )   034710/1-6   2008.3

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  • 23pTF-2 Multi-frequency-ESR measurement of Pd(dmit)_2 salt

    Yoshida T., Sakurai T., Ohmichi E., Okubo S., Ohta H., Kato R., Nakamura T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   63 ( 1 )   802 - 802   2008.2

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  • 23pWG-9 Electronic States of (TTF-Cl_y)Au_x

    Sakamoto H., Mizoguchi K., Naka K., Nakamura T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   63 ( 1 )   811 - 811   2008.2

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  • 26pTF-2 Electoronic States of Alkali-TCNQ by ESR III

    Fujita Y., Kazama S., Mizoguchi K., Sakamoto H., Nakamura T., Furukawa K., Hasegawa T.

    Meeting abstracts of the Physical Society of Japan   63 ( 1 )   846 - 846   2008.2

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  • 26aWB-3 ESR study on β'-, β"-(BEDT-TTF)(TCNQ)

    Kato A., Kihara T., Mizoguchi K., Sakamoto H., Konno S., Kazama S., Taniguchi H., Nakamura T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   63 ( 1 )   844 - 844   2008.2

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  • Multi-frequency ESR studies on low-dimensional antiferromagnets, zeta-(BEDT-TTF)(2)PF6(THF) and gamma-(BEDT-TTF)(2)PF6

    Keisuke Maeda, Toshifumi Hara, Ko Furukawa, Toshikazu Nakamura

    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN   81 ( 1 )   84 - 90   2008.1

  • Trimacrocyclic arylamine and its polycationic states

    Akihiro Ito, Yuko Yamagishi, Koji Fukui, Syuuzi Inoue, Yasukazu Hirao, Ko Furukawa, Tatsuhisa Kato, Kazuyoshi Tanaka

    CHEMICAL COMMUNICATIONS   ( 48 )   6573 - 6575   2008

  • 13C NMR study of the chemical pressure effect in (TMTTF)2[(AsF6)x(SbF6)1-x] (x > 0.5)

    F. Iwase, K. Sugiura, K. Furukawa, T. Nakamura

    J. Phys.: Conf. Series   132   012015/1-4   2008

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  • An N-substituted aza[1(4)] metacyclophane tetracation: a spin-quintet tetraradical with four para-phenylenediamine-based semi-quinone moieties

    Akihiro Ito, Syuuzi Inoue, Yasukazu Hirao, Ko Furukawa, Tatsuhisa Kato, Kazuyoshi Tanaka

    CHEMICAL COMMUNICATIONS   ( 28 )   3242 - 3244   2008

  • A Stable Radical Species from Facile Oxygenation of meso-Free 5,10,20,25-Tetrakis(pentafluorophenyl)-Substituted [26]Hexaphyrin(1.1.1.1.1.1)

    Taro Koide, Gengo Kashiwazaki, Masaaki Suzuki, Ko Furukawa, Min-Chul Yoon, Sung Cho, Dongho Kim, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   47 ( 50 )   9661 - 9665   2008

  • 低次元有機導体(TMTTF)<sub>3</sub>Ta<sub>2</sub>F<sub>11</sub>および(TMTTF)<sub>2</sub>TaF<sub>6</sub>のESR研究

    杉浦晃一, 古川貢, 古川貢, 岩瀬文達, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   47th   2008

  • 光化学系II反応中心の多周波EPR研究

    松岡秀人, SHEN Jian-Ren, 西山圭, 古川貢, 中村敏和, 山内清語, 河盛阿佐子

    電子スピンサイエンス学会年会講演要旨集   47th   2008

  • 三角格子反強磁性体EtMe<sub>3</sub>P[Pd(dmit)<sub>2</sub>]<sub>2</sub>の多周波ESR

    櫻井敬博, 吉田喬久, 大久保晋, 太田仁, 太田仁, 古川貢, 中村敏和, 加藤礼三

    電子スピンサイエンス学会年会講演要旨集   47th   2008

  • 色素増感太陽電池のスピンダイナミクス研究

    古川貢, 古川貢, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   47th   2008

  • Implementation of molecular spin quantum computing by pulsed ENDOR technique: Direct observation of quantum entanglement and spinor

    Kazunobu Sato, Robabeh Rahimi, Nobuyuki Mori, Shinsuke Nishida, Kazuo Toyota, Daisuke Shiomi, Yasushi Morita, Akira Ueda, Shuichi Suzuki, Ko Furukawa, Toshikazu Nakamura, Masahiro Kitagawa, Kazuhiro Nakasuji, Mikio Nakahara, Hideyuki Hara, Patrick Carl, Peter Hoefer, Takeji Takui

    PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES   40 ( 2 )   363 - 366   2007.12

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  • Polaron dynamics in two types of long oligothiophenes revealed by Q- and X-band ESR measurements

    Katsuichi Kanemoto, Ko Furukawa, Nobukazu Negishi, Yoshio Aso, Tetsuo Otsubo

    PHYSICAL REVIEW B   76 ( 15 )   155205   2007.10

  • 21aRA-12 Electoronic States of Alkali-TCNQ by ESR II

    Fujita Y., Kazama S., Mizoguchi K., Sakamoto H., Nakamura T., Furukawa K., Hasegawa T.

    Meeting abstracts of the Physical Society of Japan   62 ( 2 )   845 - 845   2007.8

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  • 22pRB-9 Pulsed・ESR study of Spin-dynamics of (TMTTF)_2X

    Furukawa K., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   62 ( 2 )   875 - 875   2007.8

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  • Redistribution of charge in the proximity of the spin-Peierls transition: C-13 NMR investigation of (TMTTF)(2)PF6

    Toshikazu Nakamura, Ko Furukawa, Toshifumi Hara

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   76 ( 6 )   064715/1-5   2007.6

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  • AF-like ground state of Mn-DNA and charge transfer from Fe to base-pi-band in Fe-DNA

    Kenji Mizoguchi, Shunsuke Tanaka, Masaya Ojima, Sayaka Sano, Mai Nagatori, Hirokazu Sakamoto, Yuki Yonezawa, Yuji Aoki, Hideyuki Sato, Kou Furukawa, Toshikazu Nakamura

    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN   76 ( 4 )   043801/1-4   2007.4

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  • 18aRA-12 Electronic States of β"-(BEDT-TTF)(TCNQ) by ESR with various frequency

    Kihara T., Sakamoto H., Mizoguchi K., Konno S., Kazama S., Taniguchi H., Nakamura T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   62 ( 1 )   805 - 805   2007.2

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  • 18aRA-11 ESR study on β'-(BEDT-TTF)(TCNQ)

    Kato A., Kihara T., Sakamoto H., Mizoguchi K., Konno S., Kazama S., Taniguchi H., Nakamura T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   62 ( 1 )   805 - 805   2007.2

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  • 20pRJ-9 Electoronic States of Alkali-TCNQ by ESR

    Fujita Y., Kazama S., Mizoguchi K., Sakamoto H., Kihara T., Katou A., Nakamura T., Furukawa K., Hasegawa T.

    Meeting abstracts of the Physical Society of Japan   62 ( 1 )   853 - 853   2007.2

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  • 19pRJ-5 Investigation of Charge and Spin Dynamics in (TMTTF)_2AsF_6

    Nakamura T., Satsukawa H., Furukawa K., Takahashi T.

    Meeting abstracts of the Physical Society of Japan   62 ( 1 )   835 - 835   2007.2

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  • 19pRJ-4 Low-Temeperature Electronic States of (TMTTF)_2ClO_4

    Satsukawa H., Furukawa K., Nakamura T., Takahashi T.

    Meeting abstracts of the Physical Society of Japan   62 ( 1 )   835 - 835   2007.2

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  • 19pRJ-3 Charge Order and Antiferromagnetic Fluctuation in (TMTTF)_2SbF_6

    Satsukawa H., Nakamura T., Furukawa K., Takahashi T.

    Meeting abstracts of the Physical Society of Japan   62 ( 1 )   835 - 835   2007.2

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  • 19pRJ-7 Pulse-ESR study of Spin-dynamics of MEM-TCNQ

    Furukawa K., Hara T., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   62 ( 1 )   836 - 836   2007.2

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  • Synthesis of calix[3]dipyrrins by a modified Lindsey protocol

    Mitsunori Inoue, Chusaku Ikeda, Yuji Kawata, Sundararaman Venkatraman, Ko Furukawa, Atsuhiro Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   46 ( 13 )   2306 - 2309   2007

  • Manipulating the through-space spin-spin interaction of organic radicals in the confined cavity of a self-assembled cage

    Koji Nakabayashi, Masaki Kawano, Tatsuhisa Kato, Ko Furukawa, Shin-ichi Ohkoshi, Toshiya Hozumi, Makoto Fujita

    CHEMISTRY-AN ASIAN JOURNAL   2 ( 1 )   164 - 170   2007

  • W-band ESR investigations of electronic properties in molecular based solids

    Journal of the Japan Society of Infraed Science and Technolog   16 ( 2 )   40 - 44   2007

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  • Synthesis and biradicaloid character of doubly linked corrole dimers

    Satoru Hiroto, Ko Furukawa, Hiroshi Shinokubo, Atsuhiro Osuka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   128 ( 38 )   12380 - 12381   2006.9

  • 25aYF-7 Electron spin dynamics in doped long oligothiophenes

    Kanemoto K., Furukawa K., Negishi N., Aso Y., Otsubo T.

