Graduate School of Science and Technology Advanced Materials Science and Technology Applied Chemistry and Chemical Engineering Professor
Faculty of Engineering Department of Engineering Professor
Updated on 2025/03/14
PhD ( 1995.3 Waseda University )
Nanotechnology/Materials / Polymer chemistry
Nanotechnology/Materials / Nanometer-scale chemistry
Niigata University Graduate School of Science and Technology Advanced Materials Science and Technology Applied Chemistry and Chemical Engineering Professor
2011.4
Niigata University Faculty of Engineering Department of Chemistry and Chemical Engineering Professor
2011.4
Niigata University Center for Transdisciplinary Research Professor
2005.9 - 2011.3
Niigata University Center for Transdisciplinary Research Assistant
2003.4 - 2005.8
Niigata University Faculty of Engineering Department of Chemistry and Chemical Engineering Assistant
1998.4 - 2005.8
Niigata University Graduate School of Science and Technology Assistant
1995.4 - 1998.3
Waseda University Special researcher of the Japan Society for the Promotion of Science
1992.4 - 1995.3
Niigata University Graduate School of Science and Technology Advanced Materials Science and Technology Applied Chemistry and Chemical Engineering Professor
2011.4
Niigata University Faculty of Engineering Department of Chemistry and Chemical Engineering Professor
2011.4
Niigata University Center for Transdisciplinary Research Professor
2005.9 - 2011.3
Niigata University Center for Transdisciplinary Research Research Assistant
2003.4 - 2005.8
Niigata University Faculty of Engineering Department of Chemistry and Chemical Engineering Research Assistant
1998.4 - 2005.8
Niigata University Graduate School of Science and Technology Research Assistant
1995.4 - 1998.3
Waseda University Graduate School, Division of Science and Engineering 応用化学専攻
- 1995.3
Country: Japan
Waseda University Graduate School, Division of Science and Engineering 応用化学専攻
- 1992.3
Country: Japan
Waseda University Faculty of Science and Engineering 応用化学科
1986.4 - 1990.3
Country: Japan
American Chemical Society
The Chemical Society of Japan
The Society of Polymer Science, Japan
Folding-Induced Through-Space Magnetic Interaction of Poly(1,3-phenyleneethynylene)-Based Polyradicals Reviewed
Takashi Kaneko, Hiromasa Abe, Masahiro Teraguchi, Toshiki Aoki
MACROMOLECULES 46 ( 7 ) 2583 - 2589 2013.4
Top-down preparation of self-supporting supramolecular polymeric membranes using highly selective photocyclic aromatization of cis-cisoid helical poly(phenylacetylene)s in the membrane state Reviewed
Lijia Liu, Takeshi Namikoshi, Yu Zang, Toshiki Aoki, Shingo Hadano, Yunosuke Abe, Ikuya Wasuzu, Toyokazu Tsutsuba, Masahiro Teraguchi, Takashi Kaneko
Journal of the American Chemical Society 135 ( 2 ) 602 - 605 2013.1
Synthesis of functional pi-conjugated polymers from aromatic acetylenes Reviewed
Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi
POLYMER 47 ( 14 ) 4867 - 4892 2006.6
Helix-sense-selective polymerization of phenylacetylene having two hydroxy groups using a chiral catalytic system Reviewed
T Aoki, T Kaneko, N Maruyama, A Sumi, M Takahashi, T Sato, M Teraguchi
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 125 ( 21 ) 6346 - 6347 2003.5
Ladderlike ferromagnetic spin coupling network on a pi-conjugated pendant polyradical Reviewed
T Kaneko, T Makino, H Miyaji, M Teraguchi, T Aoki, M Miyasaka, H Nishide
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 125 ( 12 ) 3554 - 3557 2003.3
Kehan Cheng, Ken‐ichi Shinohara, Osamu Notoya, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Small 2023.12
Kehan Cheng, Ken-ichi Shinohara, Koichi Higashimine, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Chemistry Letters 2023.9
Chenxi Xu, Shuaishuai Huang, Shunya Narita, Michiru Shibata, Nennei Nagaoka, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Macromolecules 56 ( 9 ) 3334 - 3344 2023.4
Jia Shi, Taisei Yashiro, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Chemistry Letters 52 ( 3 ) 160 - 162 2023.3
Preparation and oxygen permeability of pure supramolecular polymer membranes synthesized from poly (substituted phenylacetylene) Reviewed
Chenxi Xu, Shintaro Hosono, Shunya Narita, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Polymer 267 125622 - 125622 2023.2
Zhichun Shi, Jiaxiang Wen, Yingnan Zhao, Jianjun Wang, Jun Li, Ming Zhao, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
Polymer Journal 55 ( 3 ) 203 - 211 2023.1
Liang Xu, Yu Zang, Kyousuke Takata, Boyu Jing, Jianjun Wang, Masahiro Teraguchi, Takashi Kaneko, Fengjuan Miao, Toshiki Aoki
Polymer International 71 ( 11 ) 1354 - 1361 2022.11
Yoshinori Sato, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
Chemistry Letters 51 ( 10 ) 997 - 999 2022.10
Synthesis and oxygen permselectivity of multi-stranded graft copolymers Reviewed
Kehan Cheng, Takaya Ohno, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Polymer 255 125092 - 125092 2022.8
Yu Zang, Kana Matsi, Jianjun Wang, Masahiro Teraguch, Takashi Kaneko, Toshiki Aoi
Macromolecules 55 ( 13 ) 5699 - 5710 2022.7
Corrigendum to “Absolute asymmetric polymerizations in solution needing no physical chiral source” [Polymer 245 (2022) 124673] Reviewed
Guanwu Yin, Takeshi Namikoshi, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Polymer 245 124726 - 124726 2022.4
Absolute asymmetric polymerizations in solution needing no physical chiral source Reviewed
Guanwu Yin, Takeshi Namikoshi, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Polymer 245 124673 - 124673 2022.4
Yanan Tang, Lijia Liu, Junpei Suzuki, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Chirality 34 ( 3 ) 450 - 461 2022.3
On-off reversible switching of the chirality of one-handed helical Poly(phenylacetylene)s by polarity stimuli Reviewed
Guanwu Yin, Lijia Liu, Kazuomi Mottate, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Polymer 237 124347 - 124347 2021.12
Macromolecular Design for Oxygen/Nitrogen Permselective Membranes—Top-Performing Polymers in 2020— Reviewed
Jianjun Wang, Zhichun Shi, Yu Zang, Hongge Jia, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Polymers 13 ( 17 ) 3012 - 3012 2021.9
Chenxi Xu, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Chemistry Letters 50 ( 9 ) 1617 - 1619 2021.9
Yanan Tang, Lijia Liu, Junpei Suzuki, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Chemistry Letters 50 ( 9 ) 1688 - 1690 2021.9
Improved oxygen permeation of a multi-stranded network two-dimensional polymer synthesized by three-step polymerizations of a novel monomer bearing three different polymerizable groups followed by photoexfoliation Reviewed
Kehan Cheng, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Polymer 228 123857 - 123857 2021.7
Improvement of oxygen permselectivity of a rigid helical polyphenylacetylene: Effect of flexible groups, degree of polymerization, composites, thickness, orientation, and network formation Reviewed
Jia Shi, Yuka Kimura, Shohei Takeda, Chenxi Xu, Kazuki Shoji, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Polymer 228 123900 - 123900 2021.7
Yu Zang, Yinghui Lun, Masahiro Teraguchi, Takashi Kaneko, Hongge Jia, Fengjuan Miao, Xunhai Zhang, Toshiki Aoki
Membranes 10 ( 9 ) 199 - 199 2020.8
Yanqing Qu, Xiaoyu Du, Kehan Cheng, Yu Zang, Liang Xu, Ken-ichi Shinohara, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
ACS Materials Letters 1121 - 1128 2020.8
Yu Zang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia, Fengjuan Miao
ACS Applied Polymer Materials 2 ( 2 ) 853 - 861 2020.2
Synthesis, in-situ membrane preparation, and good gas permselectivity of insoluble poly(substituted acetylene)s loosely cross-linked with short and soft siloxane and silanol linkages Reviewed
Jianjun Wang, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi
Polymer 187 122081 - 122081 2020.1
Zhichun Shi, Jianjun Wang, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
Polymers 11 ( 11 ) 1877 2019.11
Takashi Kaneko, Yosuke Araki, Ken ichi Shinohara, Masahiro Teraguchi, Toshiki Aoki
Bulletin of the Chemical Society of Japan 92 ( 10 ) 1672 - 1678 2019.10
Synthesis of a Novel AB Block Copolyaceylene Consisting of a Dynamic Cis-transoidal Racemic Helical Sequence and a Static Cis-cisoidal One-handed Helical Sequence Reviewed
Yin Guanwu, Suzuki Junpei, Aoki Toshiki, Teraguchi Masahiro, Kaneko Takashi
CHEMISTRY LETTERS 48 ( 6 ) 506 - 509 2019.6
New Synthetic Methods of Novel Nanoporous Polycondensates and Excellent Oxygen Permselectivity of Their Composite Membranes Reviewed
Zang Yu, Aoki Toshiki, Teraguchi Masahiro, Kaneko Takashi, Jia Hongge, Ma Liqun, Miao Fengjuan
NANOMATERIALS 9 ( 6 ) 2019.6
Simultaneous improvement of permeability and selectivity in enantioselective permeation through solid chiral membranes from a newly synthesized one-handed helical polyphenylacetylene with aldehyde pendant groups by enantioselective reaction Reviewed
Zang Yu, Qu Yanqing, Aoki Toshiki, Teraguchi Masahiro, Kaneko Takashi, Jia Hongge, Ma Liqun, Miao Fengjuan
POLYMER 171 45 - 49 2019.5
Helix-Sense-Selective Polymerization of Phenylacetylenes Having a Porphyrin and a Zinc-Porphyrin Group: One-Handed Helical Arrangement of Porphyrin Pendants Reviewed
Teraguchi Masahiro, Nahata Nobuyuki, Nishimura Takahiro, Aoki Toshiki, Kaneko Takashi
POLYMERS 11 ( 2 ) 2019.2
Synthesis and oxygen permeability of novel graft copolymers consisting of a polyphenylacetylene backbone and long oligosiloxane grafts from phenylacetylene-type macromonomers Reviewed
Zang Yu, Aoki Toshiki, Kaneko Takashi, Teraguchi Masahiro, Ma Liqun, Jia Hongge, Miao Fengjuan
POLYMER 156 66 - 70 2018.11
