Updated on 2026/06/25

写真a

 
YAMAUCHI Kazuo
 
Organization
. Specially Appointed Professor
Title
Specially Appointed Professor
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Degree

  • Ph.D. (Engineering) ( 2001.7   Tokyo Institute of Technology )

  • M.Sc. (Science) ( 1994.3   International Christian University )

  • B.A. (Liberal Arts) ( 1992.3   International Christian University )

Research Interests

  • Instrumental Analysis

  • Solid-State NMR

  • Method Development

  • Instrument Development

  • Shared Facilities

  • Instrumentation Operation

  • Research Infrastructure

  • Analytical Chemistry

  • NMR Spectroscopy

  • Structural Analysis

Research Areas

  • Nanotechnology/Materials / Inorganic materials and properties

  • Nanotechnology/Materials / Applied physical properties

  • Manufacturing Technology (Mechanical Engineering, Electrical and Electronic Engineering, Chemical Engineering) / Measurement engineering

  • Nanotechnology/Materials / Analytical chemistry

  • Nanotechnology/Materials / Fundamental physical chemistry

  • Nanotechnology/Materials / Structural organic chemistry and physical organic chemistry

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Research History (researchmap)

  • Niigata University   Institute for Research Administration   Professor

    2026

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  • Okinawa Institute of Science and Technology Graduate University   Instrumental Analysis Section   Manager

    2017 - 2026

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  • Nazarbayev University   School of Science and Technology   Assistant Professor

    2014 - 2015

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  • King Abdullah University of Science and Technology   Imaging and Characterization Core lab   Senior Research Scientist / Lead

    2010 - 2014

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  • Tokyo University of Agriculture and Technology   Faculty of Engineering   Assistant Professor

    2004 - 2010

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  • University of Nijmegen   Solid State NMR   Post-doctoral Researcher

    2001 - 2004

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  • Bruker Japan Co. Ltd.   Application   Application chemist

    1994 - 2000

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Research History

  • Niigata University   Specially Appointed Professor

    2026.3

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    Country:Japan

  • Okinawa Institute of Science and Technology   Instrumental Analysis Section

    2017.4 - 2026.2

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    Country:Japan

  • Nazarbayev University   School of Scince and Technology

    2014.7 - 2015.8

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    Country:Kazakhstan

  • King Abdullah University of Science and Technology   NMR Core Facility

    2009.2 - 2014.7

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    Country:Saudi Arabia

  • Tokyo University of Agriculture and Technology   Assistant Professor

    2004.2 - 2010.1

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    Country:Japan

  • University of Nijmegen   Solid State NMR

    2001.7 - 2004.1

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    Country:Netherlands

  • 日本ブルカー株式会社   アプリケーション部

    1994.4 - 2000.12

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    Country:Japan

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Education

  • Tokyo Institute of Technology   Graduate School of Science and Engineering   Department of Chemistry and Materials Science

    - 2001.7

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Professional Memberships

  • The Nuclear Magnetic Resonance Society of Japan

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Papers

  • Application of Benchtop NMR for Metabolomics Study Using Feces of Mice with DSS-Induced Colitis. Reviewed International journal

    Zihao Song, Yuki Ohnishi, Seiji Osada, Li Gan, Jiaxi Jiang, Zhiyan Hu, Hiroyuki Kumeta, Yasuhiro Kumaki, Yuki Yokoi, Kiminori Nakamura, Tokiyoshi Ayabe, Kazuo Yamauchi, Tomoyasu Aizawa

    Metabolites   13 ( 5 )   2023.4

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    Nuclear magnetic resonance (NMR)-based metabolomics, which comprehensively measures metabolites in biological systems and investigates their response to various perturbations, is widely used in research to identify biomarkers and investigate the pathogenesis of underlying diseases. However, further applications of high-field superconducting NMR for medical purposes and field research are restricted by its high cost and low accessibility. In this study, we applied a low-field, benchtop NMR spectrometer (60 MHz) employing a permanent magnet to characterize the alterations in the metabolic profile of fecal extracts obtained from dextran sodium sulfate (DSS)-induced ulcerative colitis model mice and compared them with the data acquired from high-field NMR (800 MHz). Nineteen metabolites were assigned to the 60 MHz 1H NMR spectra. Non-targeted multivariate analysis successfully discriminated the DSS-induced group from the healthy control group and showed high comparability with high-field NMR. In addition, the concentration of acetate, identified as a metabolite with characteristic behavior, could be accurately quantified using a generalized Lorentzian curve fitting method based on the 60 MHz NMR spectra.

    DOI: 10.3390/metabo13050611

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  • Novel understanding of calcium silicate hydrate from dilute hydration Reviewed

    Lina Zhang, Kazuo Yamauchi, Zongjin Li, Xixiang Zhang, Hongyan Ma, Shenguang Ge

    Cement and Concrete Research   99   95 - 105   2017.9

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    DOI: 10.1016/j.cemconres.2017.04.016

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  • Nano-mole scale sequential signal assignment by (1)H-detected protein solid-state NMR. Reviewed International journal

    Songlin Wang, Sudhakar Parthasarathy, Yiling Xiao, Yusuke Nishiyama, Fei Long, Isamu Matsuda, Yuki Endo, Takahiro Nemoto, Kazuo Yamauchi, Tetsuo Asakura, Mitsuhiro Takeda, Tsutomu Terauchi, Masatsune Kainosho, Yoshitaka Ishii

    Chemical communications (Cambridge, England)   51 ( 81 )   15055 - 8   2015.10

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    DOI: 10.1039/c5cc04618a

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  • Nano-mole scale side-chain signal assignment by 1H-detected protein solid-state NMR by ultra-fast magic-angle spinning and stereo-array isotope labeling. Reviewed International journal

    Songlin Wang, Sudhakar Parthasarathy, Yusuke Nishiyama, Yuki Endo, Takahiro Nemoto, Kazuo Yamauchi, Tetsuo Asakura, Mitsuhiro Takeda, Tsutomu Terauchi, Masatsune Kainosho, Yoshitaka Ishii

    PloS one   10 ( 4 )   e0122714   2015.4

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    DOI: 10.1371/journal.pone.0122714

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  • Harvesting solar light with crystalline carbon nitrides for efficient photocatalytic hydrogen evolution. Reviewed International journal

    Manas K Bhunia, Kazuo Yamauchi, Kazuhiro Takanabe

    Angewandte Chemie (International ed. in English)   53 ( 41 )   11001 - 5   2014.10