    Meeting abstracts of the Physical Society of Japan   61 ( 2 )   689 - 689   2006.8

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  • 23pYF-8 Pulsed-ESR Study of Spin Dynamics of Organic Conductor: TMTTF Salts

    Furukawa K., Hara T., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   61 ( 2 )   672 - 672   2006.8

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  • 23pYF-9 The Antiferromagnetic state of (TMTTF)_2SbF_6: cw-NMR

    Satsukawa H., Hiraki K., Takahashi T., Nakumura T., Furukawa K., Brown S.E.

    Meeting abstracts of the Physical Society of Japan   61 ( 2 )   672 - 672   2006.8

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  • 23pYF-7 ^<13>C NMR Study of Low Temperature Charge Distribution for (TMTTF)_2PF_6

    Nakamura T., Hara T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   61 ( 2 )   672 - 672   2006.8

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  • 23aYB-2 Electronic States of β"-(BEDT-TTF)(TCNQ)

    Kihara T., Sakamoto H., Mizoguchi K., Konno S., Kazama S., Taniguchi H., Nakamura T., Furukawa K., Hiraoka M.

    Meeting abstracts of the Physical Society of Japan   61 ( 2 )   659 - 659   2006.8

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  • 23aYB-6 A low frequency ESR study on β'-(BEDT-TTF)(TCNQ) under Pressure

    Kato A., Kihara T., Sakamoto H., Mizoguchi K., Konno S., Kazama S., Taniguchi H., Nakamura T., Furukawa K., Hiraoka M.

    Meeting abstracts of the Physical Society of Japan   61 ( 2 )   660 - 660   2006.8

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  • Anisotropy of the S-2-state manganese cluster in single crystals of cyanobacterial photosystem II studied by W-band electron paramagnetic resonance spectroscopy

    H Matsuoka, K Furukawa, T Kato, H Mino, Shen, JR, A Kawamori

    JOURNAL OF PHYSICAL CHEMISTRY B   110 ( 26 )   13242 - 13247   2006.7

  • 27aRB-6 ESR Study in β'-(BEDT-TTF) (TCNQ) IV

    Konno S., Kazama S., Hiraoka M., Katou A., Sakamoto H., Mizoguchi K., Taniguchi H., Nakamura T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   61 ( 1 )   801 - 801   2006.3

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  • 27aRC-5 Magnetic resonance investigation for electronic states of hexa-peri-hexabenzocoronene nanotube fiber

    Hara T., Furukawa K., Nakamura T., Yamamoto Y., Jin W., Fukushima T., Aida T.

    Meeting abstracts of the Physical Society of Japan   61 ( 1 )   804 - 804   2006.3

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  • 28pRB-8 ESR Study of Low-Temperature Spin Behavior of TMTTF Salts

    Furukawa K., Hara T., Nakamura T.

    Meeting abstracts of the Physical Society of Japan   61 ( 1 )   828 - 828   2006.3

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  • 27aRB-7 ESR Study in (BEDT-TTF) (TCNQ)

    Kihara T., Sakamoto H., Mizoguchi K., Konno S., Kazama S., Taniguchi H., Nakamura T., Furukawa K., Hiraoka M.

    Meeting abstracts of the Physical Society of Japan   61 ( 1 )   801 - 801   2006.3

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  • EPR study of the electronic states of beta-(BEDT-TTF)(TCNQ)

    Shin'ichi Konno, Shigeo Kazama, Maki Hiraoka, Hirokazu Sakamoto, Kenji Mizoguchi, Hiromi Taniguchi, Toshikazu Nakamura, Kou Furukawa

    JOURNAL OF LOW TEMPERATURE PHYSICS   142 ( 3-4 )   621 - 624   2006.2

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  • Electron spin dynamics in (Dme-DCNQI)(2)M (M = Li1-xCux (x &lt; 0.14), Ag)

    Maki Hiraoka, Hirokazu Sakamoto, Kenji Mizoguchi, Reizo Kato, Tatsuhisa Kato, Tosikazu Nakamura, Kou Furukawa, Koichi Hiraki, Toshihiro Takahashi, Takashi Yamamoto, Hiroyuki Tajima

    JOURNAL OF LOW TEMPERATURE PHYSICS   142 ( 3-4 )   617 - 620   2006.2

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  • Redistribution of electronic charge in (TMTTF)(2)ReO4: C-13 NMR investigation

    Toshikazu Nakamura, Toshifumi Hara, Ko Furukawa

    JOURNAL OF LOW TEMPERATURE PHYSICS   142 ( 3-4 )   629 - 632   2006.2

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  • 13C NMR analyses of successive charge ordering in (TMTTF) 2ReO 4

    Toshikazu Nakamura, Ko Furukawa, Toshifumi Hara

    Journal of the Physical Society of Japan   75 ( 1 )   13707/1-4   2006.1

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  • X-band cw ESRシステム: Bruker EMX Plus Premium

    古川貢

    分子研レターズ   54   18   2006

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  • Bruker EMX plus premium装置と分子研共同利用紹介

    古川貢

    電子スピンサイエンス   4   157   2006

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  • 有機導体TMTTFの相転移点近傍のスピンダイナミクス

    古川貢, 古川貢, 原俊文, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   45th   2006

  • ドープされた長鎖オリゴチオフェンの電子スピンダイナミクス

    鐘本勝一, 古川貢, 根岸伸和, 安蘇芳雄, 大坪徹夫

    電子スピンサイエンス学会年会講演要旨集   45th   2006

  • ヘキサベンゾコロネンナノチューブの電子状態の磁気共鳴法による考察

    原俊文, 古川貢, 古川貢, 中村敏和, 中村敏和, 山本洋平, 小阪敦子, JIN Wusong, 福島孝典, 福島孝典, 相田卓三, 相田卓三

    電子スピンサイエンス学会年会講演要旨集   45th   2006

  • Generation and interconversion of molecular-spin based entangled states by pulsed ENDOR technique

    佐藤和信, RAHIMI Robabeh, 新納隆, 西田辰介, 上田顕, 鈴木修一, 森田靖, 古川貢, 豊田和男, 塩見大輔, 中村敏和, 北川勝浩, 中筋一弘, 原英之, 工位武治

    日本化学会講演予稿集   86th ( 1 )   2006

  • Deuteration effect and possible origin of the charge-ordering transition of (TMTTF)2X

    Ko Furukawa, Toshifumi Hara, Toshikazu Nakamura

    Journal of the Physical Society of Japan   74 ( 12 )   3288 - 3294   2005.12

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  • Pulsed endor-based quantum information processing

    R Rahimi, K Sato, K Furukawa, K Toyota, D Shiomi, T Nakamura, M Kitagawa, T Takui

    INTERNATIONAL JOURNAL OF QUANTUM INFORMATION   3   197 - 204   2005.11

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  • The effect of deuteration on the transition into a charge ordered state of (TMTTF)(2)X salts

    F Nad, P Monceau, T Nakamura, K Furukawa

    JOURNAL OF PHYSICS-CONDENSED MATTER   17 ( 41 )   L399 - L406   2005.10

  • 21aWB-4 Low temperature charge ordering state of (TMTTF)_2PF_6

    Hara Toshifumi, Furukawa Ko, Kakiuchi Toru, Sawa Hiroshi, Nakamura Toshikazu

    Meeting abstracts of the Physical Society of Japan   60 ( 2 )   700 - 700   2005.8

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  • 19aWB-10 ESR Study in (BEDT-TTF)(TCNQ)

    Kihara T., Sakamoto H., Mizoguchi K., Konno S., Kazama S., Taniguchi H., Nakamura T., Furukawa K., Hiraoka M.

    Meeting abstracts of the Physical Society of Japan   60 ( 2 )   672 - 672   2005.8

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  • 19aWB-11 ESR Study in B'(BEDT-TTF)(TCNQ) III

    Konno S., Kazama S., Hiraoka M., Sakamoto H., Mizoguchi K., Taniguchi H., Nakamura T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   60 ( 2 )   672 - 672   2005.8

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  • 24aPS-171 Magnetic Properties of Electrodeposited Nickel Thin Film II

    Maruyama K., Arakawa E., Furukawa K., Hiraki K., Yamaguchi H., Sakai M., Numata H., Nakamura T., Mori K., Yokoyama T., Matsushita A., Kato T., Koide T., Namikawa K., Nittono O.

    Meeting abstracts of the Physical Society of Japan   60 ( 1 )   845 - 845   2005.3

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  • 24aYK-5 Charge ordering phenomena in (TMTTF)_2ReO_4

    Nakamura T., Furukawa K., Hara T.