Enhanced performances of enantioselective permeation through one-handed helical polymer membranes by enantioselective imine exchange reaction with permeants and by partially decomposed reaction of the membrane Reviewed
Qu Yanqing, Aoki Toshiki, Teraguchi Masahiro, Kaneko Takashi
POLYMER 156 39 - 43 2018.11
Synthesis and Ultrahigh Oxygen Permeability of Silicon-containing cis-cisoidal Poly(substituted phenylacetylene)s Reviewed
Xu Chenxi, Aoki Toshiki, Ma Liqun, Jia Hongge, Teraguchi Masahiro, Kaneko Takashi
CHEMISTRY LETTERS 47 ( 10 ) 1314 - 1317 2018.10
Lijia Liu, Yuanyuan Gu, Yudan Wang, Toshiki Aoki, Guan Wang, Takeshi Kaneko, Masahiro Teraguchi
Polymer 154 253 - 257 2018.10
Synthesis and oxygen permeation of novel well-defined homopoly(phenylacetylene)s with different sizes and shapes of oligosiloxanyl side groups Reviewed
Yu Zang, Toshiki Aoki, Kazuki Shoji, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia, Fengjuan Miao
Journal of Membrane Science 561 26 - 38 2018.9
Ultrahigh oxygen permeability of chemically-modified membranes of novel (co) polyacetylenes having a photodegradative backbone and crosslinkable side chains Reviewed
Zhang Mingyu, Aoki Toshiki, Liu Lijia, Wang Jianjun, Teraguchi Masahiro, Kaneko Takashi
POLYMER 149 117 - 123 2018.8
Synthesis of soluble oligsiloxane-end-capped hyperbranched polyazomethine and their application to CO2/N-2 separation membranes Reviewed
Xu Liang, Lei Tianyang, Jing Boyu, Zang Yu, Miao Fengjuan, Aoki Toshiki, Teraguchi Masahiro, Kaneko Takashi
DESIGNED MONOMERS AND POLYMERS 21 ( 1 ) 99 - 104 2018.5
Zhichun Shi, Giseop Kwak, Young-Jae Jin, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
Polymer Journal 50 ( 7 ) 533 - 537 2018.3
Fluorescence emission and image patterning from selective photocyclic aromatization of cis–cisoid helical poly(phenylacetylene)s in situ in a film via top-down photodegradation Reviewed
Young-Jae Jin, Hyosang Park, Chang-Lyoul Lee, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki, Giseop Kwak
Dyes and Pigments 149 444 - 448 2018.2
Synthesis of Two Well-Defined Quadruple-Stranded Copolymers having Two Kinds of Backbones by Postpolymerization of a Helical Template Polymer Reviewed
Yu Zang, Toshiki Aoki, Hiroyoki Tanagi, Kana Matsui, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia, Ken-Ichi Shinohara
Macromolecular Rapid Communications 39 ( 4 ) 2018.2
A New Analysis Method for Quantitative Determination of Triads of Copoly(substituted acetylene) Backbones by Highly Selective Photocyclic Aromatization Reviewed
Guanwu Yin, Nennei Nagaoka, Lijia Liu, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
CHEMISTRY LETTERS 46 ( 11 ) 1608 - 1611 2017.11
Transformer of Achiral Amounts to Chirality: Double Reversal of Enantioselectivity Using a Single Cocatalyst in Asymmetric Polymerization Reviewed
Guanwu Yin, Geng Zhang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Jesus Rodriguez Castanon, Masashi Shiotsuki, Fumio Sanda
MACROMOLECULES 50 ( 19 ) 7468 - 7474 2017.10
Oxygen permselectivities through supramolecular polymer membranes prepared by highly selective photocyclic aromatization of poly(substituted acetylene) Reviewed
Guanwu Yin, Eri Ohtaka, Toshiki Aoki, Jianjun Wang, Masahiro Teraguchi, Takashi Kaneko
POLYMER 127 232 - 235 2017.10
Subnanoporous Highly Oxygen Permselective Membranes from Poly(conjugated hyperbranched macromonomer)s Synthesized by One-Pot Simultaneous Two-Mode Homopolymerization of 1,3-Bis(silyl)phenylacetylene Using a Single Rh Catalytic System: Control of Their Structures and Permselectivities Reviewed
Jianjun Wang, Jun Li, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguch, Zhichun Shi, Hongge Jia
MACROMOLECULES 50 ( 18 ) 7121 - 7136 2017.9
Oxygen Permselectivities of Novel Multi-bridged Copolymers Synthesized by Imine Metathesis between N-Imines and C-Imines in the Pendant Groups of Two Poly(substituted acetylene)s Reviewed
Yinghui Lun, Yu Zang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
CHEMISTRY LETTERS 46 ( 3 ) 401 - 404 2017.3
Helix-Sense-Selective Polymerization of Achiral Phenylacetylenes and Unique Properties of the Resulting Cis-cisoidal Polymers Reviewed
Lijia Liu, Yu Zang, Hongge Jia, Toshiki Aoki, Takashi Kaneko, Shingo Hadano, Masahiro Teraguchi, Mari Miyata, Geng Zhang, Takeshi Namikoshi
POLYMER REVIEWS 57 ( 1 ) 89 - 118 2017
Fluorescence emission enhancement of poly(phenylacetylene) via thermal annealing Reviewed
Young-Jae Jin, Hyojin Kim, Dong-Yeon Hwang, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki, Giseop Kwak
MOLECULAR CRYSTALS AND LIQUID CRYSTALS 645 ( 1 ) 50 - 57 2017
Synthesis of One-Handed Helical Block Copoly(substituted acetylene)s Consisting of Dynamic cis-transoidal and Static cis-cisoidal Block: Chiral Teleinduction in Helix-Sense-Selective Polymerization Using a Chiral Living Polymer as an Initiator Reviewed
Lijia Liu, Geng Zhang, Toshiki Aoki, Yudan Wang, Takashi Kaneko, Masahiro Teraguchi, Chunhong Zhang, Hongxing Dong
ACS MACRO LETTERS 5 ( 12 ) 1381 - 1385 2016.12
Synthesis and oxygen permselectivity of copoly(substituted acetylene)s with bulky fused polycyclic aliphatic groups Reviewed
Hongge Jia, Jian Luo, Toshiki Aoki, Lijia Liu, Yu Zang, Yinghui Lun, Masahiro Teraguchi, Takashi Kaneko
POLYMER 99 695 - 703 2016.9
Novel Isolated, L-Amino Acid-Ligated Rhodium Catalysts that Induce Highly Helix-Sense-Selective Polymerization of an Achiral 3,4,5-Trisubstituted Phenylacetylene Reviewed
Hongge Jia, Yongqiang Shi, Liqun Ma, Xuan Gao, Yazhen Wang, Yu Zang, Jijun Peng, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Toshio Masuda
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 54 ( 15 ) 2346 - 2351 2016.8
Highly Selective Photocyclic Aromatization (SCAT)-GPC Method for Quantitative Determination of Microstructures of Copoly(substituted acetylenes) Backbone Reviewed
Guanwu Yin, Lijia Liu, Toshiki Aoki, Takeshi Namikoshi, Masahiro Teraguchi, Takashi Kaneko
CHEMISTRY LETTERS 45 ( 7 ) 813 - 815 2016.7
Highly Emissive, Optically Active Poly(diphenylacetylene) Having a Bulky Chiral Side Group Reviewed
Hyojin Kim, Kyo-Un Seo, Young-Jae Jin, Chang-Lyoul Lee, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki, Giseop Kwak
ACS MACRO LETTERS 5 ( 5 ) 622 - 625 2016.5
Asymmetric Restriction of Intramolecular Rotation in Chiral Solvents Reviewed
Young-Jae Jin, Hyojin Kim, Jong Jin Kim, Nam Ho Heo, Jong Won Shin, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki, Giseop Kwak
CRYSTAL GROWTH & DESIGN 16 ( 5 ) 2804 - 2809 2016.5
High Oxygen Permselectivity through a Membrane from Novel Soluble Imido-bridged Ladder Polysiloxane Reviewed
Shuangping Xu, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
CHEMISTRY LETTERS 45 ( 4 ) 424 - 426 2016.4
Influence of a hydrodynamic environment on chain rigidity, liquid crystallinity, absorptivity, and photoluminescence of hydrogen-bonding-assisted helical poly(phenylacetylene) Reviewed
Young-Jae Jin, Hyojin Kim, Mari Miyata, Guanwu Yin, Takashi Kaneko, Masahiro Teraguchi, Toshiki Aoki, Giseop Kwak
RSC ADVANCES 6 ( 43 ) 36661 - 36666 2016
Highly Efficient Helix-sense-selective Polymerization of an Achiral Phenylacetylene Having a Bulky Group Reviewed
Yanqing Qu, Yu Zang, Mingyu Zhang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia
CHEMISTRY LETTERS 44 ( 12 ) 1777 - 1779 2015.12
Quantitative Introduction of Perfluoroalkyl Groups to Poly(diphenylacetylene) Membranes via Three-step Membrane Reaction Including Click Reaction and Their Gas Permeability Reviewed
Takashi Sato, Masahiro Teraguchi, Motohiro Kiuchi, Takashi Kaneko, Toshiki Aoki
CHEMISTRY LETTERS 44 ( 12 ) 1679 - 1681 2015.12
Helical Conformation Stability of Poly[3,5-bis(hydroxymethyl)phenylacetylene]s Depending on the Length of Their Rigid and Linear pi-Conjugated Side Groups Reviewed
Zhichun Shi, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
CHEMISTRY LETTERS 44 ( 10 ) 1413 - 1415 2015.10
Synthesis of a Fluorine-Containing Cis-Cisoidal One-Handed Helical Polyphenylacetylene and Application of Highly Selective Photocyclic Aromatization Product on Oxygen Permselective Membrane Reviewed
Yu Zang, Guanwu Yin, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia
CHIRALITY 27 ( 8 ) 459 - 463 2015.8
A Helical Polyphenylacetylene Having Amino Alcohol Moieties Without Chiral Side Groups as a Chiral Ligand for the Asymmetric Addition of Diethylzinc to Benzaldehyde Reviewed
Lijia Liu, Qing Long, Toshiki Aoki, Geng Zhang, Takashi Kaneko, Masahiro Teraguchi, Chunhong Zhang, Yudan Wang
CHIRALITY 27 ( 8 ) 454 - 458 2015.8
Helix-sense-selective Polymerization of Achiral Phenylacetylenes by Using One-handed Helical Poly(phenylacetylene)s as Chiral Cocatalysts Prepared by Helix-sense-selective Polymerization of Achiral Phenylacetylenes Reviewed
Geng Zhang, Lijia Liu, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
CHEMISTRY LETTERS 44 ( 3 ) 318 - 320 2015.3
A Chiral Supramolecular Polymer Membrane with no Chiral Substituents by Highly Selective Photocyclic Aromatization of a One-Handed Helical Cis-cisoidal Polyphenylacetylene Reviewed
Lijia Liu, Qing Long, Toshiki Aoki, Takeshi Namikoshi, Yunosuke Abe, Mari Miyata, Masahiro Teraguchi, Takashi Kaneko, Yudan Wang, Chunhong Zhang
MACROMOLECULAR CHEMISTRY AND PHYSICS 216 ( 5 ) 530 - 537 2015.3
Selective Polymerization of Dimethylsilylphenylacetylene and the Gas Permselectivity of the Resulting Polymer Membranes Reviewed
Jun Li, Jianjun Wang, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi
CHEMISTRY LETTERS 44 ( 2 ) 182 - 184 2015.2
Two-Dimensional and Related Polymers: Concepts, Synthesis, and their Potential Application as Separation Membrane Materials Reviewed
Yu Zang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia