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    DOI: 10.1002/anie.201405161

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  • Very fast magic angle spinning (1)H-(14)N 2D solid-state NMR: sub-micro-liter sample data collection in a few minutes. Reviewed International journal

    Yusuke Nishiyama, Yuki Endo, Takahiro Nemoto, Hiroaki Utsumi, Kazuo Yamauchi, Katsuya Hioka, Tetsuo Asakura

    Journal of magnetic resonance (San Diego, Calif. : 1997)   208 ( 1 )   44 - 8   2011.1

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    DOI: 10.1016/j.jmr.2010.10.001

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  • Microscopic structural analysis of fractured silk fibers from Bombyx mori and Samia cynthia ricini using 13C CP/MAS NMR with a 1mm microcoil MAS NMR probehead. Reviewed International journal

    Kazuo Yamauchi, Shizuo Yamasaki, Rui Takahashi, Tetsuo Asakura

    Solid state nuclear magnetic resonance   38 ( 1 )   27 - 30   2010.7

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    DOI: 10.1016/j.ssnmr.2010.06.002

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  • Molecular dynamics and orientation of stretched rubber by solid-state <sup>13</sup>C NMR Reviewed

    Hideaki Kimura, Hidehiko Dohi, Marina Kotani, Takanobu Matsunaga, Kazuo Yamauchi, Hironori Kaji, Hiromichi Kurosu, Tetsuo Asakura

    Polymer Journal   42 ( 1 )   25 - 30   2010.1

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    DOI: 10.1038/pj.2009.307

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  • Heterogeneous structure of poly(glycolic acid) fiber studied with differential scanning calorimeter, X-ray diffraction, solid-state NMR and molecular dynamic simulation Reviewed

    Sokei Sekine, Kazuo Yamauchi, Akihiro Aoki, Tetsuo Asakura

    Polymer   50 ( 25 )   6083 - 6090   2009.11

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    DOI: 10.1016/j.polymer.2009.10.040

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  • Structural analysis of the Gly-rich region in spider dragline silk using stable-isotope labeled sequential model peptides and solid-state NMR. Reviewed International journal

    Erika Yamaguchi, Kazuo Yamauchi, Terry Gullion, Tetsuo Asakura

    Chemical communications (Cambridge, England)   ( 28 )   4176 - 8   2009.7

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    DOI: 10.1039/b906145b

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  • Intra- and intermolecular effects on 1H chemical shifts in a silk model Peptide determined by high-field solid state 1H NMR and empirical calculations. Reviewed International journal

    Yu Suzuki, Rui Takahashi, Tadashi Shimizu, Masataka Tansho, Kazuo Yamauchi, Mike P Williamson, Tetsuo Asakura

    The journal of physical chemistry. B   113 ( 29 )   9756 - 61   2009.7

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    DOI: 10.1021/jp903020p

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  • Development of silk-like materials based on Bombyx mori and Nephila clavipes dragline silk fibroins Reviewed

    Mingying Yang, Junji Kawamura, Zhenghua Zhu, Kazuo Yamauchi, Tetsuo Asakura

    Polymer   50 ( 1 )   117 - 124   2009.1

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    DOI: 10.1016/j.polymer.2008.10.008

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  • Detection of poorly-oriented component in uniaxially stretched poly(glycolic acid) fiber studied using <sup>13</sup>C solid-state NMR Reviewed

    Sokei Sekine, Wataru Sakiyama, Kazuo Yamauchi, Tetsuo Asakura

    Polymer Journal   41 ( 8 )   582 - 583   2009

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    DOI: 10.1295/polymj.PJ2009050

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  • High field 17O solid-state NMR study of alanine tripeptides. Reviewed International journal

    Kazuo Yamauchi, Michi Okonogi, Hiromichi Kurosu, Masataka Tansho, Tadashi Shimizu, Terry Gullion, Tetsuo Asakura

    Journal of magnetic resonance (San Diego, Calif. : 1997)   190 ( 2 )   327 - 32   2008.2

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    DOI: 10.1016/j.jmr.2007.11.006

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  • Silklike materials constructed from sequences of Bombyx mori silk fibroin, fibronectin, and elastin. Reviewed International journal

    Mingying Yang, Chikako Tanaka, Kazuo Yamauchi, Kosuke Ohgo, Masato Kurokawa, Tetsuo Asakura

    Journal of biomedical materials research. Part A   84 ( 2 )   353 - 63   2008.2

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    DOI: 10.1002/jbm.a.31348

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  • Structural analysis of (ALA)<inf>N</inf> in crystalline region of silk fibroins using solid-state NMR

    Kazuo Yamauchi, Kumiko Horiguchi, Michi Okonogi, Tetsuo Asakura

    American Chemical Society, Polymer Preprints, Division of Polymer Chemistry   49 ( 1 )   732 - 733   2008

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  • Design of silk-like biomaterials inspired by mussel-adhesive protein. Reviewed International journal

    Mingying Yang, Kazuo Yamauchi, Masato Kurokawa, Tetsuo Asakura

    Tissue engineering   13 ( 12 )   2941 - 7   2007.12

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    DOI: 10.1089/ten.2006.0448

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  • High-field 1H MAS and 15N CP-MAS NMR studies of alanine tripeptides and oligomers: distinction of antiparallel and parallel beta-sheet structures and two crystallographically independent molecules. Reviewed International journal

    Yu Suzuki, Michi Okonogi, Kazuo Yamauchi, Hiromichi Kurosu, Masataka Tansho, Tadashi Shimizu, Hazime Saitô, Tetsuo Asakura

    The journal of physical chemistry. B   111 ( 30 )   9172 - 8   2007.8

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    DOI: 10.1021/jp072755z

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  • Role of hydroxyl side chains in Bombyx mori silk sericin in stabilizing its solid structure Reviewed

    Hidetoshi Teramoto, Aya Kakazu, Kazuo Yamauchi, Tetsuo Asakura

    Macromolecules   40 ( 5 )   1562 - 1569   2007.3

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    DOI: 10.1021/ma062604e

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  • Communications to the editor: <sup>13</sup>C-<sup>17</sup>O REAPDOR NMR as a tool for determining secondary structure in polyamides Reviewed