    Meeting abstracts of the Physical Society of Japan   60 ( 1 )   768 - 768   2005.3

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  • 24aYL-10 ESR Study in (BEDT-TTF)(TCNQ) II

    Konno S., Kazama S., Hiraoka M., Sakamoto H., Mizoguchi K., Taniguchi H., Nakamura T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   60 ( 1 )   772 - 772   2005.3

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  • 24aYK-1 Multi-frequency ESR measurements for (TMTTF)_2X (II)

    Hara Toshifumi, Furukawa Ko, Nakamura Toshikazu

    Meeting abstracts of the Physical Society of Japan   60 ( 1 )   767 - 767   2005.3

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  • The importance of a beta-beta bond for long-range antiferromagnetic coupling in directly linked copper(II) and silver(II) diporphyrins

    T Ikeue, K Furukawa, H Hata, N Aratani, H Shinokubo, T Kato, A Osuka

    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION   44 ( 42 )   6899 - 6901   2005

  • 有機導体(TMTTF)<sub>2</sub>Xの電荷秩序状態とその起源

    古川貢, 古川貢, 原俊文, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   44th   2005

  • 有機導体TMTTF系のスピンダイナミクス

    古川貢, 古川貢, 原俊文, 中村敏和, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   44th   2005

  • パルスENDOR法による分子スピン量子情報操作

    佐藤和信, RAHIMI Robabeh, 新納隆, 西田辰介, 上田顕, 鈴木修一, 森田靖, 古川貢, 豊田和男, 塩見大輔, 中村敏和, 北川勝浩, 中筋一弘, 工位武治

    電子スピンサイエンス学会年会講演要旨集   44th   2005

  • Biscopper complexes of meso-aryl-substituted hexaphyrin: Gable structures and varying antiferromagnetic coupling

    S Shimizu, VG Anand, R Taniguchi, K Furukawa, T Kato, T Yokoyama, A Osuka

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   126 ( 39 )   12280 - 12281   2004.10

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  • Multifrequency EPR study of metallofullerenes: Eu@C-82 and Eu@C-74

    H Matsuoka, N Ozawa, T Kodama, H Nishikawa, Ikemoto, I, K Kikuchi, K Furukawa, K Sato, D Shiomi, T Takui, T Kato

    JOURNAL OF PHYSICAL CHEMISTRY B   108 ( 37 )   13972 - 13976   2004.9

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  • Fullerenols revisited as stable radical anions

    LO Husebo, B Sitharaman, K Furukawa, T Kato, LJ Wilson

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY   126 ( 38 )   12055 - 12064   2004.9

  • 12pWH-14 EPR study on low dimensional DMe-DCNQI system

    Hiraoka M., Sakamoto H., Mizoguchi K., Nakamura T., Furukawa K., Hiraki K., Takahashi T., Yamamoto T., Tajima H., Kato R.

    Meeting abstracts of the Physical Society of Japan   59 ( 2 )   743 - 743   2004.8

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  • 12aWE-2 Deuteration effects for the charge ordering phenomena of (TMTTF)_2X

    Nakamura T., Furukawa K., Hara T., Maeda K.

    Meeting abstracts of the Physical Society of Japan   59 ( 2 )   732 - 732   2004.8

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  • 12aWE-3 Multi-frequency ESR measurements for (TMTTF)_2X

    Hara Toshifumi, Furukawa Ko, Nakamura Toshikazu

    Meeting abstracts of the Physical Society of Japan   59 ( 2 )   732 - 732   2004.8

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  • 13pWE-10 ESR Study in (BEDT-TTF)(TCNQ)

    Konno S., Kazama S., Hiraoka M., Sakamoto H., Mizoguchi K., Taniguchi H., Nakamura T., Furukawa K.

    Meeting abstracts of the Physical Society of Japan   59 ( 2 )   754 - 754   2004.8

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  • 13pWE-4 Multi-frequency ESR for Low-dimensional Antiferromagnets, α-and ζ-(BEDT-TTF)_2PF_6

    Maeda Keisuke, Furukawa Ko, Nakamura Toshikazu

    Meeting abstracts of the Physical Society of Japan   59 ( 2 )   753 - 753   2004.8

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  • Spin soliton dynamics and pressure effects in the spin-Peierls system (DMe-DCNQI)(2)M (M = Li, Ag)

    M Hiraoka, H Sakamoto, K Mizoguchi, T Kato, K Furukawa, R Kato, K Hiraki, T Takahashi

    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS   272   1077 - 1078   2004.5

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  • 28aWN-8 Uniaxial strain effect to ferromagnetism of TDAE-C_<60>

    Takei M., Mizoguchi K., Sakamoto H., Tokumoto M., Kawamoto T., Omerzu A., Mihailovic D., Kato T., Furukawa M.

    Meeting abstracts of the Physical Society of Japan   59 ( 1 )   842 - 842   2004.3

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  • 28aXJ-7 EPR study on (DMe-DCNQI)_2M(M=Li, Ag)

    Hiraoka M., Sakamoto H., Mizoguchi K., Kato T., Furukawa K., Hiraki K., Takahashi T., Kato R.

    Meeting abstracts of the Physical Society of Japan   59 ( 1 )   845 - 845   2004.3

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  • 28pWG-10 ESR Study in (BEDO-TTF)(Cl_2TCNQ) III

    Sakamoto H., Mizoguchi K., Hasegawa T., Furukawa K., Kato T.

    Meeting abstracts of the Physical Society of Japan   59 ( 1 )   848 - 848   2004.3

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  • Magnetic characteristics of Fe4N epitaxial films grown by halide vapor phase deposition under atmospheric pressure

    T Takahashi, N Takahashi, T Nakamura, T Kato, K Furukawa, GM Smith, PC Riedi

    SOLID STATE SCIENCES   6 ( 1 )   97 - 99   2004.1

  • W-band EPR studies of Mn-cluster in the S-0 and S-2 states of Cyanobacterial single crystals.

    A Kawamori, Shen, JR, K Furukawa, E Matsuoka, T Kato

    PLANT AND CELL PHYSIOLOGY   45   S81 - S81   2004

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  • (TMTTF)<sub>2</sub>X系の電荷秩序現象における重水素効果

    中村敏和, 古川貢, 原俊文, 前田圭介

    電子スピンサイエンス学会年会講演要旨集   43rd   2004

  • 低次元反強磁性体αおよびζ-(BEDT-TTF)<sub>2</sub>PF<sub>6</sub>におけるESRの周波数依存性

    前田圭介, 古川貢, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   43rd   2004

  • (TMTTF)<sub>2</sub>XにおけるESRの周波数依存性

    原俊文, 古川貢, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   43rd   2004

  • (TMTTF)<sub>2</sub>Xの異常gシフト

    古川貢, 原俊文, 中村敏和

    電子スピンサイエンス学会年会講演要旨集   43rd   2004

  • パルスENDOR法を用いたスピン操作と量子計算の可能性

    佐藤和信, RAHIMI R, 古川貢, 豊田和男, 塩見大輔, 中村敏和, 北川勝浩, 工位武治

    電子スピンサイエンス学会年会講演要旨集   43rd   2004

  • Importance of fourth-order zero-field splitting terms in random-orientation EPR spectra of Eu(II)-doped strontium aluminate

    H Matsuoka, K Furukawa, K Sato, D Shiomi, Y Kojima, K Hirotsu, N Furuno, T Kato, T Takui

    JOURNAL OF PHYSICAL CHEMISTRY A   107 ( 51 )   11539 - 11546   2003.12

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  • High-field/high-frequency ESR study of Gd@C-82-I

    K Furukawa, S Okubo, H Kato, H Shinohara, T Kato

    JOURNAL OF PHYSICAL CHEMISTRY A   107 ( 50 )   10933 - 10937   2003.12

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  • High-field FMR investigation of epitaxially grown Fe4N films on a MgO(001) substrate

    T Nakamura, T Takahashi, N Takahashi, T Kato, K Furukawa, GM Smith, CJ Oates, PC Riedi

    ELECTROCHEMICAL AND SOLID STATE LETTERS   6 ( 10 )   C146 - C148   2003.10

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  • EPR study on (DMe-DCNQI)_2M (M=Li, Ag)

    Hiraoka M., Sakamoto H., Mizoguchi K., Kato T., Furukawa K., Hiraki K., Takahashi T., Kato R.

    Meeting abstracts of the Physical Society of Japan   58 ( 2 )   758 - 758   2003.8

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  • Metal-dependent regioselective oxidative coupling of 5,10,15-triarylporphyrins with DDQ-Sc(OTf)(3) and formation of an oxo-quinoidal porphyrin

    M Kamo, A Tsuda, Y Nakamura, N Aratani, K Furukawa, T Kato, A Osuka

    ORGANIC LETTERS   5 ( 12 )   2079 - 2082   2003.6

  • The ESR g-Anisotropy of Polypyrrole

    Sato S., Sakamoto H., Mizoguchi K., Morioka H., Kimura T., Masubuchi S., Kato T., Hurukawa K.

    Meeting abstracts of the Physical Society of Japan   58 ( 1 )   794 - 794   2003.3

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  • Cu2核ヘキサフィリンの磁気特性

    古川貢, VENKATARAMANARAO G A, 清水宗治, 荒谷直樹, 大須賀篤弘, 加藤立久

    電子スピンサイエンス学会年会講演要旨集   42nd   2003

  • 基底状態<sup>8</sup>S<sub>7/2</sub>のEu<sup>2+</sup>イオンを内包するフラーレンのゼロ磁場 分裂定数と分子構造との関係

    松岡秀人, 尾沢紀生, 児玉健, 西川浩之, 池本勲, 古川貢, 佐藤和信, 塩見大輔, 工位武治

    電子スピンサイエンス学会年会講演要旨集   42nd   2003

  • Dynamic Magnetic Properties of the Microstructured Thin Films

    FURUKAWA Ko, SHIOMI Daisuke, SATO Kazunobu, TAKUI Takeji, UMEMOTO Takashi, YAMANO Koji, MAEDA Atsushi, TAKAHASHI Sei-Nchiro

    Meeting abstracts of the Physical Society of Japan   55 ( 1 )   413 - 413   2000.3

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  • Magnetostatic Spin Waves in Ferromagnetic Wires

    Umemoto T., Yamano K., Maeda A., Takahashi S., Furukawa K., Shiomi D., Sato K., Takui T.