POLYMER REVIEWS 55 ( 1 ) 57 - 89 2015.1
Synthesis and oxygen permeation of novel polymers of phenylacetylenes having two hydroxyl groups via different lengths of spacers Reviewed
Yu Zang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia
POLYMER 56 ( SI ) 199 - 206 2015.1
Catalytic helix-sense-selective polymerisation of achiral substituted acetylenes containing bulky pi-conjugated planar substituents yielding soluble and statically stable one-handed helical polymers Reviewed
Y. Zang, X. Wang, W. Zhang, T. Aoki, M. Teraguchi, T. Kaneko, L. Ma, H. Jia
RSC ADVANCES 5 ( 129 ) 106819 - 106823 2015
Helix-sense-selective Degradation of Poly[4-dodecyloxy-3,5-bis(hydroxymethyl)phenylacetylene] by Selective Photocyclic Aromatization (SCAT) Using Circularly Polarized Light (CPL) Reviewed
Mari Miyata, Masahiro Teraguchi, Hiromichi Endo, Takashi Kaneko, Toshiki Aoki
CHEMISTRY LETTERS 43 ( 9 ) 1476 - 1477 2014.9
Synthesis of Poly(1,2-phenyleneethynylene-1,2-phenylenevinylene) Bearing Phenol Residues and Forming Ability of the Folded Helical Conformation Reviewed
Takashi Kaneko, Yuta Togashi, Masahiro Teraguchi, Toshiki Aoki
CHEMISTRY LETTERS 43 ( 8 ) 1219 - 1221 2014.8
Synthesis of sequential poly(1,3-phenyleneethynylene)-based polyradicals and through-space antiferromagnetic interaction of their solid state Reviewed
Takashi Kaneko, Kyohei Iwamura, Ryo Nishikawa, Masahiro Teraguchi, Toshiki Aoki
POLYMER 55 ( 5 ) 1097 - 1102 2014.3
Facile synthesis of five 2D surface modifiers by highly selective photocyclic aromatization and efficient enhancement of oxygen permselectivities of three polymer membranes by surface modification using a small amount of the 2D surface modifiers Reviewed
Jianjun Wang, Yu Zang, Guanwu Yin, Toshiki Aoki, Hiroyuki Urita, Ken Taguwa, Lijia Liu, Takeshi Namikoshi, Masahiro Teraguchi, Takashi Kaneko, Liqun Ma, Hongge Jia
POLYMER 55 ( 6 ) 1384 - 1396 2014.3
Synthesis and Enantioselective Permeability of One-handed Helical Multihydroxy Poly(phenylacetylene) Membrane by In Situ Removal of the Original Chiral Substituents Reviewed
Lijia Liu, Kazuomi Mottate, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi
CHEMISTRY LETTERS 43 ( 2 ) 237 - 239 2014.2
Helix-Sense-Selective Polymerization of Novel Substituted Acetylenes Having a Rigid Planar Imino-Linked Substituent and Quantitative Polymer Reactions in the Optically Active Polymer Membranes Reviewed
Mari Miyata, Yuya Katsushika, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
KOBUNSHI RONBUNSHU 71 ( 8 ) 372 - 381 2014
Facile Synthesis of an Amphiphilic 1,3,5-Trisubstituted Benzene as a Novel Surface Modifier by Selective Photocyclic Aromatization and Efficient Improvement of Oxygen Permselectivity by the Addition of the Surface Modifier Reviewed
Jianjun Wang, Toshiki Aoki, Lijia Liu, Takeshi Namikoshi, Masahiro Teraguchi, Takashi Kaneko
CHEMISTRY LETTERS 42 ( 9 ) 1090 - 1092 2013.9
Helix-sense-selective Polymerization of 3,5-Bis(hydroxymethyl)phenylacetylene Connected with a Rigid and pi-Conjugated Substituent Reviewed
Zhichun Shi, Yoshinori Murayama, Takashi Kaneko, Masahiro Teraguchi, Toshiki Aoki
CHEMISTRY LETTERS 42 ( 9 ) 1087 - 1089 2013.9
Flexible self-supporting supramolecular polymeric membranes consisting of 1,3,5-trisubstituted benzene derivatives synthesized by highly selective photocyclic aromatization of helical poly(phenylacetylene)s in the membrane state Reviewed
Mari Miyata, Takeshi Namikoshi, Lijia Liu, Yu Zang, Toshiki Aoki, Yunosuke Abe, Yoshiyuki Oniyama, Toyokazu Tsutsuba, Masahiro Teraguchi, Takashi Kaneko
Polymer (United Kingdom) 54 ( 17 ) 4431 - 4435 2013.8
Chiral Amplification during Asymmetric-Induced Copolymerization of Phenylacetylenes with Tight Cis-Cisoidal Main Chains Reviewed
Lijia Liu, Kazuomi Mottate, Geng Zhang, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi
MACROMOLECULAR RAPID COMMUNICATIONS 34 ( 14 ) 1140 - 1144 2013.7
Excellent oxygen permselectivity of fluorine-containing poly(trimethylsilyldiphenylacetylene)s prepared by direct alkylation of perfluorodecyl groups in membrane state Reviewed
Takashi Sato, Naoki Yoshida, Akihiro Ishida, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
Polymer (United Kingdom) 54 ( 9 ) 2231 - 2234 2013.4
Helix-sense-selective Polymerization of Achiral Acetylene Monomer Catalyzed by Rh Zwitterionic Complexes with Tethered Chiral Amino and Ether Groups Reviewed
Naoya Onishi, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi, Natsuhiro Sano, Toshio Masuda, Masashi Shiotsuki, Fumio Sanda
CHEMISTRY LETTERS 42 ( 3 ) 278 - 280 2013.3
Living-like helix-sense-selective polymerization of an achiral substituted acetylene having bulky substituents Reviewed
Yu Zang, Kazuki Nakao, Hiroki Yotsuyanagi, Toshiki Aoki, Takeshi Namikoshi, Toyokazu Tsutsuba, Masahiro Teraguchi, Takashi Kaneko
POLYMER 54 ( 7 ) 1729 - 1733 2013.3
Helix-sense-selective polymerization of substituted acetylenes by using an isolated rh chiral initiator with an amino acid ligand Reviewed
Yu Zang, Tomoyuki Ohishi, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
Chemistry Letters 42 ( 4 ) 430 - 432 2013
Two modes of asymmetric polymerization of phenylacetylenes having an L-amino alcohol residue and two hydroxy groups Reviewed
Hongge Jia, Jun Li, Yu Zang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 50 ( 24 ) 5134 - 5143 2012.12
Helix-Sense-Selective Polymerization of Achiral Phenylacetylenes with Two N-Alkylamide Groups to Generate the One-Handed Helical Polymers Stabilized by Intramolecular Hydrogen Bonds Reviewed
Masahiro Teraguchi, Daisuke Tanioka, Takashi Kaneko, Toshiki Aoki
ACS MACRO LETTERS 1 ( 11 ) 1258 - 1261 2012.11
Enhanced Gas Permselectivity of Copoly(Hyperbranched Macromonomer) Synthesized by One-pot Simultaneous Copolymerization of Dimethylsilyl-containing Phenylacetylenes Reviewed
Jun Li, Jianjun Wang, Yu Zang, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi
CHEMISTRY LETTERS 41 ( 11 ) 1462 - 1464 2012.11
Synthesis of stable and soluble one-handed helical poly(substituted acetylene)s without chiral pendant groups via polymer reaction in membrane state Reviewed
Yunosuke Abe, Toshiki Aoki, Hongge Jia, Shingo Hadano, Takeshi Namikoshi, Yuriko Kakihana, Lijia Liu, Yu Zang, Masahiro Teraguchi, Takashi Kaneko
POLYMER 53 ( 11 ) 2129 - 2133 2012.5
Transformation from preformed racemic helical poly(phenylacetylene)s to the enantioenriched helical polymers by chiral solvation, followed by removal of the chiral solvents Reviewed
Takashi Kaneko, Xiaoyun Liang, Atsuko Kawami, Masayuki Sato, Takeshi Namikoshi, Masahiro Teraguchi, Toshiki Aoki
POLYMER JOURNAL 44 ( 4 ) 327 - 333 2012.4
Chiral Teleinduction in Asymmetric Polymerization of 3,5-Bis(hydroxymethyl)phenylacetylene Having a Chiral Group via a Very Long and Rigid Spacer at 4-Position Reviewed
Yunosuke Abe, Toshiki Aoki, Hongge Jia, Shingo Hadano, Takeshi Namikoshi, Yuriko Kakihana, Lijia Liu, Yu Zang, Masahiro Teraguchi, Takashi Kaneko
CHEMISTRY LETTERS 41 ( 3 ) 244 - 246 2012.3
Asymmetric-induced polymerization and polymer reaction of the resulting one-handed helical polymer membranes Reviewed
Yunosuke Abe, Takeshi Namikoshi, Yu Zang, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 243 2012.3
Helix-sense-selective polymerization of achiral phenylacetylenes and selective cyclicaromatization of the resulting cis-cisoidal poly(phenylacetylene)s Reviewed
Yu Zang, Yunosuke Abe, Lijia Liu, Takeshi Namikoshi, Tomoyuki Ohishi, Ikuya Wasuzu, Kazutomo Kikuchi, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 243 2012.3
Helix-sense-selective polymerization of chiral or achiral silicon-containing phenylacetylenes Reviewed
Liu Lijia, Zang Yu, Jia Hongge, Teraguchi Masahiro, Kaneko Takashi, Aoki Toshiki
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY 243 2012.3
Synthesis of Stable and Soluble One-Handed Helical Homopoly(substituted acetylene)s without the Coexistence of Any Other Chiral Moieties via Two-Step Polymer Reactions in Membrane State: Molecular Design of the Starting Monomer Reviewed
Yunosuke Abe, Toshiki Aoki, Hongge Jia, Shingo Hadano, Takeshi Namikoshi, Yuriko Kakihana, Lijia Liu, Yu Zang, Masahiro Teraguchi, Takashi Kaneko
MOLECULES 17 ( 1 ) 433 - 451 2012.1
Advanced Polymer Particles Reviewed
Eri Yoshida, Takashi Kaneko, Toshifumi Satoh, Yusuf Menceloglu, Atsuyoshi Nakayama
INTERNATIONAL JOURNAL OF POLYMER SCIENCE 168412 - 168412 2012
Polymerization of Phenylacetylene-Based Monodendrons with Alkoxy Peripheral Groups and Oxygen/Nitrogen Permeation Behavior of Their Membranes Reviewed
Takashi Kaneko, Kazuaki Sato, Yoshihiko Uchiya, Masahiro Teraguchi, Toshiki Aoki
INTERNATIONAL JOURNAL OF POLYMER SCIENCE 974204 - 974204 2012
Pseudo helix-sense-selective polymerisation of achiral substituted acetylenes Reviewed
Yu Zang, Toshiki Aoki, Lijia Liu, Yunosuke Abe, Yuriko Kakihana, Masahiro Teraguchi, Takashi Kaneko
CHEMICAL COMMUNICATIONS 48 ( 39 ) 4761 - 4763 2012
Reversible Photogeneration of a Stable Chiral Radical-Pair from a Fast Photochromic Molecule Reviewed
Sayaka Hatano, Kana Fujita, Nobuyuki Tamaoki, Takashi Kaneko, Takuya Nakashima, Masanobu Naito, Tsuyoshi Kawai, Jiro Abe
JOURNAL OF PHYSICAL CHEMISTRY LETTERS 2 ( 21 ) 2680 - 2682 2011.11
Synthesis and Function of Chiral π-Conjugated Polymers from Phenylacetylenes Reviewed
Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi
Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis 423 - 455 2011.6
Enantioselective Pervaporation through Membranes from Poly(1,3-phenyleneethynylene)-based One-handed Helical Foldamer and Unfoldamer Reviewed
Makoto Inoue, Masahiro Teraguchi, Toshiki Aoki, Takeshi Namikoshi, Edy Marwanta, Takashi Kaneko