    Terry Gullion, Kazuo Yamauchi, Michi Okonogi, Tetsuo Asakura

    Macromolecules   40 ( 5 )   1363 - 1365   2007.3

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    DOI: 10.1021/ma062835l

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  • Characterization of molecular orientation of stretched natural rubber by solid-state<sup>13</sup>C NMR Reviewed

    Hidehiko Dohi, Hideaki Klmura, Marina Kotani, Takanobu Matsunaga, Kazuo Yamauchi, Hironori Kaji, Tetsuo Asakura

    Polymer Journal   39 ( 6 )   502 - 503   2007

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    DOI: 10.1295/polymj.PJ2006220

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  • Structural analysis of alanine tripeptide with antiparallel and parallel beta-sheet structures in relation to the analysis of mixed beta-sheet structures in Samia cynthia ricini silk protein fiber using solid-state NMR spectroscopy. Reviewed International journal

    Tetsuo Asakura, Michi Okonogi, Yasumoto Nakazawa, Kazuo Yamauchi

    Journal of the American Chemical Society   128 ( 18 )   6231 - 8   2006.5

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    DOI: 10.1021/ja060251t

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  • Development of MicroMAS NMR probehead for mass-limited solid-state samples Reviewed

    Kazuo Yamauchi, Tetsuo Asakura

    Chemistry Letters   35 ( 4 )   426 - 427   2006.4

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    DOI: 10.1246/cl.2006.426

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  • Solid-state NMR studies on alanine oligomers with parallel and anti-parallel β-sheet structures in relation to the structural analysis of Samia cynthia ricini silk fiber

    Michi Okonogi, Akiko Mori, Naoki Asakawa, Kazuo Yamauchi, Tetsuo Asakura

    Polymer Preprints, Japan   55 ( 1 )   1830   2006

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  • Structural study of elongated natural rubber by solid-state NMR

    Hideaki Kimura, Hidehiko Dohi, Marina Kotani, Takanobu Matsunaaa, Kazuo Yamauchi, Tetsuo Asakura

    Polymer Preprints, Japan   55 ( 1 )   859   2006

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  • Development of NMR probehead for silk fibers with μg sample volume

    Kazuo Yamauchi, Daisuke Hasegawa, Tetsuo Asakura

    Polymer Preprints, Japan   55 ( 1 )   725   2006

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  • <sup>17</sup>O NMR studies of biopolymers with β-sheet structure using 930MHz solid state NMR and chemical shift calculation

    Kazuo Yamauchi, Michi Okonogi, Hiromichi Kurosu, Takahiro Nemoto, Masataka Tansho, Shimizu Tadashi, Tetsuo Asakura

    Polymer Preprints, Japan   55 ( 2 )   4188 - 4189   2006

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  • Structure of model peptides based on Nephila clavipes dragline silk spidroin (MaSp1) studied by 13C cross polarization/magic angle spinning NMR. Reviewed International journal

    Mingying Yang, Yasumoto Nakazawa, Kazuo Yamauchi, David Knight, Tetsuo Asakura

    Biomacromolecules   6 ( 6 )   3220 - 6   2005.11

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    DOI: 10.1021/bm050550v

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  • Use of microcoil probehead for determination of the structure of oriented silk fibers by solid-state NMR Reviewed

    K. Yamauchi, T. Imada, T. Asakura

    Journal of Physical Chemistry B   109 ( 37 )   17689 - 17692   2005.9

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    DOI: 10.1021/jp052441g

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  • Development of microMAS probehead and its application to mass limited polymers

    Kazuo Yamauchi, Daisuke Hasegawa, Tetsuo Asakura

    Polymer Preprints, Japan   54 ( 2 )   3197 - 3198   2005

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  • Liquid crystal formation of Bombyx mori silk fibroin in hexafluoroacetone and preparation of regenerated silk fiber with high strength

    Teizo Imada, David P. Knight, Shigetoshi Amiya, Kiyofumi Enomoto, Shigemitu Murase, Kazuo Yamauchi, Tetsuo Asakura

    Polymer Preprints, Japan   54 ( 1 )   1501   2005

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  • Structural analysis of alanine tripeptide with anti-parallel and parallel β-sheet structures using solid state NMR (RFDR and REDOR) methods

    Michi Okonogi, Akiko Mori, Kazuo Yamauchi, Tetsuo Asakura

    Polymer Preprints, Japan   54 ( 2 )   3113 - 3114   2005

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  • Design, synthesis and fiber formation of silk-like proteins constructed from the sequences selected from Bombyx mori, Samia cynthia ricini and spider silks

    Mingying Yang, Junji Kawamura, Kazuo Yamauchi, Tetsuo Asakura

    Polymer Preprints, Japan   54 ( 1 )   2295   2005

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  • NMR structural analysis of silk sericin prepared from fibroin-deficient silkworm

    Hidetoshi Teramoto, Yasumoto Nakazawa, Kazuo Yamauchi, Tetsuo Asakura

    Polymer Preprints, Japan   54 ( 1 )   2292   2005

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  • Structural analysis of alanine tripeptides using solid-State NMR (RFDR and REDOR) methods

    Michi Okonogi, Kazuo Yamauchi, Tetsuo Asakura

    Polymer Preprints, Japan   54 ( 1 )   724   2005

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  • Development of microcoil probehead for solid state NMR and its application to fibril polymers

    Kazuo Yamauchi, Teizo Imada, Tetsuo Asakura

    Polymer Preprints, Japan   54 ( 1 )   775   2005

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  • Implementing solenoid microcoils for wide-line solid-state NMR Reviewed

    K. Yamauchi, J. W.G. Janssen, A. P.M. Kentgens

    Journal of Magnetic Resonance   167 ( 1 )   87 - 96   2004.3

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    DOI: 10.1016/j.jmr.2003.12.003

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  • Proton NMR chemical shift behavior of hydrogen-bonded amide proton ofglycine-containing peptides and polypeptides as studied by ab initio MOcalculation Reviewed

    S. Hori, K. Yamauchi, S. Kuroki, I. Ando

    International Journal of Molecular Sciences   3 ( 8 )   907 - 913   2002.8

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    DOI: 10.3390/i3080907

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  • Structural characterization of nylon 4 in the solid state by high-resolution solid-state <sup>1</sup>H NMR spectroscopy Reviewed

    Kazuo Yamauchi, Shigeki Kuroki, Isao Ando

    Polymer   43 ( 11 )   3331 - 3333   2002.4

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    DOI: 10.1016/S0032-3861(02)00164-7