    Meeting abstracts of the Physical Society of Japan   55 ( 1 )   413 - 413   2000.3

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  • Novel spin wave from low-dimensional superlattice of microstructured ferromagnetic thin films

    Ko Furukawa, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Koichi Itoh, Atsushi Maeda, Minoru Kume, Kenichi Shibata, Isao Nakatani

    Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals   335   875 - 884   1999.12

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  • Dipolar Standing Waves Excited in Ferromagnetic Wire Arrays.

    Umemoto T., Yamano K., Maeda A., Takahashi S., Furukawa K., Shiomi D., Satou K., Takui T.

    Journal of the Magnetics Society of Japan   23 ( 4-2 )   1125 - 1128   1998

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    Recently, unique multiple microwave absorption has been observed in ferromagnetic Ni<sub>80</sub>Fe<sub>20</sub> wire arrays with lateral periodicity. As the origin of this phenomenon, we have proposed the excitation of dipolar standing waves arising from a novel collective motion of giant magnetic moments. In the present study, the dependence of the microwave absorption characteristics on the wire spacing, width, and number of wires was investigated to confirm our model. The intensity of the absorption with higher wave number decreased as wire spacing increased. Complex spectra were observed in arrays with wider wires, suggesting an overlap of main and multiple absorption. No change was obtained in the microwave absorption characteristics when the number of wires was varied between 50 and 500. These results imply the validity of the dipolar standing wave model.

    DOI: 10.3379/jmsjmag.23.1125

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  • Dipolar standing waves excited in ferromagnetic wire array

    T. Umemoto, K. Yamano, A. Maeda, S. Takahashi, K. Furukawa, D. Shiomi, K. Sato, T. Takui

    J. Magn. Soc. Japan   23 ( 4-2 )   1125 - 1128   1998

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    Recently, unique multiple microwave absorption has been observed in ferromagnetic Ni<sub>80</sub>Fe<sub>20</sub> wire arrays with lateral periodicity. As the origin of this phenomenon, we have proposed the excitation of dipolar standing waves arising from a novel collective motion of giant magnetic moments. In the present study, the dependence of the microwave absorption characteristics on the wire spacing, width, and number of wires was investigated to confirm our model. The intensity of the absorption with higher wave number decreased as wire spacing increased. Complex spectra were observed in arrays with wider wires, suggesting an overlap of main and multiple absorption. No change was obtained in the microwave absorption characteristics when the number of wires was varied between 50 and 500. These results imply the validity of the dipolar standing wave model.

    DOI: 10.3379/jmsjmag.23.1125

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  • Dipolar Spin-Wave from Low-Dimensional Superlattices in Ferromagnetic Thin Films

    K. Furukawa, D. Shiomi, K. Sato, T. Takui, K. Itoh, A. Maeda, M. Kume, K. Shibata, I. Nakatani

    Magnetic Resonance and Related Phenomena Vol. II   1033 - 1034   1998

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  • Dipolar standing waves excited in ferromagnetic wire arrays

    MAEDA A., KUME M., SHIBATA K., FURUKAWA K., SHIOMI D., TAKUI T., NAKATANI I.

    21   58 - 58   1997.10

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Presentations

  • オペランドESR観測における燃料電池触媒のメカニズム解明

    高須温, 古川貢

    第24回ESRフォーラム研究会  2021.9 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

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  • ジアザポルフィリン類縁体の光励起高スピン状態の時間分解ESR研究

    大隣仁, 落合ひかり, 古川貢, 俣野善博

    第24回ESRフォーラム研究会  2021.9 

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    Event date: 2021.9

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  • パルスESRによる茶葉における微量金属元素の解析

    藤田倖平, 古川貢

    第24回ESRフォーラム研究会  2021.9 

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  • 米ぬかのQ-band pulse ESR測定による含有金属イオン同定研究

    平賀惇哉, 古川貢

    第24回ESRフォーラム研究会  2021.9 

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    Event date: 2021.9

    Language:Japanese   Presentation type:Oral presentation (general)  

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  • 米糠の電子スピン共鳴計測

    古川 貢

    日本分析化学会関東支部 第33回新潟地区部会発表会  2019.9 

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  • Trimethylenemethane Stabilized by Embedding in Porphyrin-based Fused π-Framework

    K. Kato, K. Furukawa, A. Osuka

    日本化学会第98春季年会  2018.3 

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    Venue:日大  

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  • ベンゼンの1,3,5位で架橋したポルフィリンメゾオキシラジカル三量体の合成と物性

    山本貴之, 清水大貴, 古川貢, 大須賀篤弘

    日本化学会第98春季年会  2018.3 

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    Venue:日大  

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  • TTF-ニトロキシドラジカル混晶系における光誘起磁気特性

    阿部匡矩, 古川貢, 堀切一樹, 藤原秀紀

    日本化学会第98春季年会  2018.3 

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    Venue:日大  

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  • ESRによる燃料電池の酸化チタン触媒のメカニズム解明

    遠藤夏実, 石原顕光, 太田健一郎, 村瀬典子, 李建燦, 古川貢

    第56回電子スピンサイエンス学会年会  2017.11 

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    Venue:東工大  

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  • Cu(II)イオンを用いた共有結合性有機骨格構造の光誘起磁気特性

    古川 貢, 大高 秀仁, 江 東林

    第11回分子科学討論会  2017.9 

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    Venue:東北大  

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  • Ndを含む二核金属内包フラーレンアニオンの分光学的研究

    西本 真也, 古川 貢, 加藤 立久, 菊地 耕一, 阿知波 洋次, 兒玉 健

    第11回分子科学討論会  2017.9 

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    Venue:東北大  

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  • GdM@C80(Ih)(M=Y, La)アニオンの合成とキャラクタリゼーション

    三谷 拓示, 山口 貴久, 古川 貢, 加藤 立久, 菊地 耕一, 阿知波 洋次, 兒玉 健

    第11回分子科学討論会  2017.9 

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    Venue:東北大  

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  • 安定ラジカル種を生じるジフェニルメタン縮環ポルフィリンの化学

    加藤研一, 古川貢, 依光英樹, 大須賀篤弘

    日本化学会第97春季年会  2017.3 

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    Venue:慶應義塾大  

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  • 金属ジアザポルフィリンの励起状態におけるスピンダイナミクス

    丸山裕久, 須貝拓馬, 古川貢, 俣野善博

    日本化学会第97春季年会  2017.3 

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    Venue:慶應義塾大  

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  • ニトロキシドラジカルを有するTTF誘導体の光誘起磁気特性

    阿部匡矩, 古川貢, 堀切一樹, 藤原秀紀

    日本化学会第97春季年会  2017.3 

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    Venue:慶應義塾大  

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  • ESRによる燃料電池の酸化チタン触媒のメカニズム解明

    遠藤夏実, 古川貢, 石原顕光, 太田健一郎

    日本化学会第97春季年会  2017.3 

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    Venue:慶應義塾大  

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  • ドナー・アクセプター型COFの光誘起磁気特性と結晶構造の相関

    大高秀仁, 古川貢, 江東林

    日本化学会第97春季年会  2017.3 

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    Venue:慶應義塾大  

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  • 新規5,10,15,20-テトラアリール-5,15-ジアザポルフィリン金属錯体の合成と物性

    須藤啓佑, 佐藤隆治, 古川貢, 雨夜徹, 俣野善博

    日本化学会第97春季年会  2017.3 

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    Venue:慶應義塾大  

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  • TTF縮環サブフタロシアニンを用いた超分子ポリマーの構築

    内原岬哉, 古川貢, 古田弘幸, 清水宗治

    日本化学会第97春季年会  2017.3 

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    Venue:慶應義塾大  

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  • ジアザポルフィリン二量体の磁気特性

    丸山裕久, 大桃理志, 川俣昌弘, 古川貢, 俣野善博

    第55回電子スピンサイエンス学会年会  2016.11 

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    Venue:大阪市立大  

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  • Y2@C80(Ih)の単離法の開発とキャラクタリゼーション

    中鳥なつみ, 富樫愛美, 三谷拓示, 山口貴久, 古川貢, 加藤立久, 藤田渉, 菊地耕一, 阿知波洋次, 兒玉健

    第10回分子科学討論会  2016.9 

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    Venue:神戸ファッションマート  

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  • 特異なスピン状態を持つGd2@Cn(n=78,80)アニオンの単離とキャラクタリゼーション

    三谷拓示, 中鳥なつみ, 山口貴久, 小林樹来, 古川貢, 加藤立久, 菊地耕一, 阿知波洋次, 兒玉健

    第10回分子科学討論会  2016.9 

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    Venue:神戸ファッションマート  

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  • 安定有機ラジカルを有するTTF誘導体の光誘起磁気特性

    阿部匡矩, 古川貢, 堀切一樹, 藤原秀紀

    第10回分子科学討論会  2016.9 

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    Venue:神戸ファッションマート  

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  • Cuフタロシアニンを使用した共有結合性有機骨格構造(COF)の光誘起磁気特性

    渡邊聖也, 小野健太, 古川貢, 金尚彬, 江東林

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大  

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  • ポルフィリンおよびサブポルフィリンによって安定化された中性窒素ラジカルの合成と物性

    清水大貴, 古川貢, 大須賀篤弘

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大  

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  • 5,10,15,20-テトラアリール-5,15-ジアザポルフィリンニッケル錯体の合成、構造、および反応