CHEMISTRY LETTERS 40 ( 4 ) 384 - 386 2011.4
SHIMIZU Tadaaki, KODAMA Tatsuya, KIMURA Isao, YOSHIDA Masanori, KANEKO Takashi, TERAGUCHI Masahiro
Journal of Jsee 59 ( 1 ) 74 - 78 2011.3
New Achiral Phenylacetylene Monomers Having an Oligosiloxanyl Group Most Suitable for Helix-Sense-Selective Polymerization and for Obtaining Good Optical Resolution Membrane Materials Reviewed
Lijia Liu, Yu Zang, Shingo Hadano, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Takeshi Namikoshi
MACROMOLECULES 43 ( 22 ) 9268 - 9276 2010.11
Three Mechanisms of Asymmetric Polymerization of Phenylacetylenes Having an L-Amino Ether Residue and Two Hydroxy Groups Reviewed
Hongge Jia, Masahiro Teraguchi, Toshiki Aoki, Yunosuke Abe, Takashi Kaneko, Shingo Hadano, Takeshi Namikoshi, Tomoyuki Ohishi
MACROMOLECULES 43 ( 20 ) 8353 - 8362 2010.10
Synthesis and helix-sense-selective polymerization of a novel phenylacetylene having a trisiloxanyl group and two hydroxyl groups and enantioselective permeability of the resulting chiral polymeric membrane: Effect of the trisiloxanyl group on the polymerization and enantioselective permeability Reviewed
Lijia Liu, Yoshiyuki Oniyama, Yu Zang, Shingo Hadano, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Takeshi Namikoshi, Edy Marwanta
POLYMER 51 ( 12 ) 2460 - 2464 2010.5
Optically active helical structure and magnetic interaction of poly(phenylacetylene)-based polyradicals Reviewed
Takashi Kaneko, Hiroo Katagiri, Yasuhiro Umeda, Takeshi Namikoshi, Edy Marwanta, Masahiro Teraguchi, Toshiki Aoki
POLYHEDRON 28 ( 9-10 ) 1927 - 1929 2009.6
Synthesis of poly(1,3-phenyleneethynylenes) membranes having one-handed helical conformation without any chiral side groups by in-situ desubstitution of D-menthoxy groups Reviewed
Makoto Inoue, Masahiro Teraguchi, Toshiki Aoki, Shingo Hadano, Takeshi Namikoshi, Edy Marwanta, Takashi Kaneko
SYNTHETIC METALS 159 ( 9-10 ) 854 - 858 2009.5
Synthesis of an optically active poly(aryleneethynylene) bearing galvinoxyl residues and its chiroptical and magnetic properties Reviewed
Takashi Kaneko, Hiromasa Abe, Takeshi Namikoshi, Edy Marwanta, Masahiro Teraguchi, Toshiki Aoki
SYNTHETIC METALS 159 ( 9-10 ) 864 - 867 2009.5
Helix-Sense-Selective Polymerization of Achiral Bis(hydroxymethyl)phenylacetylenes Bearing Alkyl Groups of Different Lengths Invited Reviewed
Shingo Hadano, Takuya Kishimoto, Tomonori Hattori, Daisuke Tanioka, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko, Takeshi Namikoshi, Edy Marwanta
MACROMOLECULAR CHEMISTRY AND PHYSICS 210 ( 9 ) 718 - 727 2009.5
Phenyleneethynylene Macrocycle-Fused Phenylacetylene Monomers: Synthesis and Polymerization Invited Reviewed
Takashi Kaneko, Takahiro Horie, Shinji Matsumoto, Masahiro Teraguchi, Toshiki Aoki
MACROMOLECULAR CHEMISTRY AND PHYSICS 210 ( 1 ) 22 - 36 2009.1
Two Modes of Asymmetric Polymerization of Phenylacetylene Having a L-Valinol Residue and Two Hydroxy Groups Reviewed
Hongge Jia, Masahiro Teraguchi, Toshiki Aoki, Yunosuke Abe, Takashi Kaneko, Shingo Hadano, Takeshi Namikoshi, Edy Marwanta
MACROMOLECULES 42 ( 1 ) 17 - 19 2009.1
Copper(I) iodide accelerates catalytic activation in rhodium complex-catalyzed helix-sense-selective polymerization of achiral phenylacetylene monomers Reviewed
Hiroo Katagiri, Takashi Kaneko, Masahiro Teraguchi, Toshiki Aoki
CHEMISTRY LETTERS 37 ( 4 ) 390 - 391 2008.4
Helix-sense-selective polymerization of trimethylsilyl or siloxanyl group containing monomer
Liu Lijia, Masahiro Teraguchi, Takeshi Namikoshi, Edy Marwanta, Takashi Kaneko, Toshiki Aoki
2008 Niigata-Inha Joint Symposium on Advanced Polymeric Materials 6 2008
Function of one-handed helical backbone of polyphenylacetylenes Invited
Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
The 5th International Symposium on Advanced Materials in Asia-Pacific Rim (5th ISAMAP) 2008
Synthesis and Properties of Chiral Polyphenylacetylenes Having their Chiral Structures Only in the Backbone Invited
Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
International Symposium on Polymer Chemistry (PC'2008, Hefei) 2008
Synthesis of Chiral Helical Poly(phenyleneethynylene) Membranes by Desubstitution of Chiral Group /2008 Niigata-Inha Joint Symposium on Advanced Polymeric Materials
Makoto Inoue, Masahiro Teraguchi, Takeshi Namikoshi, Edy Marwanta, Takashi Kaneko, Toshiki Aoki
2008 Niigata-Inha Joint Symposium on Advanced Polymeric Materials 3 2008
Helix-sense tunability induced by achiral diene ligands in the chiral catalytic system for the helix-sense-selective polymerization of achiral and bulky phenylacetylene monomers Reviewed
Takashi Kaneko, Yasuhiro Umeda, Honge Jia, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
MACROMOLECULES 40 ( 20 ) 7098 - 7102 2007.10
Efficient charge transport through a metal oxide semiconductor in the nanocomposite film with tris(2,2 '-bipyridine)ruthenium(II) Reviewed
Koji Sone, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki, Masayuki Yagi
JOURNAL OF PHYSICAL CHEMISTRY C 111 ( 31 ) 11636 - 11641 2007.8
Electrochemical and photosensitized redox reactions of a Prussian blue film layered on a WO3/[Ru(bpy)(3)](2+)/polymer hybrid film Reviewed
Koji Sone, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki, Masayuki Yagi
CHEMPHYSCHEM 8 ( 9 ) 1357 - 1362 2007.6
Synthesis of an optically active helical poly(1,3-phenyleneethynylene) bearing stable radicals and its chiroptical and magnetic properties Reviewed
Takashi Kaneko, Shota Yoshimoto, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
POLYHEDRON 26 ( 9-11 ) 1825 - 1829 2007.6
Enantioselective permeability through membranes from a poly(substituted phenylacetylene) having a chiral helical backbone and achiral bidentate ligands as pendant groups Reviewed
Shingo Hadano, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
CHEMISTRY LETTERS 36 ( 2 ) 220 - 221 2007.2
Synthesis and Helix-Sense-Selective Copolymerization of Disiloxane Containing Monomer Reviewed
Liu Lijia, Hadano Shingo, Hoshi Yuya, Teraguchi Masahiro, Kaneko Takashi, Aoki Toshiki
Proceedings of International Symposium on Fusion Technology 2006-2007 at Niigata P-3 2007
Helix-sense-selective copolymerization of phenylacetylene having two silanol groups and chemical fixation of ladder chiral double helical structure of the resulting copolymer
Shingo Hadano, Kazuo Futamata, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
International Symposiumon Fusion Tech 2006-2007 41 2007
Electrochemical and photosensitized redox reactions of a Prussian blue film layered on a WO3 / tris(2,2'-bipyridine)ruthenium(II) / polymer hybrid film
Koji Sone, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki, Masayuki Yagi
International Symposiumon Fusion Tech 2006-2007 38 2007
Synthesis of optically active helical polyacetylenes bearing stable radicals via helix-sense-selective polymerization
Takashi Kaneko, Yasuhiro Umeda, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
International Symposiumon Fusion Tech 2006-2007 40 2007
Synthesis of poly(phenylacetylene)-based polydendrons consisting of a phenyleneethynylene repeating unit, and oxygen/nitrogen permeation behavior of their membranes Reviewed
T Kaneko, K Yamamoto, M Asano, M Teraguchi, T Aoki
JOURNAL OF MEMBRANE SCIENCE 278 ( 1-2 ) 365 - 372 2006.7
Synthesis of optically active helical polymers bearing stable radicals via helix-sense-selective polymerization of phenylacetylenes
Takashi Kaneko, Yasuhiro Umeda, Shingo Hadano, Masahiro Teraguchi, Toshiki Aokil
WMSCI 2006 - The 10th World Multi-Conference on Systemics, Cybernetics and Informatics, Jointly with the 12th International Conference on Information Systems Analysis and Synthesis, ISAS 2006 - Proc. 3 8 2006
Thermodynamic and kinetic insights into a reversible association- dissociation reaction of phthalocyanine Zinc(II) in a Nafion film
Takayuki Kuwabara, Masayuki Yagi, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Polymer Preprints, Japan 55 ( 1 ) 1625 2006
Synthesis of poly(1,3-phenyleneethynylene)-based chiral polyradical bearing galvinoxyl groups and its optical and magnetic properties
Shota Yoshimoto, Takashi Kaneko, Masahiro Teraguchi, Toshiki Aoki
Polymer Preprints, Japan 55 ( 1 ) 1505 2006
Synthesis of chiral helical poly(phenylacetylene) bearing metal complex site on side chain and effect of the metal complex on chiral recognition ability
Shingo Hadano, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
Polymer Preprints, Japan 55 ( 1 ) 1665 2006
Synthesis, structures and properties of poly(phenylacetylene) having optically active pinanylsilyl group and two hydroxyl groups
Kazuomi Mottate, Masahiro Teraguchi, Shingo Hadano, Toshiki Aoki, Takashi Kaneko
Polymer Preprints, Japan 55 ( 1 ) 491 2006
Oxidization, electronic state and magnetic property of oligo(anthryleneethynylene)s with pendant phenol residues at 2- and 7- positions
Tsuyoshi Tanaka, Takashi Kaneko, Masayuki Yagi, Masahiro Teraguchi, Toshiki Aoki
Polymer Preprints, Japan 55 ( 1 ) 1504 2006
Synthesis of poly(1,3-phenyleneethynylene)-based chiral polyradical bearing galvinoxyl and its magnetic property and magnetoptical effect
Shota Yoshimoto, Takashi Kaneko, Masahiro Teraguchi, Shingo Hadano, Toshiki Aoki
Polymer Preprints, Japan 55 ( 2 ) 4730 - 4731 2006
Unexpected degradability of one-handed helical poly(phenylacetylene) -Degradation mechanism and control
Shingo Hadano, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
Polymer Preprints, Japan 55 ( 2 ) 2811 2006
Synthesis of poly(phenyleneethynylene) membranes and their chiral helical structures
Makoto Inoue, Masahiro Teraguchi, Shingo Hadano, Toshiki Aoki, Takashi Kaneko