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  • A structural study of silicon-based interpenetrating polymer networks by solid state <sup>1</sup>H and <sup>13</sup>C NMR spectroscopy Reviewed

    Masatoshi Kobayashi, Shigeki Kuroki, Isao Ando, Kazuo Yamauchi, Hideaki Kimura, Koichi Okita, Manabu Tsumura, Keisuke Sogabe

    Journal of Molecular Structure   602-603   321 - 333   2002.1

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    DOI: 10.1016/S0022-2860(01)00776-1

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  • The amide proton NMR chemical shift and hydrogen-bonded structure of glycine-containing peptides and polypeptides in the solid state as studied by multi-pulse-associated high-speed MAS <sup>1</sup>H NMR Reviewed

    Kazuo Yamauchi, Shigeki Kuroki, Isao Ando

    Journal of Molecular Structure   602-603   9 - 16   2002.1

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    DOI: 10.1016/S0022-2860(01)00781-5

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  • High-resolution solid-state <sup>17</sup>O NMR studies of polyglycines and their hydrogen-bonded structures Reviewed

    Kazuo Yamauchi, Shigeki Kuroki, Isao Ando

    Journal of Molecular Structure   602-603   171 - 175   2002.1

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    DOI: 10.1016/S0022-2860(01)00779-7

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  • A study of hydrogen-bonding of amino acids, peptides and polypeptides in the solid state as a function of temperature by static <sup>2</sup>H NMR method Reviewed

    Shinnosuke Ono, Takashi Taguma, Shigeki Kuroki, Isao Ando, Hideaki Kimura, Kazuo Yamauchi

    Journal of Molecular Structure   602-603   49 - 58   2002.1

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    DOI: 10.1016/S0022-2860(01)00770-0

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  • Solid-state <sup>1</sup>H-static, <sup>1</sup>H-MAS, and <sup>1</sup>H → <sup>19</sup>F/<sup>19</sup>F → <sup>1</sup>H CP/MAS NMR study of poly(vinyl fluoride) Reviewed

    Shinji Ando, Robin K. Harris, Peter Holstein, Stefan A. Reinsberg, Kazuo Yamauchi

    Polymer   42 ( 19 )   8137 - 8151   2001.6

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    DOI: 10.1016/S0032-3861(01)00303-2

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  • <sup>17</sup>O-isotope labeling and hydrogen-bonded structure investigation in peptides and polypeptides by solid state <sup>17</sup>O NMR Reviewed

    Shigeki Kuroki, Kazuo Yamauchi, Isao Ando, Akira Shoji, Takuo Ozaki

    Current Organic Chemistry   5 ( 10 )   1001 - 1015   2001

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  • The amide proton NMR chemical shift and hydrogen-bonded structure of peptides and polypeptides in the solid state as studied by high-frequency solid-state <sup>1</sup>H NMR Reviewed

    Kazuo Yamauchi, Shigeki Kuroki, Kazuma Fujii, Isao Ando

    Chemical Physics Letters   324 ( 5-6 )   435 - 439   2000.7

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    DOI: 10.1016/S0009-2614(00)00543-1

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  • <sup>17</sup>O NMR chemical shifts and quadrupole coupling constants in solid poly(L-alanine)s determined using a high-speed MAS technique Reviewed

    Kazuo Yamauchi, Shigeki Kuroki, Isao Ando, Takuo Ozaki, Akira Shoji

    Chemical Physics Letters   302 ( 3-4 )   331 - 336   1999.3

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    DOI: 10.1016/S0009-2614(99)00127-X

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  • NMR imaging of <sup>1</sup>H in hydrous minerals Reviewed

    Yoshito Nakashima, Satoru Nakashima, Dieter Gross, Karlheinz Weiss, Kazuo Yamauchi

    Geothermics   27 ( 1 )   43 - 53   1998.2

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    DOI: 10.1016/S0375-6505(97)00029-1

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Books

  • 広がるNMRの世界 -40人の研究者からの熱いメッセージ-

    山内 一夫( Role: Joint author ,  超微量高速固体NMRプローブの開発)

    コロナ社  2011.4  ( ISBN:9784339066197

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MISC

  • Study of analysis techniques using benchtop NMR for biological samples

    相沢智康, SONG Zihao, GAN Li, JIANG Jiaxi, HU Zhiyan, 大西裕季, 長田誠司, 久米田博之, 熊木康裕, 山内一夫

    Abstracts. Annual Meeting of the NMR Society of Japan   61st   2022

  • 固体<sup>19</sup>F MAS NMRとWAXD測定を用いたVDF-TFE共重合体の結晶構造と分子運動性の解析

    大橋龍二, 山田和彦, 安藤慎治, 山内一夫

    高分子学会予稿集(CD-ROM)   61 ( 1 )   2012

  • 固体<sup>15</sup>NNMRを用いた鉄含有ポリアニリン炭素化物の構造解析

    黒木重樹, 上口憲陽, 木村英昭, 山内一夫

    Abstracts. Annual Meeting of the NMR Society of Japan   51st   2012

  • 芳香族ポリアミド硬化物の固体NMR研究

    松本光貴, 松本光貴, 浅野敦志, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   60 ( 1 Disk1 )   2011

  • 架橋を制御したポリアミドに関する固体NMR研究

    松本光貴, 松本光貴, 浅野敦志, 山内一夫, 朝倉哲郎

    日本化学会講演予稿集   91st ( 3 )   2011

  • 架橋基含有ポリアミドの合成とその架橋物の構造解析

    松本光貴, 松本光貴, 浅野敦志, 山内一夫, 朝倉哲郎

    固体NMR・材料フォーラム報告   ( 48 )   2010

  • 超高速MASのもとでの<sup>1</sup>H-<sup>14</sup>N2次元固体NMR:1μL以下の微量試料を数分で測定

    西山裕介, 遠藤由宇生, 根本貴宏, 黒子弘道, 内海博明, 山内一夫, 樋岡克哉, 朝倉哲郎

    Abstracts. Annual Meeting of the NMR Society of Japan   49th   2010

  • クモ牽引糸及びエリ蚕絹繊維の安定同位体<sup>13</sup>Cラベリングと固体NMR構造解析

    山崎静夫, 亀谷俊輔, 山内一夫, 齊藤準, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   59 ( 1 Disk1 )   2010