    佐藤隆治, 俣野善博, 中野晴之, 古川貢

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大  

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  • アミノキシルラジカルを有するTTF誘導体のスピンダイナミクス

    阿部匡矩, 古川貢, 堀切一樹, 藤原秀紀

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大  

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  • ジシアノメチレン部位を有する縮合多環安定中性ラジカルの電子物性および結晶構造

    安藤沙也伽, 西田辰介, 古川貢, 村田剛志, 森田靖

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大  

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  • フェニレン架橋シクロブタジエン誘導体の合成とビラジカル特性

    小林譲, 中本真晃, 古川貢, 関口章

    日本化学会第96春季年会  2016.3 

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    Venue:同志社大  

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  • ヘテロール架橋ジアザポルフィリン二量体の磁気特性

    丸山裕久, 大桃理志, 川俣昌弘, 古川貢, 俣野善博

    第54回電子スピンサイエンス学会年会  2015.11 

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    Venue:朱鷺メッセ:新潟コンベンションセンター  

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  • ベンズイミダゾリウム塩の微結晶薄膜における光キャリアダイナミクス

    内田賢, 脇川祐介, 三浦智明, 古川貢, 根本一輝, 長谷川英悦, 生駒忠昭

    第54回電子スピンサイエンス学会年会  2015.11 

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    Venue:朱鷺メッセ:新潟コンベンションセンター  

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  • トリアンギュレン骨格に二個のジシアノメチレン部位を組み込んだ電子スピン比局在型安定中性ラジカルの構造と物性

    安藤沙也伽, 西田辰介, 村田剛志, 古川貢, 森田靖

    第54回電子スピンサイエンス学会年会  2015.11 

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    Venue:朱鷺メッセ:新潟コンベンションセンター  

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  • 磁性イオンを使用した共有結合性有機骨格構造(COF)のスピンダイナミクス

    渡邊聖也, 小野健太, 古川貢, 金尚彬, 江東林

    第54回電子スピンサイエンス学会年会  2015.11 

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    Venue:朱鷺メッセ:新潟コンベンションセンター  

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  • Gd,Y金属が2個内包されたフラーレン類のESR測定

    山口貴久, 中鳥なつみ, 三谷拓示, 菊地耕一, 兒玉健, 古川貢, 加藤立久

    第54回電子スピンサイエンス学会年会  2015.11 

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    Venue:朱鷺メッセ:新潟コンベンションセンター  

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  • ヘテロール架橋ジアザポルフィリン二量体の磁気特性

    丸山裕久, 大桃理志, 俣野善博, 古川 貢

    第9回分子科学討論会  2015.9 

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    Venue:東工大  

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  • 共有結合性有機骨格構造(COF)のスピンダイナミクス研究

    古川貢, 中村敏和, 陳龍, 江東林

    第9回分子科学討論会  2015.9 

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    Venue:東工大  

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  • ドナー・アクセプター型共有結合性有機骨格構造(COF)のスピンダイナミクス

    古川貢, 陳龍, 江東林

    感応性化学種が拓く新物質科学 第4回公開シンポジウム  2015.5 

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    Venue:京都大学・宇治おうばくプラザ・きはだホール  

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  • 酸応答性ビカルバゾール誘導体

    パンディット パラッシュ, 山本浩司, 中村敏和, 西村勝之, 倉重佑輝, 柳井毅, 中村豪, 正岡重行, 古川貢, 東林修平

    日本化学会第95春季年会  2015.3 

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    Venue:日大  

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  • 非対称 diborane(4)化合物 pinB-BMes2の反応性とその高い電子受容性の起源

    浅川博祈, 山下 誠, 古川 貢, Lin Zhenyang, Lee Ka Ho

    日本化学会第95春季年会  2015.3 

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    Venue:日大  

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  • ヘテロール架橋ジアザポルフィリン二量体の合成と物性

    大桃理志, 古川貢, 中野晴之, 俣野善博

    第25回基礎有機化学討論会  2014.9 

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    Venue:東北大  

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  • TTF縮環ケイ素フタロシアニン多量体の酸化還元による分子配列制御

    椎名祐太, 清水宗治, 古川貢, 小林長夫

    第25回基礎有機化学討論会  2014.9 

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    Venue:東北大  

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  • ドナー・アクセプター共有結合性有機骨格構造の光誘起伝導性メカニズムの時間分解ESR研究

    古川貢, 佐久間駿, 中村敏和, 金尚彬, 陳龍, 江東林

    錯体化学会第64回討論会  2014.9 

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    Venue:中央大  

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  • 安定な三重項カルベンの合成検討

    山本純基, 福圓真一, 古川貢, 中野雅由, 岸亮平, 安倍学, 山本陽介

    第25回基礎有機化学討論会  2014.9 

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    Venue:東北大  

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  • ドナー・アクセプター型共有結合性有機骨格構造(COF)のスピンダイナミクス研究

    古川 貢, 佐久間 駿, 金 尚彬, 陳 龍, 江 東林, 中村 敏和

    日本化学会第94春季年会  2014.3 

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    Venue:名古屋大  

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  • 光誘起伝導性ドナー・アクセプター型COFのスピンダイナミクス

    古川貢

    分子研研究会「先端スピン計測技術による分子性物質研究の現状と展望」  2013.12 

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    Venue:分子研  

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  • ドナー・アクセプター型COFのスピンダイナミクス

    古川貢, 金尚彬, 陳龍, 江東林, 中村敏和

    第52回電子スピンサイエンス学会年会  2013.10 

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    Venue:大宮ソニック市民ホール  

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  • 光誘起伝導性ドナー・アクセプター型COFのスピンダイナミクス

    古川 貢, 高橋誠弥, 金尚彬, 陳龍, 江東林, 中村 敏和

    第7回分子科学討論会  2013.9 

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    Venue:京都テルサ  

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  • ドナー・アクセプター結合型COFの時間分解ESRによる光伝導性の解明

    古川貢, 江東林, 中村敏和

    感応性化学種が拓く新物質科学 第2回公開シンポジウム  2013.6 

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    Venue:九州大学医学部百年記念講堂  

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  • C60を内包した光誘起伝導性COFのスピンダイナミクス

    古川貢, 陳龍, 江東林, 高橋誠弥, 中村敏和

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大  

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  • ポルフィリン/フタロシアニン4重ロタキサン-TPPS会合体を利用した金属錯体のプログラム配列化

    三原のぞみ, 山田泰之, 柴野慎也, 岡本光弘, 古川貢, 加藤立久, 田中健太郎

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大  

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  • ヘリウム原子内包フラーレンの有機合成と新規異種原子内包フラーレンの発生

    森中裕太, 佐藤悟, 若宮淳志, 二川秀史, 溝呂木直美, 田邊史行, 村田理尚, 小松紘一, 古川貢, 加藤立久, 永瀬茂, 赤阪健, 村田靖次郎

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大  

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  • self-dope型有機導体TTFCOO,TTPCOO系の磁気共鳴研究

    中村敏和, 古川貢, 寺内毅, 小林由佳, 御崎洋二

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大  

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  • トリホスファ[3]ラジアレンおよびそのラジカルアニオンの電子密度分布解析

    三宅秀明, 笹森貴裕, 時任宣博, 橋爪大輔, 古川貢, 金朋, 永瀬茂

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大  

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  • 4重ロタキサン型ポルフィリン‐フタロシアニンヘテロダイマー内における電子的コミュニケーション

    飯田隼人, 山田泰之, 岡本光弘, 古川貢, 加藤立久, 田中健太郎

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大  

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  • ドナー・アクセプター結合型COFの時間分解ESRによる光伝導性の解明

    高橋誠弥, 金尚彬, 古川貢, 江東林, 中村敏和

    日本化学会第93春季年会  2013.3 

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    Venue:立命館大  

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  • 光化学IIにおける酸素発生中心Mnクラスターの多周波EPR研究

    松岡秀人, 沈建仁, 伊東伸哉, 古川貢, 中村敏和, 山内清吾

    第51回電子スピンサイエンス学会年会  2012.11 

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    Venue:札幌コンベンションセンター  

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  • π拡張した光誘起伝導性物質(EDT-TTF)BTAのスピンダイナミクス

    古川貢, 辻本啓次郎, 藤原秀紀, 高橋誠弥, 中村敏和

    第51回電子スピンサイエンス学会年会  2012.11 

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    Venue:札幌コンベンションセンター  

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  • 時間分解ESR法による共有結合性有機骨格構造の光伝導性解明

    高橋誠弥, 金尚彬, 古川貢, 江東林, 中村敏和

    第51回電子スピンサイエンス学会年会  2012.11 

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    Venue:札幌コンベンションセンター  

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  • イオン液体中におけるニトロキシドのg値と超微細結合定数のWバンドEPR測定

    荒牧龍太, 三宅祐輔, 河合明雄, 古川貢, 中村敏和

    第51回電子スピンサイエンス学会年会  2012.11 

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    Venue:札幌コンベンションセンター  

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  • 新規三重項カルベンの合成の試みとESR測定

    福圓真一, 山本陽介, 古川貢

    第51回電子スピンサイエンス学会年会  2012.11 

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    Venue:札幌コンベンションセンター  

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  • TTFCOONH4塩ならびに類縁体の磁気共鳴研究

    中村敏和, 古川貢, 寺内毅, 小林由佳, 御崎洋二

    第6回 分子科学討論会  2012.9 

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    Venue:東大  

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  • 時間分解ESRによる光誘起伝導性TTF誘導体におけるメカニズムの解明研究