Polymer Preprints, Japan 55 ( 2 ) 2847 2006
Immobilization of the ladder-like double helical structure of poly(phenylacetylene) derivatives bearing two functional group with hydrogen bonding ability
Kazuo Futamata, Shingo Hadano, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
Polymer Preprints, Japan 55 ( 2 ) 2867 2006
Analysis and regulation of unusual adsorption of phthalocyanine zinc(II) into a Nafion film as investigated by UV-vis spectroscopic techniques Reviewed
T Kuwabara, M Teraguchi, T Kaneko, T Aoki, M Yagi
JOURNAL OF PHYSICAL CHEMISTRY B 109 ( 44 ) 21202 - 21208 2005.11
Assignment of helical sense for poly(phenylacetylene) bearing achiral galvinoxyl chromophore synthesized by helix-sense-selective polymerization Reviewed
T Kaneko, Y Umeda, T Yamamoto, M Teraguchi, T Aoki
MACROMOLECULES 38 ( 23 ) 9420 - 9426 2005.11
Synthesis and magnetic characterization of monodisoerse oligo(9, 10-anthryleneethynylene)-based polyradicals with two pendant stable phenoxyls in one anthracene skeleton Reviewed
T Kaneko, A Onuma, H Ito, M Teraguchi, T Aoki
POLYHEDRON 24 ( 16-17 ) 2544 - 2549 2005.11
Synthesis of chiral helical poly(hydroxyl-containing phenylacetylene) membranes by in-situ depinanylsilylation and their enantioselective permeabilities Reviewed
M Teraguchi, K Mottate, SY Kim, T Aoki, T Kaneko, S Hadano, T Masuda
MACROMOLECULES 38 ( 15 ) 6367 - 6373 2005.7
Helix-sense-selective polymerization of a phenylacetylene bearing an achiral and bulky galvinoxyl moiety Reviewed
Y Umeda, T Kaneko, M Teraguchi, T Aoki
CHEMISTRY LETTERS 34 ( 6 ) 854 - 855 2005.6
Preparation of chiral polystyrene monoliths by utilizing W/O emulsion polymerization and their optical resolution ability Reviewed
M Teraguchi, M Ohtake, H Inoue, A Yoshida, T Aoki, T Kaneko, K Yamanaka
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 43 ( 11 ) 2348 - 2357 2005.6
New macromolecular architectures for permselective membranes - Gas permselective membranes from dendrimers and enantioselectively permeable membranes from one-handed helical polymers Reviewed
T Aoki, T Kaneko
POLYMER JOURNAL 37 ( 10 ) 717 - 735 2005
Specific ion exchange properties of a new porous ion exchange resin having an open-celled monolith structure Reviewed
H Inoue, K Yamanaka, A Yoshida, A Nakamura, T Aoki, M Teraguchi, T Kaneko
KOBUNSHI RONBUNSHU 62 ( 1 ) 7 - 16 2005
Helix-sense-selective (Co)polymerization of 4-alkyloxy-3,5-bis (hydroxymethyl)phenylacetylene using a chiral catalytic system
Takuva Kishimoto, Shingo Hadano, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi, Sun-Young Kim
Polymer Preprints, Japan 54 ( 1 ) 253 2005
Synthesis of optically active helical poly(phenylacetylene)s bearing galvinoxyl residues
Takashi Kaneko, Yasuhiro Umeda, Masahiro Teraguch, Toshiki Aoki
Polymer Preprints, Japan 54 ( 2 ) 2867 - 2868 2005
The control of helix-sense by achiral diene-ligands on the helix-sense-selective polymerization of (4-ethynylphenyl)hydrogalvinoxyl
Takashi Kaneko, Yasuhiro Umeda, Masahiro Teraguchi, Toshiki Aoki
Polymer Preprints, Japan 54 ( 1 ) 250 2005
Control of chiral helical structure of poly(phenylacetylene) stabilized by only intramolecular hydrogen bonds - Stability, stimuli-responsibility and degradability
Shingo Hadano, Toshiki Aoki, Masahiro Teraguchi, Sun-Young Kim, Takashi Kaneko
Polymer Preprints, Japan 54 ( 1 ) 251 2005
Analysis and regulation of unusual adsorption of phthalocyanine Zinc (II) into a Nafion film
Takavuki Kuwabara, Masayuki Yagi, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki
Polymer Preprints, Japan 54 ( 1 ) 1870 2005
Helix-sense-selective copolymerization of phenylacetylene having optically active pinanylsilyl group and two hydroxy groups with an achiral phenylacetylene
Kazuomi Mottate, Sun-Young Kim, Masahiro Teraguchi, Shingo Hadano, Toshiki Aoki, Takashi Kaneko
Polymer Preprints, Japan 54 ( 1 ) 252 2005
Helix-sense-selective copolymerization of phenylacetylene bearing two silanol groups and immobilization of the resulting chiral helical structure
Kazuo Futamata, Sun-Young Kim, Shingo Hadano, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
Polymer Preprints, Japan 54 ( 2 ) 2618 2005
Synthesis of chiral helical poly(hydroxyl-containing phenylacetylene) membranes by depinanylsilylation in membran state and their enantioselective permeabilities
Masahiro Teraguchi, Kazuomi Mottate, Toshiki Aoki, Takashi Kaneko, Shingo Hadano
Polymer Preprints, Japan 54 ( 2 ) 2743 - 2744 2005
Helix-sense-selective copolymerization of phenylacetylene having optically active pinanylsilyl group and two hydroxyl groups, desilylation of the formed polymers and their enantioselective permeabilities
Kazuomi Mottate, Masahiro Teraguchi, Shingo Hadano, Toshiki Aoki, Takashi Kaneko
Polymer Preprints, Japan 54 ( 2 ) 2741 - 2742 2005
Stability, stimuli-responsibility and degradability of chiral helical structure of poly(phenylacetylene) having asymmetric structure only in the main chain - Effects of intramolecular hydrogen bonds
Shingo Hadano, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
Polymer Preprints, Japan 54 ( 2 ) 2855 2005
Enantioselective permeability of chiral helical poly(phenylacetylene) membranes containing carboxyl groups or amino groups
Kazuomi Mottate, Masahiro Teraguchi, Shingo Hadano, Toshiki Aoki, Takashi Kaneko
Polymer Preprints, Japan 54 ( 2 ) 4071 2005
Role of chiral amine cocatalysts in the helix-sense-selective polymerization of a phenylacetylene using a catalytic system Reviewed
T Sato, T Aoki, M Teraguchi, T Kaneko, SY Kim
POLYMER 45 ( 24 ) 8109 - 8114 2004.11
Synthesis of chiral helical poly[p-(oligopinanylsiloxanyl)phenylacetylene]s and enantioselective permeability of their membranes Reviewed
T Aoki, T Fukuda, KI Shinohara, T Kaneko, M Teraguchi, M Yagi
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 42 ( 18 ) 4502 - 4517 2004.9
Synthesis and cation exchange properties of a new porous cation exchange resin having an open-celled monolith structure Reviewed
H Inoue, K Yamanaka, A Yoshida, T Aoki, M Teraguchi, T Kaneko
POLYMER 45 ( 1 ) 3 - 7 2004.1
Synthesis and ion exchange properties of a new porous ion exchange resin having an open-celled monolith structure Reviewed
H Inoue, K Yamanaka, A Yoshida, T Aoki, T Kaneko, M Teraguchi
KOBUNSHI RONBUNSHU 61 ( 5 ) 301 - 309 2004
Enantioselective permeation through membranes of chiral helical polymers prepared by depinanylsilylation of poly(diphenylacetylene) with a high content of the pinanylsilyl group Reviewed
M Teraguchi, J Suzuki, T Kaneko, T Aoki, T Masuda
MACROMOLECULES 36 ( 26 ) 9694 - 9697 2003.12
Entropy effect on physical displacement of redox molecules in a naflon film as studied by double potential-step chronoabsorptometry Reviewed
M Yagi, M Takahashi, M Teraguchi, T Kaneko, T Aoki
JOURNAL OF PHYSICAL CHEMISTRY B 107 ( 46 ) 12662 - 12667 2003.11
A poly(9, 10-anthryleneethynylene)-based polyradical designed to be a ladder-like ferromagnetic spin coupling network Reviewed
T Kaneko, T Makino, H Miyaji, A Onuma, M Teraguchi, T Aoki
POLYHEDRON 22 ( 14-17 ) 1845 - 1850 2003.7
Synthesis of a pendant polyradical with a new pi-conjugated polymer backbone containing an anthracene skeleton and its ferromagnetic spin coupling Reviewed
T Kaneko, T Matsubara, T Aoki
CHEMISTRY OF MATERIALS 14 ( 9 ) 3898 - 3906 2002.9
Helical chirality of pi-conjugated main-chain induced by polymerization of phenylacetylene with chiral bulky pinanyl groups: Effects of the flexible spacer and polymerization catalyst Reviewed
K Shinohara, T Aoki, T Kanek
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 40 ( 11 ) 1689 - 1697 2002.6
Synthesis and stable high oxygen permeability of poly(diphenylacetylene)s with two or three trimethylsilyl groups Reviewed
G Kwak, T Aoki, T Kaneko
POLYMER 43 ( 5 ) 1705 - 1709 2002.3
Pervaporation of nonaqueous ethanol azeotropes through interpenetrating polymer network membranes prepared from poly(4-vinylpyridine) and poly(vinyl alcohol) Reviewed
E Oikawa, K Nozawa, T Kaneko, T Aoki
JOURNAL OF APPLIED POLYMER SCIENCE 82 ( 11 ) 2729 - 2738 2001.12
Poly(9,10-anthryleneethynylene)-based polyradicals with pendant phenoxyls Reviewed
T Kaneko, T Makino, G Sato, T Aoki
POLYHEDRON 20 ( 11-14 ) 1291 - 1296 2001.5
Syntheses and enantioselective recognition of chiral poly(phenyleneethynylene)s bearing bulky optically active menthyl groups Reviewed
K Shinohara, T Aoki, T Kaneko, E Oikawa
POLYMER 42 ( 1 ) 351 - 355 2001.1
Polymerization of phenylacetylene-based monodendrons and structure of the corresponding polydendrons Reviewed
T Kaneko, M Asano, K Yamamoto, T Aoki
POLYMER JOURNAL 33 ( 11 ) 879 - 890 2001
Synthesis of galvinoxyl unit-containing derivatives of poly(phenylacetylene) and polystyrene, and oxygen permeation behavior of their membranes Reviewed
T Kaneko, T Yamamoto, H Tatsumi, T Aoki, E Oikawa
POLYMER 41 ( 12 ) 4437 - 4444 2000.6
Charge propagation in a polymer membrane incorporating zinc(II) phthalocyanine as studied by spectroelectrochemical techniques Reviewed
M Yagi, H Fukiya, T Kaneko, T Aoki, E Oikawa, M Kaneko
JOURNAL OF ELECTROANALYTICAL CHEMISTRY 481 ( 1 ) 69 - 75 2000.1
Polydendrons and polymacrocycles with phenyleneethynylene repeating unit Reviewed
Takashi Kaneko, Takahiro Horie, Motohiro Asano, Shinji Matsumoto, Kazuto Yamamoto, Toshiki Aoki, Eizo Oikawa
Polymers for Advanced Technologies 11 ( 8-12 ) 685 - 691 2000
Polymerization of a monodendron with phenylacetylene repeating unit Reviewed
T Kaneko, T Horie, T Aoki, E Oikawa
KOBUNSHI RONBUNSHU 57 ( 10 ) 672 - 677 2000
Synthesis of an optically active poly(phenylacetylene) bearing galvinoxyl radicals for magnetic materials Reviewed