  • 4メガrpm級慣性気体軸受

    遠藤由宇生, 樋岡克哉, 山内一夫

    日本トライボロジー学会トライボロジー会議予稿集   2010-9   2010

  • <sup>1</sup>H-<sup>14</sup>N 2D solid-state NMR under very fast MAS: A few minutes observation for a sample less than 1mg

    西山裕介, 遠藤由宇生, 根本貴宏, 内海博明, 山内一夫, 樋岡克哉, 朝倉哲郎

    東京コンファレンス講演要旨集   2010   2010

  • Development of Solid State NMR for Small Samples and the Benefits of Using It

    YAMAUCHI Kazuo

    分光研究 = Journal of the spectroscopical research of Japan   58 ( 3 )   113 - 116   2009.6

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  • クモ牽引糸モデルペプチドに関する固体NMR構造解析

    池永万希子, 山口恵理香, 堀口紅実子, 亀谷俊輔, 山内一夫, 朝倉哲郎, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   58 ( 2 Disk1 )   2009

  • 平行および逆平行βシート構造を有するアラニンオリゴペプチドの分子間構造に関する固体NMR解析

    亀谷俊輔, 堀口紅実子, 黒子弘道, 青木昭宏, 山内一夫, 朝倉哲郎, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   58 ( 1 Disk1 )   2009

  • クモ牽引糸,野蚕絹糸間の著しい物性の違いと関連するポリアラニン領域の異なる分子間β構造の発現

    亀谷俊輔, 山内一夫, 朝倉哲郎, 朝倉哲郎

    Abstracts. Annual Meeting of the NMR Society of Japan   48th   2009

  • 1mm超高速MASプローブの開発

    遠藤由宇生, 根本貴宏, 蜂谷健一, 西山裕介, 下池田勇一, 山内一夫, 樋岡克哉

    Abstracts. Annual Meeting of the NMR Society of Japan   48th   2009

  • 1mmφ高速MASプローブによる新たな固体NMR法の可能性

    山内一夫, 西山裕介, 石井佳誉, 朝倉哲郎, 樋岡克哉

    Abstracts. Annual Meeting of the NMR Society of Japan   48th   2009

  • 強くて伸びるクモの糸の分子構造を固体NMRから解き明かす

    山内一夫, 山口恵理香, 青木昭宏, 朝倉哲郎

    繊維学会予稿集   64 ( 1 )   2009

  • 先端分析機器を日本から発信する 3 固体NMRを小型化する 微量な試料で観測できる溶液用NMRにも取り付け可能な固体NMRプローブの開発

    山内一夫

    化学と工業   61 ( 11 )   1047 - 1049   2008.11

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  • POLY 384-Characterization of molecular behavior of stretched rubber by solid-state NMR

    Hideaki Kimura, Hidehiko Dohi, Marina Kotani, Hiromichi Kurosu, Hironori Kaji, Kazuo Yamauchi, Tetsuo Asakura

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   235   2008.4

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  • POLY 544-Structural analysis of (Ala)n in crystalline region of silk fibroins using solid-state NMR

    Kazuo Yamauchi, Kumiko Horiguchi, Michi Okonogi, Tetsuo Asakura

    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY   235   2008.4

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  • 生体吸収縫合糸ポリグリコール酸の延伸にともなう構造変化に関する固体NMR研究

    関根素馨, 関根素馨, 咲山航, 山内一夫, 朝倉哲郎

    Abstracts. Annual Meeting of the NMR Society of Japan   47th   2008

  • アラニンオリゴマーの構造多様性と固体NMR精密構造解析

    堀口紅実子, 山内一夫, GULLION Terry, 古屋秀峰, 山崎俊正, 西内祐二, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   57 ( 2 Disk1 )   2008

  • 絹モデルペプチドの分子内・分子間水素結合に関する高磁場<sup>1</sup>H固体NMRと経験的<sup>1</sup>H化学シフト計算を用いた研究

    鈴木悠, 山内一夫, 朝倉哲郎, WILLIAMSON Mike P

    繊維学会予稿集   63 ( 1/2 )   2008

  • 高い生分解性を有する再生家蚕絹繊維の開発

    ZHU Zhenghua, 長谷川大祐, 中澤靖元, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   57 ( 1 Disk1 )   2008

  • Characterization of molecular behavior of stretched rubber by solid-state NMR

    Hideaki Kimura, Hidehiko Dohi, Marina Kotani, Hiromichi Kurosu, Hironori Kaji, Kazuo Yamauchi, Tetsuo Asakura

    American Chemical Society, Polymer Preprints, Division of Polymer Chemistry   49 ( 1 )   649 - 650   2008

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  • 生体吸収縫合糸ポリグリコール酸の配向構造に関する固体NMR研究

    関根素馨, 関根素馨, 咲山航, 山内一夫, 朝倉哲郎

    繊維学会予稿集   63 ( 1/2 )   2008

  • アラニン連鎖ペプチド平行型および逆平行型βシート構造に関する固体NMR構造解析

    堀口紅実子, 池永万希子, 山内一夫, 朝倉哲郎

    固体NMR・材料フォーラム報告   ( 43/8 )   2008

  • 微量試料用固体NMRプローブの開発

    山内一夫, 朝倉哲郎

    固体NMR・材料フォーラム報告   ( 43/8 )   2008

  • 固体NMR測定用超高速MASプローブの製作と構造解析への応用

    山内一夫, 朝倉哲郎, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   57 ( 1 Disk1 )   2008

  • 平行および逆平行βシート構造を発現するアラニンオリゴマーの固体NMRならびに単結晶X線解析による精密構造の解明

    堀口紅実子, 池永万希子, 青木昭夫, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   57 ( 1 Disk1 )   2008

  • 微量試料用固体NMRプローブの開発とその応用

    山内一夫, 朝倉哲郎

    分析化学討論会講演要旨集   69th   2008

  • 縫合糸として用いられるポリグリコール酸繊維の固体NMR構造解析

    咲山航, 山内一夫, 朝倉哲郎, 関根素馨

    固体NMR・材料フォーラム報告   ( 43/8 )   2008

  • 縫合糸素材;ポリグリコール酸の配向構造と分解挙動に関する固体NMR研究

    関根素馨, 関根素馨, 咲山航, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   57 ( 1 Disk1 )   2008