    古川貢, 辻本啓次郎, 藤原秀紀, 高橋誠弥, 中村敏和

    第6回 分子科学討論会  2012.9 

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    Venue:東大  

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  • 機能性物質のアドバンスドESR

    古川貢, 辻本啓次郎, 藤原秀紀, 高橋誠弥, 中村敏和

    分子研研究会「レーザー分光および磁気測定による分子構造探求の新展開」  2012.7 

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    Venue:分子研  

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  • アントラセン骨格を含む環状芳香族アミンの合成と電子物性

    増田泰之, 酒巻大輔, 伊藤彰浩, 田中一義, 古川貢, 加藤立久

    日本化学会第92春季年会  2012.3 

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    Venue:慶応大  

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  • 4重ロタキサン型ポルフィリンーフタロシアニン超分子アレイ

    山田泰之, 古川貢, 加藤立久, 田中健太郎

    日本化学会第92春季年会  2012.3 

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    Venue:慶応大  

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  • 時間分解ESRによる光誘起伝導性TTF誘導体の電荷分離状態の研究

    古川貢, 辻本啓次郎, 藤原秀紀, 高橋誠弥, 中村敏和

    日本化学会第92春季年会  2012.3 

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    Venue:慶応大  

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  • パルスQ-bandシステムを利用した生体系物質の PELDORによる距離測定の試み

    古川貢, 平岡和佳子, 稲波修, 中村敏和

    第50回電子スピンサイエンス学会年会  2011.11 

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    Venue:仙台国際センター  

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  • 光誘起伝導性TTF誘導体の時間分解ESR研究

    古川貢, 辻本啓次郎, 藤原秀紀, 中村敏和

    第50回電子スピンサイエンス学会年会  2011.11 

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    Venue:仙台国際センター  

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  • 光誘起機能性物質の時間分解ESRによるスピンダイナミクス研究

    古川貢, 辻本啓次郎, 藤原秀紀, 中村敏和

    第5回 分子科学討論会  2011.9 

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    Venue:札幌コンベンションセンター  

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  • 磁性及び構造的観点からの(TMTTF)2SCNの電子状態研究

    杉浦晃一, 古川貢, 中村敏和

    日本物理学会 2011年秋季大会  2011.9 

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    Venue:富山大  

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  • 蛍光性部位を有するTTF複合分子の光機能性

    藤原秀紀, 林定快, 笹部圭祐, 辻本啓次郎, 中澄博行, 古川貢, 中村敏和, 内田隆介, 松崎弘幸, 岡本博

    第5回 分子科学討論会  2011.9 

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    Venue:札幌コンベンションセンター  

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  • (TMTTF)2SCNの電子状態と磁気相関の解明 〜リエントラント反強磁性の構造学的理解〜

    杉浦晃一, 古川貢, 中村敏和

    日本物理学会 第66回年次大会  2011.3 

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    Venue:新潟大  

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  • 光伝導性TTF誘導体の光誘起スピンダイナミクス

    古川貢, 辻本啓次郎, 杉島泰雄, 藤原秀紀, 中村敏和

    日本化学会第91春季年会  2011.3 

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    Venue:神奈川大  

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  • 光誘起伝導性TTF誘導体のスピンダイナミクス研究

    古川貢, 辻本啓次郎, 杉島泰雄, 藤原秀紀, 中村敏和

    第49回電子スピンサイエンス学会年会  2010.11 

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    Venue:名古屋大  

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  • 非対称アニオンを持つ有機導体(TMTTF)2SCNの電子構造と結晶構造

    杉浦晃一, 古川貢, 中村敏和

    第49回電子スピンサイエンス学会年会  2010.11 

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    Venue:名古屋大  

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  • TTF系伝導性物質のスピンダイナミクスと構造による研究

    古川貢, 藤原秀紀, 中村敏和

    MDF A03班会議  2010.11 

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    Venue:箱根  

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  • Time-Resolved ESR Study for Photo-induced Functional Materials, TTF-Derivatives

    ISSP-MDF研究会  2010 

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  • 一次元有機導体(TMTTF)2Xの構造と電子相との相関

    日本物理学会 第65回年次大会  2010 

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  • Time-Resolved ESR Study for Photo-induced Functional Materials, TTF-Derivatives

    ISSP-MDF研究会  2010 

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  • 一次元有機導体(TMTTF)2Xの構造と電子相との相関

    CMRC研究会「分子結晶における構造物性研究」 2010/04/22-23  2010 

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  • 光誘起伝導物質におけるスピンダイナミクスと蛍光部位との相関

    第4回 分子科学討論会  2010 

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  • TMTCF系の修正一般化相図の構造的理解

    日本物理学会 2010年秋季大会  2010 

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  • 時間分解ESR による光誘起機能性物質TTF 誘導体のスピンダイナミクス研究

    新学術領域研究「分子自由度が拓く新物質科学」 第3回領域研究会  2010 

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  • 光誘起機能性物質TTF誘導体のスピンダイナミクス

    日本化学会第90春季年会  2010 

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  • Spin Dynamics of Photo-Induced Functional Materials

    The 3rd Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices  2009 

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  • 光誘起伝導性物質TTF誘導体のスピンダイナミクス研究

    第48回電子スピンサイエンス学会年会  2009 

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  • 光誘起機能性物質の時間分解ESRによるスピンダイナミクス研究

    第3回 分子科学討論会  2009 

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  • 光誘起伝導性TTF誘導体の時間分解ESRによる研究

    日本化学会第89春季年会  2009 

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  • Spin Dynamics of Photo-Induced Functional Materials

    The 3rd Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices  2009 

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  • 光誘起機能性材料のアドバンスドESRによるスピンダイナミクス研究

    新学術領域研究「分子自由度が拓く新物質科学」 第2回領域研究会  2009 

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  • ESR Study of Spin Dynamics for Dye-Sensitized Solar Cell

    Asia Pacific EPR Society - EPR Symposium 2008  2008 

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  • 色素増感太陽電池のスピンダイナミクス研究

    第47回電子スピンサイエンス学会年会  2008 

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  • 色素増感太陽電池のスピンダイナミクス研究

    第2回 分子科学討論会  2008 

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  • ESR Study of Spin Dynamics for Dye-Sensitized Solar Cell

    Asia Pacific EPR Society - EPR Symposium 2008  2008 

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  • Pulsed-ESR Study of Spin Dynamics for Organic Conductor, (TMTTF)2PF6

    A Joint Conference of the International Symposium on Electron Spin Science and the 46th Annual Meeting of the Society of Electron Spin Science and Technology  2007 

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  • ESR Study of Spin Dynamics for Organic Conductors

    COE21 “QUESTS” International workshop -New Developments in ESR of Strongly Correlated Systems  2007 

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  • アドバンスドESRを利用した研究

    次世代を担う若手研究者共同研究ネットワークの構築 -分子研共同利用装置・大型計算機を軸とした分野横断型研究の新展開-  2007 

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  • MEM-TCNQのESRによるスピンダイナミクス研究

    日本物理学会2007年春季大会  2007 

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  • Pulsed-ESR Study of Spin Dynamics for Organic Conductor, (TMTTF)2PF6

    A Joint Conference of the International Symposium on Electron Spin Science and the 46th Annual Meeting of the Society of Electron Spin Science and Technology  2007 

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  • サーモクロミック材料CoCl2 nH2O (n = 2, 6)の磁気特性

    日本化学会 第87春季年会  2007 

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  • Pulse-ESRによるTMTTF系のスピンダイナミクス研究

    特定領域研究 「新しい環境下における分子性導体の特異な機能の探索」 第7回シンポジウム  2007 

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  • ESR Study of Spin Dynamics for Organic Conductors

    COE21 “QUESTS” International workshop -New Developments in ESR of Strongly Correlated Systems  2007 

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  • パルスESRによるTMTTF系のスピンダイナミクス研究

    日本物理学会 第62回年次大会  2007 

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  • 有機導体TMTTF系のパルスESRによるスピンダイナミクス研究

    第1回 分子科学討論会  2007 

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  • パルスESRによる有機導体のスピンダイナミクス研究

    分子研研究会 「先端的ESR手法による分子性物質の新機能性探索」  2007 

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  • 有機導体TMTTF系のパルスESRによるスピンダイナミクス研究

    日本物理学会2006年秋季大会  2006 

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  • 有機導体(TMTTF)2XのESRによるスピン構造研究

    日本化学会 第86春季年会  2006 

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  • スピンの多周波ESR観測

    スピン化学シンポジウム  2006 

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  • 有機導体TMTTF系の相転移点近傍のスピンダイナミクス

    2006年 分子構造総合討論会  2006 

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  • TMTTF塩の低温スピン挙動:ESRによる考察

    日本物理学会第61回年次大会  2006 

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  • 有機導体TMTTFの相転移点近傍のスピンダイナミクス

    第45回 電子スピンサイエンス学会年会  2006 

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  • TMTTF系のスピン構造

    2005年 分子構造総合討論会  2005 

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  • Spin Structure of Organic Conductors (TMTTF)2X

    Pacifichem2005  2005 

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  • 有機導体TMTTF系のスピンダイナミクス

    第44回 電子スピンサイエンス学会年会  2005 

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  • Anomalous g-shift of organic conductor (TMTTF)2X

    International Symposium on Molecular Conductors 2005  2005 

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  • 有機導体TMTTF系のスピン構造

    日本化学会 第85春季年会  2005 

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  • Anomalous g-shift of organic conductor (TMTTF)2X