T Kaneko, T Yamamoto, T Aoki, E Oikawa
CHEMISTRY LETTERS 28 ( 7 ) 623 - 624 1999.7
Synthesis and properties of polymers from disubstituted acetylenes with chiral pinanyl groups Reviewed
T Aoki, Y Kobayashi, T Kaneko, E Oikawa, Y Yamamura, Y Fujita, M Teraguchi, R Nomura, T Masuda
MACROMOLECULES 32 ( 1 ) 79 - 85 1999.1
Polymerization of (p-vinylphenyl)hydrogalvinoxyl and formation of a stable polyradical derivative Reviewed
T Kaneko, H Tatsumi, T Aoki, E Oikawa, H Yoshiki, N Yoshioka, E Tsuchida, H Nishide
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 37 ( 2 ) 189 - 198 1999.1
pi-conjugated polyradicals containing anthracene skeleton in the backbone chain Reviewed
T Kaneko, T Matsubara, T Aoki, E Oikawa
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS 334 221 - 228 1999
Pervaporation and solute separation through semi-interpenetrating and interpenetrating polymer network membranes prepared from poly(4-vinylpyridine) and poly(glycidyl methacrylate) Reviewed
E Oikawa, H Tatsumi, C Takano, T Kaneko, T Aoki
JOURNAL OF APPLIED POLYMER SCIENCE 69 ( 10 ) 1953 - 1963 1998.9
Polydendron: Polymerization of dendritic phenylacetylene monomers Reviewed
T Kaneko, T Horie, M Asano, T Aoki, E Oikawa
MACROMOLECULES 30 ( 10 ) 3118 - 3121 1997.5
Enantioselective permeation of racemates through a solid (+)-poly{2-[dimethyl(10-pinanyl)silyl]norbornadiene} membrane Reviewed
T Aoki, M Ohshima, KI Shinohara, T Kaneko, E Oikawa
POLYMER 38 ( 1 ) 235 - 238 1997.1
Detection of the site of an enantioselective interaction between chiral polypinanylsilane and a hydrophobic enantiomer by use of circular dichroism Reviewed
K Shinohara, T Aoki, T Kaneko, E Oikawa
CHEMISTRY LETTERS 1997 ( 4 ) 361 - 362 1997
FT Pulsed ESR/ESTN (Electron Spin Transient Nutation) Spectroscopy Applied to High-Spin Systems; Direct Evidence of the First High-Spin Polymer as Models for Organic Ferro- and Superpara-Magnets Reviewed
Takeji Takui, Kazunobu Sato, Daisuke Shiomi, Koichi Itoh, Takashi Kaneko, Eishun Tsuchida, Hiroyuki Nishide
Bulletin of Magnetic Resonance 18 ( 1-2 ) 21 - 29 1996.12
Poly(phenylenevinylene)-attached phenoxyl radicals: Ferromagnetic interaction through planarized and pi-conjugated skeletons Reviewed
H Nishide, T Kaneko, T Nii, K Katoh, E Tsuchida, PM Lahti
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 118 ( 40 ) 9695 - 9704 1996.10
Enantioselective permeation of various racemates through an optically active poly{1-[dimethyl(10-pinanyl)silyl]-1-propyne} membrane Reviewed
T Aoki, K Shinohara, T Kaneko, E Oikawa
MACROMOLECULES 29 ( 12 ) 4192 - 4198 1996.6
Synthesis of and ferromagnetic coupling in poly(phenylenevinylene)s bearing built-in t-butyl nitroxides Reviewed
H Nishide, T Kaneko, S Toriu, Y Kuzumaki, E Tsuchida
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 69 ( 2 ) 499 - 508 1996.2
UPS study of poly(phenylenevinylene)s substituted with hexyloxy, phenoxy, and nitroxy residues Reviewed
T Kaneko, E Ito, K Seki, E Tsuchida, H Nishide
POLYMER JOURNAL 28 ( 2 ) 182 - 184 1996
FT pulsed ESR/electron spin transient nutation (ESTN) spectroscopy applied to high-spin systems in solids; Direct evidence of a topologically controlled high-spin polymer as models for quasi 1D organic ferro- and superpara-magnets Reviewed
T Takui, K Sato, D Shiomi, K Itoh, T Kaneko, E Tsuchida, H Nishide
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS 278 A155 - A176 1996
FERROMAGNETIC SPIN COUPLING OF TERT-BUTYLNITROXIDE DIRADICALS THROUGH A CONJUGATED OLIGO(1,2-PHENYLENEVINYLENE)-COUPLER Reviewed
T KANEKO, S TORIU, E TSUCHIDA, H NISHIDE, D YAMAKI, G MARUTA, K YAMAGUCHI
CHEMISTRY LETTERS 24 ( 6 ) 421 - 422 1995.6
Synthesis of π-Conjugated Polyradicals with Poly(phenylenevinylene) Skeleton and Their Molecular Magnetism
Takashi Kaneko
1995.2
THROUGH-BOND AND LONG-RANGE FERROMAGNETIC SPIN ALIGNMENT IN A PI-CONJUGATED POLYRADICAL WITH A POLY(PHENYLENEVINYLENE) SKELETON Reviewed
H NISHIDE, T KANEKO, T NII, K KATOH, E TSUCHIDA, K YAMAGUCHI
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 117 ( 1 ) 548 - 549 1995.1
Electrochemical study of the nitroxyl radical derivatives built in the π‐conjugated poly(phenylenevinylene) skeleton Reviewed
Shuichi Toriu, Takashi Kaneko, Hiroyuki Nishide, Eishun Tsuchida
Polymers for Advanced Technologies 6 ( 11 ) 707 - 710 1995
pi-Conjugated polyradicals with poly(phenylenevinylene) skeleton and their through-bond and long-range interaction Reviewed
H Nishide, T Kaneko, S Toriu, K Katoh, M Takahashi, E Tsuchida, K Yamaguchi
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS 271 A131 - A138 1995
Poly[(N-oxyamino) and (oxyphenyl)phenylenevinylene]s: Magnetically coupled polyradicals in the chain Reviewed
T Kaneko, S Toriu, T Nii, E Tsuchida, H Nishide
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS 271 A153 - A160 1995
New aspects of high-spin chemistry Reviewed
K Itoh, T Takui, Y Teki, K Sato, D Shiomi, T Kinoshita, T Nakamura, T Momose, T Shida, T Okuno, A Izuoka, T Sugawara, T Kaneko, E Tsuchida, H Nishide
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS 271 129 - 146 1995
FT pulsed ESR/electron spin transient nutation spectroscopy in the study of molecular based magnetism: Applications to high-spin polymers and ferromagnetic materials Reviewed
T Takui, K Sato, D Shiomi, K Itoh, T Kaneko, E Tsuchida, H Nishide
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS 271 191 - 212 1995
Kazunobu Sato, Daisuke Shiomi, Takeji Takui, Koichi Itoh, Takashi Kaneko, Eishun Tsuchida, Hiroyuki Nishide
Journal of Spectroscopical Society of Japan 43 ( 5 ) 280 - 291 1994.12
POLY(PHENYLENEVINYLENE) BEARING BUILT-IN TERT-BUTYLNITROXIDE - A POLYRADICAL FERROMAGNETICALLY COUPLED IN THE INTRACHAIN Reviewed
T KANEKO, S TORIU, Y KUZUMAKI, H NISHIDE, E TSUCHIDA
CHEMISTRY LETTERS 23 ( 11 ) 2135 - 2138 1994.11
SEMIEMPIRICAL INVESTIGATION OF STILBENE-LINKED DIRADICALS AND MAGNETIC STUDY OF THEIR BIS(N-TERT-BUTYLNITROXIDE) VARIANTS Reviewed
N YOSHIOKA, PM LAHTI, T KANEKO, Y KUZUMAKI, E TSUCHIDA, H NISHIDE
JOURNAL OF ORGANIC CHEMISTRY 59 ( 15 ) 4272 - 4280 1994.7
MAGNETIC CHARACTERIZATION AND COMPUTATIONAL MODELING OF POLY(PHENYLACETYLENE)S BEARING STABLE RADICAL GROUPS Reviewed
H NISHIDE, T KANEKO, M IGARASHI, E TSUCHIDA, N YOSHIOKA, PM LAHTI
MACROMOLECULES 27 ( 11 ) 3082 - 3086 1994.5
ADSORPTION OF CALCIUM-ION AND OF HUMAN TOOTH ENAMEL TO METHACRYLIC-ACID RESIN Reviewed
T FUJIMORI, T KANEKO, H NISHIDE, E TSUCHIDA
KOBUNSHI RONBUNSHU 51 ( 1 ) 1 - 4 1994
Polyacetylene Derivatives with Chain-Sided Phenoxy and Galvinoxyl Radicals Reviewed
Hiroyuki Nishide, Takashi Kaneko, Ritsuko Gotoh, Eishun Tsuchida
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 233 ( 1 ) 89 - 95 1993.9
Poly(Phenylvinylene) and Poly(Phenylene-Vinylene) with Nitroxide Radicals Reviewed
Hiroyuki Nishide, Takashi Kaneko, Yoshihiro Kuzumaki, Naoki Yoshioka, Eishun Tsuchida
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 232 ( 1 ) 143 - 150 1993.8
POLY[[4-(N-TERT-BUTYL-N-HYDROXYAMINO)PHENYL]ACETYLENE] AND THE MAGNETIC PROPERTY OF ITS RADICAL DERIVATIVE Reviewed
H NISHIDE, T KANEKO, N YOSHIOKA, H AKIYAMA, M IGARASHI, E TSUCHIDA
MACROMOLECULES 26 ( 17 ) 4567 - 4571 1993.8
POLY(PHENYLVINYLENE) AND POLY(PHENYLENEVINYLENE) WITH NITROXIDE RADICALS Reviewed
H NISHIDE, T KANEKO, Y KUZUMAKI, N YOSHIOKA, E TSUCHIDA
MOLECULAR CRYSTALS AND LIQUID CRYSTALS 232 143 - 150 1993
PHOTOREACTION AND PHOTOINITIATION BEHAVIOR IN THE LIGHT-CURED DENTAL COMPOSITE RESINS Reviewed
Y FUJIMORI, T KANEKO, H NISHIDE, E TSUCHIDA
KOBUNSHI RONBUNSHU 50 ( 6 ) 485 - 488 1993
POLY[(P-ETHYNYLPHENYL)HYDROGALVINOXYL] AND ITS POLYRADICAL DERIVATIVE WITH HIGH-SPIN CONCENTRATION Reviewed
N YOSHIOKA, H NISHIDE, T KANEKO, H YOSHIKI, E TSUCHIDA
MACROMOLECULES 25 ( 15 ) 3838 - 3842 1992.7
Polymerization and photoinitiation behavior in the light‐cured dental composite resins Reviewed
Yukio Fujimori, Takashi Kaneko, Takahiko Kaku, Naoki Yoshioka, Hiroyuki Nishide, Eishun Tsuchida
Polymers for Advanced Technologies 3 ( 8 ) 437 - 441 1992
SYNTHESIS AND MAGNETIC-PROPERTIES OF CONJUGATED STABLE POLYRADICALS Reviewed
H NISHIDE, N YOSHIOKA, T KAKU, T KANEKO, M YAMAZAKI, E TSUCHIDA
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY A28 ( 11-12 ) 1177 - 1187 1991
UPS SPECTRA OF THE POLYACETYLENE DERIVATIVES CARRYING STABLE RADICAL SUBSTITUENTS Reviewed
N YOSHIOKA, H NISHIDE, T KAKU, T KANEKO, E TSUCHIDA, S NARIOKA, K SEKI
POLYMER JOURNAL 23 ( 7 ) 921 - 924 1991
POLY(PARA-ETHYNYLPHENYL)GALVINOXYL - FORMATION OF A NEW CONJUGATED POLYRADICAL WITH AN EXTRAORDINARILY HIGH-SPIN CONCENTRATION Reviewed
H NISHIDE, N YOSHIOKA, T KANEKO, E TSUCHIDA
MACROMOLECULES 23 ( 20 ) 4487 - 4488 1990.10
Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis
Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi( Role: Joint author , Chapter 15, pp.423-455, 共同研究につき分担部分抽出不可能)
Wiley 2011.9
次世代共役ポリマーの超階層制御と革新機能
金子隆司( Role: Joint author , 第II編, 第8章, pp 164-170)
シーエムシー出版 2009.1
化学便覧応用化学編第6版II
金子隆司( Role: Joint author , 20.3.5, pp1094-1097)
丸善 2003.1
Magnetic Properties of Organic Materials
Hiroyuki Nishide, Takashi Kaneko( Role: Joint author , Pendant and π-Conjugated Organic Polyradicals)
marcel dekker, inc. 1999.5
Magnetism: A Supramolecular Function
Takeji Takui, Kazunobu Sato, Daisuke Shiomi, Koichi Itoh, Takashi Kaneko, Eishun Tsuchida, Hiroyuki Nishide( Role: Joint author , FT Pulsed ESR/ESTN(Electron Spin Transient Nutation) Spectroscopy Applied to High-Spin Systems)
Kluwer Academic Publishers 1996.12
進化し続ける高分子酸素分離膜 Reviewed
青木俊樹, 金子隆司, 寺口昌宏
化学 74 ( 10 ) 66 - 67 2019.10
Synthesis of Two-dimensional Polymer for Molecular-sieve Membranes
Yu Zang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