  • 平行および逆平行β-シート構造ならびにその混在系に関する固体NMR構造解析

    堀口紅実子, 亀谷俊輔, 山内一夫, 朝倉哲郎

    Abstracts. Annual Meeting of the NMR Society of Japan   47th   2008

  • マイクロコイルNMRプローブの製作と微量試料測定

    山内一夫

    NMRマイクロイメージング研究会講演要旨集   11th   2007

  • 高磁場固体<sup>1</sup>Hならびに<sup>17</sup>O-NMR法によるアラニンオリゴマーの構造解析と化学シフト計算

    鈴木悠, 山内一夫, 朝倉哲郎, 黒子弘道, 清水禎, 丹所正孝, WILLIAMSON Mike P

    高分子学会予稿集(CD-ROM)   56 ( 1 Disk1 )   2007

  • マルチコイル高感度固体NMRプローブの開発と生体高分子への応用

    山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   56 ( 2 Disk1 )   2007

  • 絹繊維結晶領域にふくまれるアラニン連鎖の固体NMR高次構造解析

    山内一夫, 小此木美智, 堀口紅実子, 朝倉哲郎

    繊維学会予稿集   62 ( 1 )   2007

  • アラニン四量体の平行及び逆平行βシート構造の<sup>13</sup>C固体NMR解析

    堀口紅実子, 小此木美智, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   56 ( 1 Disk1 )   2007

  • 高磁場固体<sup>1</sup>H NMR法によるアラニンオリゴマーのβシート構造に関する研究

    鈴木悠, 山内一夫, 朝倉哲郎, 黒子弘道, 清水禎, 丹所正孝

    固体NMR・材料フォーラム報告   ( 41/6 )   2007

  • 高磁場固体<sup>1</sup>H及び<sup>17</sup>O-NMR法によるアラニンオリゴマーの構造解析と化学シフト計算

    鈴木悠, 山内一夫, 黒子弘道, 清水禎, 丹所正孝, 朝倉哲郎

    Abstracts. Annual Meeting of the NMR Society of Japan   46th   2007

  • 絹フィブロイン及び絹モデルペプチドに関する高磁場<sup>1</sup>Hならびに<sup>17</sup>O-NMR法による構造解析

    高橋塁, 山内一夫, 丹所正孝, 清水禎, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   56 ( 1 Disk1 )   2007

  • アラニンオリゴマーの平行および逆平行βシート構造に関する固体NMR構造解析

    堀口紅実子, 池永万希子, 山内一夫, 朝倉哲郎

    Abstracts. Annual Meeting of the NMR Society of Japan   46th   2007

  • 超微量用固体NMRプローブの開発

    山内一夫, 朝倉哲郎, 朝倉哲郎

    Abstracts. Annual Meeting of the NMR Society of Japan   46th   2007

  • 固体<sup>13</sup>C NMRによる伸長ゴムの分子挙動解析

    木村英昭, 木村英昭, 土肥英彦, 土肥英彦, 小谷真理奈, 松永貴信, 梶弘典, 黒子弘道, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   56 ( 2 Disk1 )   2007

  • ポリグリコール酸の配向解析

    関根素馨, 関根素馨, 山内一夫, 安藤勲, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   56 ( 2 Disk1 )   2007

  • 既存溶液NMR装置で測定可能な固体高分解能NMRプローブの開発

    山内一夫, 浅野敦志, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   56 ( 1 Disk1 )   2007

  • Magnetic Resonance Spectroscopy V. Practical Solid State NMR

    山内一夫

    分光研究   55 ( 5 )   350 - 359   2006.10

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    Solid state nuclear magnetic resonance (Solid state NMR) is the one of the most powerful analysis method for the chemistry, physics, solid material sciences, bio-molecules and etc. The solid state NMR needs more advanced technique in the field of hardwares and pulse programs to obtain information compare to liquid state NMR. This review introduces these technologies and examples of application.

    DOI: 10.5111/bunkou.55.350

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  • エリ蚕絹繊維の構造解析と関連したβシート構造を有するアラニンオリゴマーの固体NMR研究

    小此木美智, 堀口久美子, 山内一夫, 黒子弘道, 朝倉哲郎

    Abstracts. Annual Meeting of the NMR Society of Japan   45th   2006

  • 固体NMRによる伸張ゴムの分子挙動の研究

    木村英昭, 土肥英彦, 土肥英彦, 小谷真理奈, 松永貴信, 山内一夫, 朝倉哲郎, 梶弘典

    固体NMR・材料研究会報告集   ( 40 )   2006

  • ナノグラム繊維の構造解析をめざした固体NMRプローブの開発

    山内一夫, 朝倉哲郎

    繊維学会予稿集   61 ( 1 )   2006

  • μgオーダーの絹繊維の構造を解析できる新しい固体NMRプローブの開発

    山内一夫, 長谷川大祐, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   55 ( 1 Disk1 )   2006

  • 固体NMRによる天然ゴムの伸長挙動解析

    木村英昭, 土肥英彦, 土肥英彦, 小谷真理奈, 松永貴信, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   55 ( 1 Disk1 )   2006

  • 固体<sup>13</sup>C NMRによる天然ゴムの伸長挙動解析

    木村英昭, 土肥英彦, 小谷真理奈, 山内一夫, 朝倉哲郎

    日本ゴム協会研究発表講演会講演要旨   2006   2006

  • 高磁場固体<sup>17</sup>O NMR法によるβシート構造を有する生体高分子の構造解析と化学シフト計算

    山内一夫, 小此木美智, 黒子弘道, 根本貴宏, 丹所正孝, 清水禎, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   55 ( 2 Disk1 )   2006

  • アラニンオリゴマーの平行および逆平行βシート構造に関する固体NMR研究と野蚕絹繊維の構造解析への応用

    小此木美智, 森亜紀子, 浅川直紀, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   55 ( 1 Disk1 )   2006

  • 微量試料用microMASプローブの開発と生体高分子への応用

    山内一夫, 高橋塁, 朝倉哲郎

    Abstracts. Annual Meeting of the NMR Society of Japan   45th   2006

  • 微量物質の距離測定用マイクロコイルNMRプローブの開発

    山内一夫, 高橋塁, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   55 ( 2 Disk1 )   2006

  • 逆平行及び平行β-sheet構造を有するアラニン三量体の固体NMR(RFDR,REDOR)構造解析

    小此木美智, 森亜紀子, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   54 ( 2 Disk1 )   2005