    International Symposium on Molecular Conductors 2005  2005 

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  • Spin Structure of Organic Conductors (TMTTF)2X

    Pacifichem2005  2005 

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  • 有機導体(TMTTF)2Xの分子構造とスピン構造の相関

    2004年 分子構造総合討論会  2004 

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  • Gd内包フラーレンアニオンの高磁場・高周波ESR

    日本化学会 第84春季年会  2004 

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  • (TMTTF)2Xの異常gシフト

    第43回 電子スピンサイエンス学会年会  2004 

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  • 金属内包フラーレンの高磁場・高周波ESR

    第24回フラーレン・ナノチューブ総合シンポジウム  2003 

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  • 三角スピンフラストレーション系の高磁場・高周波ESR及び磁化率測定による研究

    日本化学会 第83春季年会  2003 

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  • Cu(II)2核拡張ポルフィリンの磁性特性

    2003年 分子構造総合討論会  2003 

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  • A Study of High-Field/High-Frequency ESR Spectroscopy and Magnetic Susceptibility Measurements for Triangular Spin Frustration Clusters

    Osaka City University International Conference on Molecular Science 2003  2003 

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  • Cu2 核ヘキサフィリンの磁気特性 Cu2 核ヘキサフィリンの磁気特性

    第42回 電子スピンサイエンス学会年会  2003 

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  • A Study of High-Field/High-Frequency ESR Spectroscopy and Magnetic Susceptibility Measurements for Triangular Spin Frustration Clusters

    Osaka City University International Conference on Molecular Science 2003  2003 

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  • Gd@C82の高磁場/高周波ESR

    第41回 ESR討論会/第7回 in vivo ESR研究会連合討論会  2002 

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  • 金属内包フラーレンの高周波ESR

    第22回フラーレンシンポジウム  2002 

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  • High-Field/High-Frequency ESR Study of Metallofullerenes

    Sendai-Berlin Joint Seminar on Advanced EPR  2002 

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  • Gd金属内包フラーレンのスピン状態

    2002年 分子構造総合討論会  2002 

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  • High-Field/High-Frequency ESR Study of Metallofullerenes

    Sendai-Berlin Joint Seminar on Advanced EPR  2002 

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  • パラメトリック励起磁気共鳴分光

    2001年 分子構造総合討論会  2001 

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  • Novel Quantized Modes of Magnetization from Artificial Superlattices in Ferromagnetic Thin Films

    平成12年度分子科学研究所COE国際シンポジウム「分子集合体の電子物性 分子固体から単一分子まで」  2001 

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  • シアナニル酸を配位子としフェナジンを含んだ遷移金属錯体の合成と物性

    日本化学会 第79春季年会  2001 

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  • Parametric Excitation Magnetic Resonance Spectroscopy

    平成12年度分子科学研究所COE国際シンポジウム「分子集合体の電子物性 分子固体から単一分子まで」  2001 

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  • Low-dimensional Molecule-Based Magnets; Cooperative Jahn-Teller Distortion in Hydrogen-Bonded Network Systems

    The VIIth International Symposium on Magnetic Field and Spin Effects in Chemistry and Related Phenomena  2001 

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  • ビオルル酸及びシアナニル酸誘導体を配位子としたCu(II)錯体の構造と磁性:ネットワーク水素結合系の協同的ヤーン・テラー相互作用

    日本化学会 第79春季年会  2001 

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  • Novel Quantized Modes of Magnetization from Artificial Superlattices in Ferromagnetic Thin Films

    14th Conference of the International Society of Magnetic Resonance  2001 

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  • Parametric Excitation Magnetic Resonance Spectroscopy

    The VIIth International Symposium on Magnetic Field and Spin Effects in Chemistry and Related Phenomena  2001 

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  • Gd内包金属フラーレンのケージ効果

    2001年 分子構造総合討論会  2001 

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  • Parametric Excitation Magnetic Resonance Spectroscopy

    14th Conference of the International Society of Magnetic Resonance  2001 

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  • Parametric Excitation Magnetic Resonance Spectroscopy; General Quantum Mechanical Description of Magnetic Resonance

    The 3rd Asia-Pacific EPR/ESR Symposium  2001 

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  • 強磁性人工格子薄膜のスピン波共鳴現象III

    第40回 ESR討論会  2001 

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  • 金属内包フラーレンの高周波ESR

    第40回 ESR討論会  2001 

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  • High-Field/High-Frequency ESR Study of Gd@C82

    The 3rd Asia-Pacific EPR/ESR Symposium  2001 

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  • 磁気共鳴分光学における解析的一般厳密解-パラメトリック励起および垂直励起共鳴のベクトル表現-

    第40回 ESR討論会  2001 

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  • High-Field/High-Frequency ESR Study of Gd@C82

    The 3rd Asia-Pacific EPR/ESR Symposium  2001 

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  • Parametric Excitation Magnetic Resonance Spectroscopy

    The VIIth International Symposium on Magnetic Field and Spin Effects in Chemistry and Related Phenomena  2001 

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  • Low-dimensional Molecule-Based Magnets; Cooperative Jahn-Teller Distortion in Hydrogen-Bonded Network Systems

    The VIIth International Symposium on Magnetic Field and Spin Effects in Chemistry and Related Phenomena  2001 

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  • Parametric Excitation Magnetic Resonance Spectroscopy

    14th Conference of the International Society of Magnetic Resonance  2001 

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  • Novel Quantized Modes of Magnetization from Artificial Superlattices in Ferromagnetic Thin Films

    14th Conference of the International Society of Magnetic Resonance  2001 

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  • Parametric Excitation Magnetic Resonance Spectroscopy; General Quantum Mechanical Description of Magnetic Resonance

    The 3rd Asia-Pacific EPR/ESR Symposium  2001 

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  • Spin Wave-like Collective Excitations from Microstructured Ferromagnetic Thin Films

    Pacifichem 2000  2000 

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  • 強磁性細線における静磁モードスピン波

    日本物理学会 春の分科会  2000 

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  • 微細加工人工格子薄膜の動的磁気特性

    日本物理学会 春の分科会  2000 

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  • Low-Dimensional Molecule-Based Magnets; Structures and Magnetic Properties of Cupper(II) Complexes with Hydrogen-Bonded Network

    AMPERE Congress 2000  2000 

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  • Dynamic Magnetic Properties from Microstructured Ferromagnetic Thin Films with 1-d Periodic Lattice Structure

    AMPERE Congress 2000  2000 

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  • Collective Excitation from Microstructured Ferromagnetic Thin Films with Superlattices on a Semi-Macroscopic Scale

    7th Internatinal Conference on Molecule Based Magnets  2000 

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  • Low-Dimensional Molecule-Based Magnets with Hydrogen-Bonded Network

    International Conference on Science and Technology of Synthetic Metals  2000 

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  • セミマクロスコピック強磁性人工格子薄膜の動的磁気特性

    2000年 分子構造総合討論会  2000 

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  • Structures and Magnetic Properties of Cu (II) Complexes with Hydrogen-Bonded Network; Novel Functionality of Low-Dimensional Molecule-Based Magnets

    7th Internatinal Conference on Molecule Based Magnets  2000 

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  • 強磁性人工格子薄膜のスピン波共鳴現象 II

    第39回 ESR討論会  2000 

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  • 水素結合ネットワーク系Cu(II)錯体の磁性と構造

    2000年 分子構造総合討論会  2000 

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  • フラストレーション系Cu(II)三角クラスターの磁性

    第39回 ESR討論会  2000 

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  • ネットワーク水素結合系低次元Cu(II)磁性体の構造と協同的ヤーン・テラー相互作用

    第39回 ESR討論会  2000 

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  • Correlation between Magnetism and Hydrogen-bonding Network in Cu(II) Complexes with Violuric Acid Ligands

    Pacifichem 2000  2000 

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  • Correlation between Magnetism and Hydrogen-bonding Network in Cu(II) Complexes with Violuric Acid Ligands

    Pacifichem 2000  2000 

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  • Low-Dimensional Molecule-Based Magnets; Structures and Magnetic Properties of Cupper(II) Complexes with Hydrogen-Bonded Network

    AMPERE Congress 2000  2000 

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  • Dynamic Magnetic Properties from Microstructured Ferromagnetic Thin Films with 1-d Periodic Lattice Structure

    AMPERE Congress 2000  2000 

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  • Collective Excitation from Microstructured Ferromagnetic Thin Films with Superlattices on a Semi-Macroscopic Scale

    7th Internatinal Conference on Molecule Based Magnets  2000 

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  • Low-Dimensional Molecule-Based Magnets with Hydrogen-Bonded Network

    International Conference on Science and Technology of Synthetic Metals  2000 

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  • Spin Wave-like Collective Excitations from Microstructured Ferromagnetic Thin Films

    Pacifichem 2000  2000 

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  • Structures and Magnetic Properties of Cu (II) Complexes with Hydrogen-Bonded Network; Novel Functionality of Low-Dimensional Molecule-Based Magnets

    7th Internatinal Conference on Molecule Based Magnets  2000 

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  • 強磁性人工格子薄膜のスピン波共鳴現象

    第38回ESR討論会  1999 

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  • 人工格子薄膜における磁気双極子相互作用を起源とした強磁性スピン波共鳴

    日本化学会 第76春季年会  1999 

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  • 強磁性人工格子薄膜による強磁性スピン波共鳴現象の起源