MEMBRANE 39 ( 3 ) 118 - 131 2014.3
らせん選択重合体膜の光トポケミカル超分子膜化
浪越毅, 波多野慎悟, 寺口昌宏, 金子隆司, 青木俊樹
化学工業 61 ( 11 ) 846 - 854 2010.11
P-17 Program for Promoting High-Quality University Education "Breaking Away from Shallow Learning Habits" : Practice of design education in Department of Chemistry and Chemical Engineering, Niigata University
Shimizu Tadaaki, Kodama Tatsuya, Kimura Isao, Yoshida Masanori, Kaneko Takashi, Teraguchi Masahiro
22 690 - 691 2010.8
かさ高いイミノ置換基を持つフェニルアセチレンのらせん選択重合のリビング化とブロックコポリマーの合成
四柳宏基, 寺口昌宏, 寺口昌宏, 寺口昌宏, 浪越毅, 浪越毅, MARWANTA Edy, MARWANTA Edy, 金子隆司, 金子隆司, 青木俊樹, 青木俊樹, 青木俊樹, 青木俊樹
高分子学会予稿集(CD-ROM) 59 ( 1 Disk1 ) 2010
二つの種々のイミノ置換基を持つフェニルアセチレンのらせん選択重合により得られた片巻きらせんポリマーをキラル共触媒に用いたフェニルアセチレンのらせん選択重合
松本和樹, 四柳宏基, 浪越毅, 浪越毅, 寺口昌宏, 寺口昌宏, 寺口昌宏, 寺口昌宏, MARWANTA Edy, MARWANTA Edy, 金子隆司, 金子隆司, 金子隆司, 青木俊樹, 青木俊樹, 青木俊樹, 青木俊樹, 青木俊樹
高分子学会予稿集(CD-ROM) 58 ( 1 Disk1 ) 2009
片巻きらせんポリフェニルアセチレン自立膜の選択的芳香環形成による超分子膜の調製
浪越毅, 浪越毅, 鬼山祥幸, 波多野慎悟, 寺口昌宏, 寺口昌宏, 金子隆司, 金子隆司, 青木俊樹, 青木俊樹, 青木俊樹, 青木俊樹
高分子学会予稿集(CD-ROM) 57 ( 1 Disk1 ) 2008
アキラル配位子を持つフェニルアセチレンのらせん選択重合と生成ポリマー膜を用いた不斉反応
松本和樹, 四柳宏基, 浪越毅, 浪越毅, 寺口昌宏, 寺口昌宏, 寺口昌宏, MARWANTA Edy, MARWANTA Edy, 金子隆司, 金子隆司, 青木俊樹, 青木俊樹, 青木俊樹, 青木俊樹
高分子学会予稿集(CD-ROM) 57 ( 2 Disk1 ) 2008
高スピンπ共役高分子の設計と磁性 Invited
金子隆司, 青木俊樹, 寺口昌宏
Electrochemistry 75 ( 10 ) 834 - 838 2007.10
キラルらせんポリフェニルアセチレンを用いた選択吸着沈殿法による光学分割
波多野慎悟, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, 金子隆司
高分子学会予稿集(CD-ROM) 56 ( 1 Disk1 ) 2007
ラダー二重らせん構造を有するポリ(フェニルアセチレン)誘導体の合成と特性
二俣和夫, 波多野慎悟, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, 金子隆司
高分子学会予稿集(CD-ROM) 56 ( 1 Disk1 ) 2007
二つのアルキルアミド基を有するアキラルフェニルアセチレンのキラルロジウム触媒系によるらせん選択重合
寺口昌宏, 寺口昌宏, LIU Chenchen, 谷岡大輔, 波多野慎悟, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司
日本化学会講演予稿集 87th ( 2 ) 2007
光学分割膜素材としてのイオン交換基含有キラルポリ置換フェニルアセチレンの合成
石塚真由美, 波多野慎悟, 波多野慎悟, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, 金子隆司
日本化学会講演予稿集 87th ( 2 ) 2007
ガルビノキシル残基を有する3,5-ビス(ヒドロキシメチル)-4-ベンジルオキシフェニルアセチレンのらせん選択重合とそのキラルポリラジカルの光学活性・磁気特性
片桐寛夫, 金子隆司, 波多野慎悟, 寺口昌宏, 青木俊樹
日本化学会講演予稿集 87th ( 2 ) 2007
側鎖にガルビノキシルを有するポリ(ビナフチル-6,6′-ジイルエチニレン-1,3-フェニレンエチニレン)型キラルポリラジカルの合成と光学活性・磁気特性
阿部寛正, 金子隆司, 波多野慎悟, 寺口昌宏, 青木俊樹
日本化学会講演予稿集 87th ( 2 ) 2007
光学活性なメンチル基やピナニル基を有するポリ(フェニレンエチニレン)膜の脱置換基によるキラルらせん高分子膜の合成
井上真, 寺口昌宏, 寺口昌宏, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司
日本膜学会年会講演要旨集 29th 2007
側鎖にガルビノキシルを有するポリ(フェニルアセチレン)型キラルポリラジカルの合成と光学活性・磁気特性
梅田泰裕, 金子隆司, 波多野慎悟, 寺口昌宏, 青木俊樹
日本化学会講演予稿集 87th ( 2 ) 2007
ガルビノキシル残基を有するポリ(フェニルアセチレン)のらせん方向制御とそのポリラジカルの光・磁気特性
梅田泰裕, 金子隆司, 金子隆司, 波多野慎吾, 波多野慎吾, 寺口昌宏, 寺口昌宏, 青木俊樹, 青木俊樹
高分子学会予稿集(CD-ROM) 56 ( 1 Disk1 ) 2007
Dendrimers for Membrane Separation
Takashi Kaneko, Toshiki Aoki
Oleoscience 6 ( 9 ) 443 - 450 2006.9
二つの水酸基を有するポリ(フェニルアセチレン)誘導体の二重らせん構造の固定化
二俣和夫, 波多野慎悟, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, 金子隆司
高分子学会北陸支部研究発表講演会講演要旨集 55th 2006
金属錯体を有する片巻きらせんポリマー光学分割膜
波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, 金子隆司
日本膜学会年会講演要旨集 28th 2006
Enatioselective permeability through membranes containing one-handed helical polymer as chiral recognition agent
波多野慎悟, 千野隆之, 寺口昌宏, 寺口昌宏, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司, 田中孝明
日本化学会講演予稿集 86th ( 2 ) 2006
ガルビノキシルを有するポリ(1,3-フェニレンエチニレン)型キラルポリラジカルの合成とその磁性及び磁気光学効果
吉本翔太, 金子隆司, 寺口昌宏, 寺口昌宏, 波多野慎吾, 波多野慎吾, 青木俊樹, 青木俊樹, 青木俊樹
高分子学会予稿集(CD-ROM) 55 ( 2 Disk1 ) 2006
らせん選択重合による高分子不斉らせん構造を持つ配位子の合成
松本和樹, 寺口昌宏, 寺口昌宏, 波多野慎悟, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司
高分子学会北陸支部研究発表講演会講演要旨集 55th 2006
安定ラジカル骨格を有するフェニルアセチレン誘導体の合成と重合
佐藤誠之, 金子隆司, 寺口昌宏, 寺口昌宏, 波多野慎悟, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹
高分子学会北陸支部研究発表講演会講演要旨集 55th 2006
片巻きらせんポリフェニルアセチレンの異常な分解性-分解機構の考察と分解制御-
波多野慎悟, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, 金子隆司
高分子学会予稿集(CD-ROM) 55 ( 2 Disk1 ) 2006
キラルなポリ(フェニレンエチニレン)膜の合成とそれらポリマーの不斉らせん構造
井上真, 寺口昌宏, 寺口昌宏, 波多野慎悟, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司
高分子学会予稿集(CD-ROM) 55 ( 2 Disk1 ) 2006
側鎖に金属錯体部位を有するキラルらせんポリフェニルアセチレンの合成とキラル認識能への金属錯体の効果
波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, 金子隆司
高分子学会予稿集(CD-ROM) 55 ( 1 Disk1 ) 2006
光学活性なピナニルシリル基と2つの水酸基を持つフェニルアセチレンのらせん選択共重合と生成高分子の主鎖らせん構造の刺激応答性,脱シリル化反応および光学異性体選択透過性
寺口昌宏, 寺口昌宏, 持舘和臣, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司
高分子学会予稿集(CD-ROM) 55 ( 2 Disk1 ) 2006
二つの水素結合可能な官能基を有するポリ(フェニルアセチレン)誘導体のラダー二重らせん構造の固定化
二俣和夫, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, 金子隆司
高分子学会予稿集(CD-ROM) 55 ( 2 Disk1 ) 2006
光学活性なポリ(フェニレンエチニレン)膜の合成と生成ポリマーの主鎖不斉らせん構造
寺口昌宏, 寺口昌宏, 井上真, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司
ポリマー材料フォーラム講演予稿集 15th 2006
光学活性な置換基を持つポリ(フェニレンエチニレン)膜の合成とそれらポリマーの不斉らせん構造
井上真, 寺口昌宏, 寺口昌宏, 波多野慎悟, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司
高分子学会北陸支部研究発表講演会講演要旨集 55th 2006
主鎖のらせんのみに起因する不斉を持つポリフェニルアセチレンの合成-アキラル フェニルアセチレンのらせん選択重合とキラル置換ポリフェニルアセチレンの脱置換基-
青木俊樹, 寺口昌宏, 金子隆司
高分子加工 54 ( 12 ) 542 - 550 2005.12
分子内水素結合のみにより安定化されたポリフェニルアセチレンのキラルらせん主鎖構の制御-安定性,刺激応答性と分解性
波多野慎悟, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, KIM Sun-Young, 金子隆司, 金子隆司
高分子学会予稿集(CD-ROM) 54 ( 1 Disk1 ) 2005
二つのシラノール基をもつフェニルアセチレンのらせん選択共重合と生成キラルらせん主鎖の固定
二俣和夫, KIM Sun-Young, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, 金子隆司, 金子隆司
高分子学会予稿集(CD-ROM) 54 ( 2 Disk1 ) 2005
主鎖のみに不斉構造をもつポリフェニルアセチレンのキラルらせん構造の安定性,刺激応答性,分解性-分子内水素結合の効果
波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 寺口昌宏, 寺口昌宏, 金子隆司, 金子隆司
高分子学会予稿集(CD-ROM) 54 ( 2 Disk1 ) 2005
カルボキシル基またはアミノ酸基含有キラルらせんポリ(フェニルアセチレン)膜の光学異性体選択透過性
持舘和臣, 寺口昌宏, 寺口昌宏, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司, 金子隆司
高分子学会予稿集(CD-ROM) 54 ( 2 Disk1 ) 2005
水酸基含有キラルらせんポリ(フェニルアセチレン)膜の光学異性体選択透過性
持舘和臣, 寺口昌宏, 寺口昌宏, KIM Sun-Young, 波多野慎悟, 金子隆司, 金子隆司, 青木俊樹, 青木俊樹
日本膜学会年会講演要旨集 27th 2005
光学活性なピナニルシリル基と2つの水酸基を持つフェニルアセチレンのらせん選択共重合
持舘和臣, KIM Sun-Young, 寺口昌宏, 寺口昌宏, 青木俊樹, 青木俊樹, 波多野慎吾, 金子隆司, 金子隆司
高分子学会予稿集(CD-ROM) 54 ( 1 Disk1 ) 2005
膜状態での脱ピナニルシリル化反応による水酸基含有キラルらせんポリフェニルアセチレン膜の合成と光学異性体選択透過性
寺口昌宏, 寺口昌宏, 持舘和臣, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司, 金子隆司, 波多野慎悟
高分子学会予稿集(CD-ROM) 54 ( 2 Disk1 ) 2005
キラル触媒系を用いた4-アルキルオキシ-3,5-ビス(ヒドロキシメチル)フェニルアセチレンのらせん選択(共)重合
岸本拓也, 波多野慎悟, 青木俊樹, 青木俊樹, 金子隆司, 金子隆司, 寺口昌宏, 寺口昌宏, KIM Sun-Young
高分子学会予稿集(CD-ROM) 54 ( 1 Disk1 ) 2005
光学活性なピナニルシリル基と2つの水酸基を持つフェニルアセチレンのらせん選択共重合と生成高分子の脱シリル化反応,光学異性体選択透過性
持舘和臣, 寺口昌宏, 寺口昌宏, 波多野慎悟, 青木俊樹, 青木俊樹, 青木俊樹, 金子隆司, 金子隆司
高分子学会予稿集(CD-ROM) 54 ( 2 Disk1 ) 2005
青木俊樹, 金子隆司, 寺口昌宏
高分子加工 51 ( 4 ) 168 - 176 2002.4
青木俊樹, 金子隆司, 寺口昌宏
化学工業 52 ( 9 ) 683 - 691 2001.9
Synthesis of π-Conjugated Polymers Using Acetylene Units
KANEKO Takashi
Kobunshi 50 ( 3 ) 153 - 153 2001.3
金子隆司, 青木俊樹, 及川栄蔵
高分子加工 48 ( 3 ) 113 - 117 1999.3
Macromolecular Design of Synthetic Polymer for Optical Resolution Membrane
AOKI Toshiki, KANEKO Takashi, OIKAWA Eizo
MEMBRANE 22 ( 3 ) 126 - 134 1997.3
KANEKO Takashi
49 ( 2 ) 139 - 142 1996.2
Macromolecular design for optical resolution membrane
Toshiki Aoki, Ken ichi Shinohara, Takashi Kaneko, Eizo Oikawa
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry 54 ( 6 ) 525 - 536 1996
ガルビノキシル残基を有するポリ(1,3-フェニレンエチニレン)の片 巻優 先らせんフォルダマー形成における置換基効果
二宮浩彰, 金子隆司, 大石智之, 垣花百合子, 寺口昌宏, 青木俊樹
第60回高分子学会年次大会 2011.5 高分子学会
側鎖にニトロ基とニトロニルニトロキシド残基を有するポリ(1,3-フェニレンエチニレン)型キラルポリラジカルの合成とらせんフォルダマー形成
廣野一也, 加藤清亮, 大石智之, 垣花百合子, 寺口昌宏, 青木俊樹, 金子隆司
日本化学会第91回春季年会 2011.3 日本化学会
フェノキシ置換ポリ(1,8-ナフチレンエチニレン-9,10-アントリレンエチニレン)およびそのダイマーモデルの合成
塚本圭太, 大石智之, 垣花百合子, 寺口昌宏, 青木俊樹, 金子隆司
日本化学会第91回春季年会 2011.3 日本化学会
側鎖にガルビノキシルとフェノキシルを有するポリ(1,3-フェニレンエチニレン)型ポリラジカルフォルダマーの合成とその磁気的性質
岩村恭平, 大石智之, 垣花百合子, 寺口昌宏, 青木俊樹, 金子隆司
第59回高分子学会北陸支部研究発表会 2010.11 高分子学会北陸支部
フェノール残基を導入した2,6-置換ポリ(9,10-アントリレンエチニレン)の合成とその電子状態
今野良平, 大石智之, 垣花百合子, 寺口昌宏, 青木俊樹, 金子隆司
第59回高分子学会北陸支部研究発表会 2010.11 高分子学会北陸支部
Sequential Poly(aryleneethynylene)-Based Polyradicals: Synthesis and Magnetic Property International conference
Takashi Kaneko, Kiyoaki Kato, Toshihiro Saito, Masahiro Teraguchi, Toshiki Aoki
Interanational Conference on Science and Technology of Synthetic Metals 2010 2010.7
Helix-Sense-Selective Polymerization of (3,5-Bis(hydroxymethyl)-4-phenyl)phenylacetylenes International conference
Manami Osawa, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
Interanational Conference on Science and Technology of Synthetic Metals 2010 2010.7
Synthesis of Poly(1,3-phenyleneethynylene)s with Pendant Galvinoxyl, Chiral and Hydrophilic Moieties, and Their Forming Ability of Helical Foldamer International conference
Hiroaki Ninomiya, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
Interanational Conference on Science and Technology of Synthetic Metals 2010 2010.7
Synthesis of Optically Active Poly(Binaphthyl-6,6-diylethynylene-9,10-anthryleneethynylene) Bearing Phenoxyls at 2,7-Positions of Anthracene International conference
Masahiro Tsuchida, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko
Interanational Conference on Science and Technology of Synthetic Metals 2010 2010.7
4位にフェニル基を有する3,5-ビス(ヒドロキシメチル)フェニルアセチレンのらせん選択重合と光学不活性な重合体からの片巻優先らせん誘起
大澤愛実, 浪越 毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
第59回高分子学会年次大会 2010.5 高分子学会
側鎖にニトロニルニトロキシドを有するポリ(1,3-フェニレンエチニレン)型キラルポリラジカルのらせんフォルダマー構造制御と磁気的性質
加藤清亮, 浪越毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
第58回高分子討論会 2009.9 高分子学会
オリゴ(9,10-アントリレンエチニレン)構造を介したフェノキシラジカル類の磁気的相互作用
高村政克, 浪越毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
第58回高分子討論会 2009.9 高分子学会
アントラセンの2,7位にフェノール残基を有する光学活性なポリ(ビナフチル-6,6'-ジイルエチニレン-9,10-アントリレンエチニレン)の合成
土田昌弘, 浪越毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
2009年支部合同新潟地方大会(第58回高分子学会北陸支部研究発表講演会) 2009.8 日本化学会関東支部、高分子学会北陸支部
4位にフェニル基を有する3,5-ビス(ヒドロキシメチル)フェニルアセチレンのらせん選択重合
大澤愛実, 浪越毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
2009年支部合同新潟地方大会(第58回高分子学会北陸支部研究発表講演会) 2009.8 日本化学会関東支部、高分子学会北陸支部
2位にヒドロキシエトキシ基、5位にガルビノキシル残基を有するポリ(1,3-フェニレンエチニレン)の合成とらせんフォルダマー形成能
二宮浩彰, 浪越毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