  • クモ糸及び関連の絹様生体材料の構造ならびに含水による構造変化に関する固体NMR研究

    大郷耕輔, YANG Mingying, 川村純司, 中沢靖元, 山内一夫, 朝倉哲郎

    繊維学会予稿集   60 ( 2 )   2005

  • 繊維状配向試料解析用マイクロコイルNMRプローブの開発

    山内一夫, 今田悌三, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   54 ( 1 Disk1 )   2005

  • 生体高分子精密構造解析のための固体NMR手法(RFDR・REDOR)とそれを用いたアラニン三量体の分子間構造の決定

    小此木美智, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   54 ( 1 Disk1 )   2005

  • ヘキサフルオロアセトン中での絹の液晶形成と高強度絹繊維の作成

    今田悌三, KNIGHT David P, 網屋繁俊, 榎本清文, 村瀬繁満, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   54 ( 1 Disk1 )   2005

  • 絹ならびに遺伝子組み換え法により生産されたクモ絹連鎖を含む絹様材料の液晶形成と高強度絹繊維の作成

    今田悌三, 山内一夫, 朝倉哲郎, 村瀬繁満, 榎本清文, 網屋繁俊, KNIGHT David P

    繊維学会予稿集   60 ( 1 )   2005

  • 微量サンプル用マイクロMASプローブの開発と高分子材料への応用

    山内一夫, 長谷川大祐, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   54 ( 2 Disk1 )   2005

  • フィブロイン合成能が退化したカイコ幼虫から得られる絹セリシンタンパク質のNMR構造解析

    寺本英敏, 寺本英敏, 中沢靖元, 中沢靖元, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   54 ( 1 Disk1 )   2005

  • セリシン蚕から得られる未変性セリシンタンパク質のNMR構造解析

    寺本英敏, 寺本英敏, 中沢靖元, 中沢靖元, 山内一夫, 朝倉哲郎

    日本蚕糸学会大会・蚕糸・昆虫機能学術講演会講演要旨集   75th   2005

  • 家蚕ならびにエリ蚕絹とクモ糸の特徴的配列を組み合わせた新規絹様タンパク質の設計・大腸菌による生産・繊維化の試み

    YANG Mingying, 川村純司, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   54 ( 1 Disk1 )   2005

  • 固体高分解能NMR法によるペプチド分子間構造決定法の開発

    山内一夫, 小此木美智, 松崎光隆, 中沢靖元, 朝倉哲郎

    NMR討論会講演要旨集   43rd   2004

  • 固体NMR法による生体高分子分子間構造決定法の開発

    山内一夫, 小此木美智, 松崎光隆, 茂呂ふみか, 朝倉哲郎, 中沢靖元

    高分子学会予稿集(CD-ROM)   53 ( 2 Disk1 )   2004

  • ラメラ構造を有する安定同位体ペプチドの固体NMR精密構造解析

    中沢靖元, 大西絵里佳, 茂呂ふみか, 山内一夫, 安藤勲, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   53 ( 2 Disk1 )   2004

  • 遺伝子組み換え法を用いたクモならびにクモ・カイコ融合絹タンパク質の作成とキャラクタリゼーション

    川村純司, YANG M, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   53 ( 2 Disk1 )   2004

  • ナノ材料解析用固体NMRマイクロコイルプローブの開発と応用

    山内一夫, 今田悌三, 小此木美智, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   53 ( 2 Disk1 )   2004

  • 絹セリシンフィルムの分子配向メカニズム

    寺本英敏, 宮沢光博, 山内一夫, 朝倉哲郎

    高分子学会予稿集(CD-ROM)   53 ( 2 Disk1 )   2004

  • 固体NMRマイクロコイルプローブの開発と繊維状高分子の配向度解析

    山内一夫, 今田悌三, 朝倉哲郎

    NMR討論会講演要旨集   43rd   2004

  • 微量サンプル・表面サンプル用高感度固体NMRプローブの製作と材料系サンプルへの応用

    山内一夫, JANSSEN H, VAN BENTUM J, KENTGENS A P M

    NMR討論会講演要旨集   42nd   2003

  • ペプチドおよびポリペプチド中のカルボニル酸素の<sup>17</sup>ONMRパラメータの決定

    黒木重樹, 山内一夫, 安藤勲, 荘司顕, 尾崎拓男, PRUSKI M

    高分子学会予稿集   51 ( 5 )   2002

  • ペプチドおよびポリペプチド中のカルボニル酸素の固体<sup>17</sup>O NMRパラメータの決定

    黒木重樹, 山内一夫, 木村英昭, 安藤勲, 荘司顕, 尾崎拓男, PRUSKI M

    NMR討論会講演要旨集   41st   2002

  • 固体NMR/磁場勾配NMR法による尿素アダクト中の長鎖n-パラフィンの構造やダイナミックス

    KIM S, 山内一夫, 木村英昭, 黒木重樹, 安藤勲

    高分子学会予稿集   50 ( 9 )   2001

  • 拡散NMRイメージング法によるポリメタクリル酸ゲル中の金属イオンおよび水の拡散過程の研究

    佐々木暁嗣, 堀田芳夫, 山内一夫, 黒木重樹, 安藤勲

    ネットワークポリマー講演討論会講演要旨集   51st ( 0 )   77 - 80   2001

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    Language:Japanese   Publisher:合成樹脂工業協会  

    DOI: 10.11364/networkpolymer1996.22.Supplement_77

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  • グリシン及びポリグリシンの<sup>13</sup>C/<sup>1</sup>H NMR化学シフトテンソルと水素結合構造

    堀聡史, 山内一夫, 黒木重樹, 安藤勲

    高分子学会予稿集   50 ( 10 )   2001

  • 固体<sup>2</sup>HNMRによるペプチドの水素結合研究

    黒木重樹, 小野真之介, 安藤勲, 山内一夫

    繊維学会予稿集   56 ( 1 )   2001

  • <sup>17</sup>O高磁場高分解能固体NMR法を用いたポリペプチドの構造解析

    山内一夫, 黒木重樹, 安藤勲

    高分子学会予稿集   50 ( 3 )   2001

  • 固体<sup>1</sup>H→<sup>19</sup>F/<sup>19</sup>F→<sup>1</sup>H CP/MAS NMRを用いたポリ(フッ化ビニル)の構造解析

    安藤慎治, HARRIS R K, REINSBERG S A, HOLSTEIN P, 山内一夫

    高分子学会予稿集   49 ( 3 )   2000

  • High-Resolution Solid-State <sup>1</sup>H NMR Spectral Observation of Peptides with Frequency-Switched Lee-Goldburg Decoupling Method.