    1999年分子構造総合討論会  1999 

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  • Novel Spin Wave-like Collective Excitation in Ferromagnetic Microstructured Thin Films

    The 2nd Asia-Pacific EPR/ESR Symposium  1999 

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  • Novel Spin Wave-like Collective Excitation in Ferromagnetic Microstructured Thin Films

    The 2nd Asia-Pacific EPR/ESR Symposium  1999 

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  • Dipolar Spin-Wave from Low-Dimensional Superlattices in Ferromagnetic Thin Films

    Joint 29th AMPERE - 13th ISMAR International Conference  1998 

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  • 磁気双極子相互作用を起源とするスピン波(II):人工格子強磁性薄膜の強磁性共鳴

    第37回ESR討論会  1998 

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  • A Novel Spin Wave from Low-Dimensional Superlattices of Microstructured Ferromagnetic Thin Films

    6th Internatinal Conference on Molecule Based Magnets  1998 

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  • Dipolar Spin Wave in Microstructured Ferromagnetic Thin Films

    International Conference on Science and Technology of Synthetic Metals  1998 

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  • 低次元人工格子薄膜における双極子相互作用を起源とした強磁性スピン波共鳴

    日本化学会第74春季年会  1998 

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  • Dipolar Spin Wave in Microstructured Ferromagnetic Thin Films

    International Conference on Science and Technology of Synthetic Metals  1998 

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  • Dipolar Spin-Wave from Low-Dimensional Superlattices in Ferromagnetic Thin Films

    Joint 29th AMPERE - 13th ISMAR International Conference  1998 

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  • A Novel Spin Wave from Low-Dimensional Superlattices of Microstructured Ferromagnetic Thin Films

    6th Internatinal Conference on Molecule Based Magnets  1998 

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  • 微細加工された磁性薄膜における強磁性スピン波共鳴

    1997年分子構造総合討論会  1997 

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  • 磁気双極子相互作用を起源とするスピン波の検出:微細加工を施した強磁性体薄膜の強磁性共鳴スペクトル

    第36回ESR討論会  1997 

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Awards

  • 平成25年度利用6大成果賞

    2015.1   文部科学省ナノテクノロジープラットフォーム   内包フラーレン分子錯体の特徴的分子磁性のESR測定

    古川 貢

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  • SEST Young Investigator Award

    2012.11   the Society of Electron Spin Science and Technology   Advanced ESR Study of Clarification of Mechanism for Organic Functional Materials

    FURUKAWA Ko

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Research Projects

  • 光誘起伝導性物質の電流検出型電子スピン共鳴法による機能性メカニズム解明

    2015.4 - 2018.3

    System name:科学研究費補助金 基盤研究(C)

    古川 貢

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    Authorship:Principal investigator  Grant type:Competitive

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  • 多周波数ESRを用いた複核金属内包フラーレンアニオンの特異なスピン状態の解明

    2015.4 - 2018.3

    System name:科学研究費補助金 基盤研究(C)

    兒玉 健

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    Grant type:Competitive

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  • 先端磁気共鳴計測による電子対相関の解明

    2013.4 - 2016.3

    System name:科学研究費補助金 基盤研究(B)

    中村 敏和

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    Grant type:Competitive

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  • 光感応性π単結合化合物の創製と機能

    2012.9 - 2017.3

    System name:科学研究費補助金 新学術領域研究(研究領域提案型)

    安倍 学

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  • 機能性物質の時間分解ESRイメージング研究

    2012.4 - 2015.3

    System name:科学研究費補助金 挑戦的萌芽研究

    古川 貢

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  • 次世代太陽光エネルギー”希土類色素増感太陽電池”のスピンダイナミクス研究

    2009 - 2011

    System name:科学研究費補助金 若手研究(A)

    古川 貢

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  • 光誘起機能性材料のアドバンスドESRによるスピンダイナミクス研究

    2009 - 2010

    System name:科学研究費補助金 新学術領域研究(研究領域提案型)

    古川 貢

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  • 低次元系の特異な電子相を利用したデバイス創製ならびにスピンダイナミックス研究

    2008.4 - 2012.3

    System name:科学研究費補助金 基盤研究(B)

    中村 敏和

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  • Relationship between spin-dynamics and photo-electric conversion characteristic of Dye-Sensitized Solar Cell

    2006 - 2008

    System name:Grant-in-Aid for Scientific Research

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    Grant type:Competitive

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  • 色素増感太陽電池の光電変換特性とスピンダイナミクスの相関

    2006 - 2008

    System name:科学研究費補助金 若手研究(B)

    古川 貢

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  • セミマクロスコピックスケールの巨大磁気モーメントイメージング

    2004 - 2005

    System name:科学研究費補助金 若手研究(B)

    古川 貢

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  • 有機導体の電子構造,スピン構造,分子構造の相関

    2004

    System name:科学研究費補助金

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    Grant type:Competitive

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  • electron spin resonance imaging of gigantic magnetic moment

    2004

    System name:Grant-in-Aid for Scientific Research

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    Grant type:Competitive

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  • correlation between molecular structure and electronic structure of organic conductors

    2004

    System name:Grant-in-Aid for Scientific Research

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  • 分子導体における電荷の局在性と遍歴性の研究

    Grant number:15073223

    2003 - 2007

    System name:科学研究費助成事業

    Research category:特定領域研究

    Awarding organization:日本学術振興会

    薬師 久弥, 山本 薫, 中村 敏和, 古川 貢, 秋田 素子, 藤山 茂樹

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    Grant amount:\50200000 ( Direct Cost: \50200000 )

    この研究では電荷秩序状態へ相転移する分子導体の相転移前後における電子状態(遍歴状態と局在状態)を赤外・ラマン分光法と磁気共鳴法を用いて解明することを目的としている。
    (1) 振動分光法による研究
    BEDT-TTFにおける電荷量と振動数の関係を精査し、ラマン活性なv_2モードと赤外活性なv_<27>モードについて新たな関係式を提唱した。これは振動分光法による研究の基礎となる重要な結果である。まず、バンド幅の異なる6種類のθ-(BEDT-TTF)_2Xを系統的に調べ、電荷秩序状態の配列様式を決定した。また、従来金属相と考えられてきた高伝導相はすでに不均化が発生しており、局在性の強い電子状態であることを明らかにした。β"-型BEDT-TTF塩を系統的に調べ、超伝導相に隣接する電子状態は振幅の小さな電荷秩序ゆらぎをもつ相である事を見出した。また、β-型のmeso-DMBEDT-TTF塩の圧力-温度相図を調べ、超伝導相に隣接するのは短距離秩序をもってゆらいでいる電荷秩序相である事を明らかにした。両方と超伝導相と電荷秩序相の関係を明らかにした重要な結果である。さらに、β"-(BEDT-TTF)(TCNQ)では高温の電荷秩序相が低温で融解するという異常な現象を見出した。
    (2) 磁気共鳴法による研究
    (TMTTF)_2Xの電荷秩序相転移を^<13>C-NMRならびに多周波ESR法によって研究した。まず、Type IIの塩(X=PF_6, AsF_6, SbF_6)と同様にType I(X=ReO4)およびType III(X=SCN)の塩でも電荷秩序相転移を起すことを明らかにした。とくに、PF_6塩の電荷秩序の振幅がρ〜0.14であることを明らかにし、さらに低温で発生するスピン・パイエルスそうではこの電荷密度波が解消することを明らかにすることができた。

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  • Novel charp pulse magnetic resonance method using field-jump

    2002 - 2003

    System name:Grant-in-Aid for Scientific Research

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  • フィールドジャンプを用いた新しいチャープパルス磁気共鳴測定法

    2002 - 2003

    System name:科学研究費補助金 萌芽研究

    加藤 立久

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    Grant type:Competitive

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  • 金属内包フラーレンの高磁場/高周波ESRによる研究

    2001 - 2003

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    Grant type:Competitive

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  • High-Field / High-Frequency ESR of Endhedral MetalloFullerenes

    2001 - 2003

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    Grant type:Competitive

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  • セミマクロ系に出現する新しい量子磁気機能の磁気共鳴による研究

    1998 - 2000

    System name:科学研究費補助金

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    Grant type:Competitive

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  • Novel quantum magnetic function in semi-macroscopic scale as studied by magnetic resonance spectroscopy

    1998 - 2000

    System name:Grant-in-Aid for Scientific Research

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Teaching Experience (researchmap)

Teaching Experience

  • 化学特論III

    2025
    Institution name:新潟大学

  • Chemistry TodayI

    2023
    Institution name:新潟大学

  • 統合化学入門

    2023
    Institution name:新潟大学

  • 化学コロキウム

    2022
    Institution name:新潟大学

  • 課題研究

    2022
    -
    2023
    Institution name:新潟大学

  • 反応化学概論

    2021
    Institution name:新潟大学

  • Advances in Physics and Chemistry

    2021
    Institution name:新潟大学

  • 課題研究 b

    2020
    Institution name:新潟大学

  • 課題研究 a

    2020
    Institution name:新潟大学

  • 化学基礎実習a

    2018
    Institution name:新潟大学

  • 化学基礎A

    2014
    Institution name:新潟大学

  • 量子化学演習

    2014
    Institution name:新潟大学

  • 化学実験II

    2014
    -
    2018
    Institution name:新潟大学

  • 大型機器分析技術

    2013
    Institution name:新潟大学

  • 反応化学概論

    2013
    -
    2021
    Institution name:新潟大学

  • 量子反応動力学

    2013
    -
    2014
    Institution name:新潟大学

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