    山内一夫, 黒木重樹, 安藤勲

    NMR討論会講演要旨集   39th   2000

  • 固体<sup>2</sup>H NMRによるペプチドおよびポリペプチドの水素結合の研究 (II)

    小野真之介, 黒木重樹, 安藤勲, 山内一夫, 木村英昭

    高分子学会予稿集   49 ( 9 )   2000

  • <sup>17</sup>O NMR chemical shifts in peptides

    S. Kuroki, K. Yamauchi, Hiromichi Kurosu, S. Ando, Isao Ando, A. Shoji, T. Ozaki

    ACS Symposium Series   732   126 - 137   1999

  • Chemical Shifts and Structural Analysis of Peptides and Polypeptides Using High Field High Resolution Solid State <sup>1</sup>H NMR.

    山内一夫, 黒木重樹, 藤井一馬, 安藤勲

    NMR討論会講演要旨集   38th   1999

  • Structural Analysis of Polymers Using <sup>2</sup>H MAS NMR Methods.

    黒木重樹, 小野真之介, 安藤勲, 木村英昭, 山内一夫

    NMR討論会講演要旨集   38th   1999

  • Odor control method of the sewage dehydrated cake.

    吉瀬寛, 正宝敏貴, 山内一夫

    廃棄物学会研究発表会講演論文集   9th ( Pt.1 )   1998

  • Structural Analysis of Peptides and Polypeptides Using High-Field High-Resolution Solid State <sup>17</sup>O NMR.

    山内一夫, 黒木重樹, 安藤勲, 荘司顕, 尾崎拓男

    NMR討論会講演要旨集   37th   1998

  • Directivity of solid NMR. Equipment and measuring method.

    山内一夫

    日本分光学会NMR研究部会シンポジウムテキスト   1997   1998

  • Heteronuclear 2D-NMR of Swollen Synthetic Polymers using Pulsed Field Gradient and HRMAS method.

    佐藤一, 山内一夫, 岡田明彦

    NMR討論会講演要旨集   36th   1997

  • Technological development of solid high- resoluble NMR.

    山内一夫

    分子科学研究所技術研究会報告   ( 15 )   1996

  • Structure Analysis of Synthetic Polymers by HR-MAS. Application of High Resolution ”Solution” NMR Techniques to Solvent-swollen Samples.

    佐藤一, 岡田明彦, 横田絵美子, 山内一夫

    NMR討論会講演要旨集   35th   1996

  • Development of an imaging technique of water in a mineral and rock.

    中嶋悟, 中島善人, 山内一夫

    日本鉱物学会年会講演要旨集   1996   1996

  • Geochemical spectroscopy.NMR spectroscopy and three-dimensional imaging : Start of earth planetary material science in the twenty-first century.

    中島善人, 中嶋悟, 山内一夫

    月刊地球   18 ( 4 )   1996

  • The 1H Chemical Sifts of Alanine Residues in Sequential Peptide with Random Coil Structure1

    Kazuo Yamauchi, Kimiko Umemoto, Mitsuo Hitomi, Mitsuaki Narita, Tetsuo Asakura

    Rep.Prog. Polym. Phys. Jpn.   36   521 - 524   1993

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  • 非水溶媒系における合成鎖状ペプチドの<sup>1</sup>H-NMR ケミカルシフトと立体構造の関係

    山内一夫, 梅本公子, 人見光夫, 成田光章, 菊池淳, 朝倉哲郎

    日本化学会講演予稿集   66th   1993

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Industrial property rights

  • 固体NMR用試料管および固体NMR測定方法

    遠藤由宇生, 樋岡克哉, 山内一夫

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    Applicant:国立大学法人東京農工大学

    Application no:特願2010-170116  Date applied:2010.7

    Announcement no:特開2011-227036  Date announced:2011.11

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  • 固体NMR用試料管および固体NMR測定方法

    遠藤由宇生, 樋岡克哉, 山内一夫

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    Applicant:株式会社 JEOL RESONANCE

    Application no:特願2010-170116  Date applied:2010.7

    Announcement no:特開2011-227036  Date announced:2011.11

    Patent/Registration no:特許第5423605号  Date registered:2013.12  Date issued:2013.12

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  • 固体核磁気共鳴装置マジック角高速回転法用試料管、及び、それを用いた核磁気共鳴吸収スペクトルの測定方法

    山内 一夫, 朝倉 哲郎

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    Applicant:国立大学法人東京農工大学

    Application no:JP2005007303  Date applied:2005.4

    Publication no:WO2006-057082  Date published:2006.6

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Research Projects

  • MRIスペクトロスコピーによる高分子生体材料の非破壊評価法の確立

    Grant number:21550112

    2009 - 2011

    System name:平成21年度 基盤研究(C)

    Research category:Grant-in-Aid for Scientific Research (C)

    Awarding organization:MEXT

    山内一夫

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    Authorship:Principal investigator  Grant type:Competitive

    The NMR imaging(MRI) method is a useful means for obtaining non-destructively・m-scale spatial information on probe molecules such as water in bulk matter. For this reason, the MRI method has been successfully applied to polymer gel systems. Further, the contrast of images comes from the difference in the^1H spin density,^1H spin-spin relaxation time(T_2), and diffusion coefficient(D). Therefore, 1^H MRI method apply non-destructively the information about the amount of water molecules in vascular grafts from the^1H spin density image and the mobility of water molecules in vascular grafts from the^1H T_2 and diffusion coefficient(D) images.
    In the present study, the spatial distribution of^1H density, T_2 and diffusion coefficient(D) of water molecules of small-diameter silk fibroin vascular grafts coated with the different materials that is, silk fibroin(SF), polyurethane(PU) in water were observed using^1H MR imaging and the difference of amount and mobility of water in the layer of the grafts were elucidated.

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  • 極細試料管固体NMRプローブの製品化

    2008 - 2010

    System name:先端計測分析技術・機器開発事業 「プロトタイプ実証・実用化プログラム」

    Awarding organization:JST

    樋岡克哉

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    Grant type:Competitive

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  • 超微量用固体NMRプローブの開発

    2004 - 2007

    System name:先端計測分析技術・機器開発事業

    Awarding organization:JST

    山内一夫

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    Authorship:Principal investigator  Grant type:Competitive

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