2009年支部合同新潟地方大会(第58回高分子学会北陸支部研究発表講演会) 2009.8 日本化学会関東支部、高分子学会北陸支部
ガルビノキシル置換オリゴ(9,10-アントリレンエチニレン)の合成及び電子構造と磁気的性質
高村政克, 浪越 毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
第58回高分子学会年次大会 2009.5 高分子学会
側鎖にニトロニルニトロキシドを有するポリ(1,3-フェニレンエチニレン)型キラルポリラジカルの合成とらせんフォルダマー構造制御
加藤清亮, 浪越 毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
第57回高分子学会北陸支部研究発表講演会 2008.11 高分子学会北陸支部
安定ラジカル部位を有するアントリレンエチニレンユニットと柔軟なオリゴメチレンユニットからなるモノマーの合成と重合
落合健祐, 浪越 毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
第57回高分子学会北陸支部研究発表講演会 2008.11 高分子学会北陸支部
Synthesis of Optically Active p-Conjugated Polymers Bearing Stable Radicals and Their Chiroptical and Magnetic Properties International conference
Takashi Kaneko, Hiromasa Abe, Hiroo Katagiri, Atsuko Kawami, Tsuyoshi Namikoshi, Edy Marwanta, Masahiro Teraguchi, Toshiki Aoki
18th Iketani Conference: Interanational Conference of Super-Hierarchical Structures and Innivative Functions of Next-Generation Conjugated Polymers 2008.10
ガルビノキシルを有するポリ(1,3-フェニレンエチニレン)の片巻優先らせんフォルダマー形成能及び磁気的性質
阿部 寛正, 浪越 毅, マルワンタ エディ, 寺口 昌宏, 青木 俊樹, 金子 隆司
第57回高分子討論会 2008.9 高分子学会
ガルビノキシル残基を有するポリ{3,5-ビス(ヒドロキシメチル)-4-ベンジルオキシフェニルアセチレン}の光学活性らせん主鎖構造と磁気特性
片桐 寛夫, 浪越 毅, エディ マルワンタ, 寺口 昌宏, 青木 俊樹, 金子 隆司
第57回高分子討論会 2008.9 高分子学会
TEMPO を有するポリ(フェニルアセチレン)の光学活性らせん形成能と磁気的性質
川見 敦子, 金子 隆司, 浪越 毅, マルワンタ エディ, 寺口 昌宏, 青木 俊樹
第57回高分子討論会 2008.9 高分子学会
Synthesis of Optically Active Helical Poly(phenylacetylene)-based Polyradicals and Magnetic Interaction Depending on Their Helicity International conference
Takashi Kaneko, Yasuhiro Umeda, Hiroo Katagiri, Atsuko Kawami, Tsuyoshi Namikoshi, Edy Marwanta, Masahiro Teraguchi, Toshiki Aoki
The 11th Int. Conf. Molecule-Based Magnets 2008.9
らせん選択重合により得られたガルビノキシル残基を有するポリ[3,5-ビス(ヒドロキシメチル)-4-ベンジルオキシフェニルアセチレン]の光学活性と磁気特性
片桐寛夫, 浪越 毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
第57回高分子学会年次大会 2008.5 高分子学会
主鎖に光学活性なビナフチル構造を含むガルビノキシル置換ポリ(1,3-フェニレンエチニレン)の合成とそのフォルダマー形成能及び磁気特性
阿部寛正, 浪越 毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
第57回高分子学会年次大会 2008.5 高分子学会
TEMPOを有するポリ(フェニルアセチレン)の光学活性らせん誘起と磁気的性質
川見敦子, 浪越 毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
日本化学会第88回春季年会 2008.3 日本化学会
側鎖にレゾルシノール誘導体を有するアセチレンモノマーの重合とその光学活性らせん誘起
梁 暁芸, 浪越 毅, エディ マルワンタ, 寺口昌宏, 青木俊樹, 金子隆司
日本化学会第88回春季年会 2008.3 日本化学会
TEMPO を有するフェニルアセチレン誘導体の重合とらせん構造制御
川見 敦子, 寺口 昌宏, 青木 俊樹, 金子 隆司
第56回高分子討論会 2007.9 高分子学会
安定ラジカル骨格を有するアントリルアセチレン誘導体の重合
佐藤 誠之, 寺口 昌宏, 青木 俊樹, 金子 隆司
第56回高分子討論会 2007.9 高分子学会
(4-エチニルフェニル)ガルビノキシルの共重合におけるらせん方向制御とそのポリラジカルの光・磁気特性
梅田 泰裕, 寺口 昌宏, 青木 俊樹, 金子 隆司
第56回高分子討論会 2007.9 高分子学会
Helix-sense-selective Polymerization of 3,5-Bis(hydroxymethyl)-4-benzyloxyphenylacetylene Bearing Galvinoxyl, and Chiroptical and Magnetic Properties International conference
Hiroo Katagiri, Takashi Kaneko, Takeshi Namikoshi, Edy Marwanta, Masahiro Teraguchi, Toshiki Aoki
The 4th International Symposium on Advanced Materials in Asia-Pacific Rim 2007.7
Synthesis of Poly(binaphthyl-6,6'-diylethynylene-1,3-phenyleneethynylene)-based Chiral Polyradical Bearing Galvinoxyl, and Its Chiroptical and Magnetic Properties International conference
Hiromasa Abe, Takashi Kaneko, Takeshi Namikoshi, Edy Marwanta, Masahiro Teraguchi, Toshiki Aoki
The 4th International Symposium on Advanced Materials in Asia-Pacific Rim 2007.7
Synthesis of Oligo(anthryleneethynylene)-based Foldamers Containing Stable Radicals International conference
Kensuke Ochiai, Takashi Kaneko, Takeshi Namikoshi, Edy Marwanta, Masahiro Teraguchi, Toshiki Aoki
The 4th International Symposium on Advanced Materials in Asia-Pacific Rim 2007.7
Synthesis of TEMPO-pendant Poly(phenylacetylene)s, and Their Chiroptical and Magnetic Properties International conference
Atsuko Kawami, Takashi Kaneko, Takeshi Namikoshi, Edy Marwanta, Masahiro Teraguchi, Toshiki Aoki
The 4th International Symposium on Advanced Materials in Asia-Pacific Rim 2007.7
Magnetic Properties of TEMPO Radicals Included in a Supramolecular Anthracene Derivative International conference
Masayuki Sato, Takashi Kaneko, Takeshi Namikoshi, Edy Marwanta, Masahiro Teraguchi, Toshiki Aoki
The 4th International Symposium on Advanced Materials in Asia-Pacific Rim 2007.7
The Control of the Helix Sense in the Copolymerization of (4-Ethynylphenyl)galvinoxyl by the Composition of Comonomer International conference
Yasuhiro Umeda, Takashi Kaneko, Takeshi Namikoshi, Edy Marwanta, Masahiro Teraguchi, Toshiki Aoki
The 4th International Symposium on Advanced Materials in Asia-Pacific Rim 2007.7
Synthesis of Optically Active Poly(aryleneethynylene)s Bearing Stable Radicals and Their Chiroptical and Magnetic Properties International conference
Takashi Kaneko, Hiromasa Abe, Shouta Yoshimoto, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
The 7th Int. Conf. on Optical Probes of -Conjugated Polymers and Functional Self-Assemblies 2007.6
Helix-sense-selective Polymerization of 3,5-bis(hydroxymethyl)-4-benzyloxyphenylacetylene Bearing Galvinoxyl, and Optical Activity International conference
Hiroo Katagiri, Takashi Kaneko, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
The 7th Int. Conf. on Optical Probes of -Conjugated Polymers and Functional Self-Assemblies 2007.6
The Control of the Helix Sense for Poly(phenylacetylene)s Bearing Galvinoxyl Residues by the Composition of Co-monomer International conference
Yasuhiro Umeda, Takashi Kaneko, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
The 7th Int. Conf. on Optical Probes of -Conjugated Polymers and Functional Self-Assemblies 2007.6
ガルビノキシル残基を有するポリ(フェニルアセチレン)のらせん方向制御とそのポリラジカルの光・磁気特性
梅田 泰裕, 金子 隆司, 寺口 昌宏, 波多野 慎悟, 青木 俊樹
第56回高分子学会年次大会 2007.5 高分子学会
ガルビノキシル残基を有する3,5-ビス(ヒドロキシメチル)-4-ベンジルオキシフェニルアセチレンのらせん選択重合とそのキラルポリラジカルの光学活性・磁気特性
片桐寛夫, 金子隆司, 波多野慎悟, 寺口昌宏, 青木俊樹
日本化学会第87回春季年会 2007.3 日本化学会
側鎖にガルビノキシルを有するポリ(ビナフチル-6,6'-ジイルエチニレン-1,3-フェニレンエチニレン)型キラルポリラジカルの合成と光学活性・磁気特性
阿部寛正, 金子隆司, 波多野慎悟, 寺口昌宏, 青木俊樹
日本化学会第87回春季年会 2007.3 日本化学会
側鎖にガルビノキシルを有するポリ(フェニルアセチレン)型キラルポリラジカルの合成と光学活性・磁気特性
梅田泰裕, 金子隆司, 波多野慎悟, 寺口昌宏, 青木俊樹
日本化学会第87回春季年会 2007.3 日本化学会
Synthesis of optically active helical polyacetylenes bearing stable radicals via helix-sense-selective polymerization International conference
Takashi Kaneko, Yasuhiro Umeda, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
International Symposiumon Fusion Tech 2006-2007 2007.1
ガルビノキシルを有するポリ(1,3-フェニレンエチニレン)型キラルポリラジカルの合成とその磁性及び磁気光学効果
吉本翔太, 金子隆司, 寺口昌宏, 波多野慎悟, 青木俊樹
第55回高分子討論会 2006.9 高分子学会
Synthesis of Optically Active Helical Polymers Bearing Stable Radicals and Their Chiroptical and Magnetic Properties International conference
Takashi Kaneko, Yasuhiro Umeda, Shota Yoshimoto, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
The 10th Int. Conf. Molecule-Based Magnets 2006.8
Synthesis of optically active helical polymers bearing stable radicals via helix-sense-selective polymerization of phenylacetylenes International conference
Takashi Kaneko, Yasuhiro Umeda, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
The 10th World Multi-Conference on Systemics, Cybernetics and Informatics (WMSCI2006) 2006.7
Helix-sense-selective polymerization of phenylacetylenes bearing galvinoxyl residues International conference
Takashi Kaneko, Yasuhiro Umeda, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
3rd IUPAC-sponsored International Symposium on Macro- and Supramolecular Architectures and Materials (MAM-06) 2006.5
2,7位にフェノール残基を有するオリゴ(アントリレンエチニレン)の酸化及びその電子状態と磁気特性
田中毅, 金子 隆司, 八木政行, 寺口 昌宏, 青木 俊樹
第55回高分子学会年次大会 2006.5 高分子学会
ガルビノキシル基を有するポリ(1,3-フェニレンエチニレン)型キラルポリラジカルの合成とその光・磁気特性
吉本翔太, 金子 隆司, 寺口 昌宏, 青木 俊樹
第55回高分子学会年次大会 2006.5 高分子学会
Helix-sense-selective polymerization of achiral and bulky phenylacetylenes International conference
Takashi Kaneko, Yasuhiro Umeda, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
The 3rd International Symposium on Advanced Materials in Asia-Pacific Rim 2006.5
Helix-sense-selective polymerization of phenylacetylene derivatives International conference
Takashi Kaneko
The 2006 symposium of the Polymer Society of Korea 2006.4
アントラセン超分子に包接された安定ラジカルの磁気特性
佐藤誠之, 金子隆司, 青木俊樹, 寺口昌宏
日本化学会第86回春季年会 2006.3 日本化学会
塩基量により分子量制御されたオリゴ(アントリレンエチニレン)誘導体の合成と単離した各オリゴマーの電子特性
田中毅, 金子隆司, 青木俊樹, 寺口昌宏
日本化学会第86回春季年会 2006.3 日本化学会
平成12年度 高分子学会 高分子研究奨励賞
2001.5 高分子学会
金子隆司
Absolute asymmetric synthesis via helix-sense-selective polymerization and selective degradation reaction using circularly polarized light as asymmetric source
Grant number:19K05453
2019.4 - 2022.3
System name:Grants-in-Aid for Scientific Research
Research category:Grant-in-Aid for Scientific Research (C)
Awarding organization:Japan Society for the Promotion of Science
TERAGUCHI Masahiro
Grant amount:\4420000 ( Direct Cost: \3400000 、 Indirect Cost:\1020000 )
In this research project, we investigated a method for producing optically active compounds without using any optically active compounds as a chiral source by utilizing helix-sense-selective polymerization and helix-sense-selective degradation by circular polarized light.
It was shown that the chiral aggregation derived from an achiral monomer may caused the spontaneous helix-sense-selective polymerization in the absence of a chiral source. In addition, optical resolution of racemic mixture of alcohol was successfully achieved by enantioselective helix-sense-selcetive polymerization of a monomer synthesized from a racemic mixture of chiral alcohol, followed by helix-sense-selective degradation of the obtained polymer by irradiation of circularly polarized light.
The optical yields of the obtained alcohol were high. Therefore, optical resolution was achieved with high optical yield without the use of any optically active compounds.
Absolute asymmetric polymer synthesis by chiral amplification helix-sense-selective polymerization using circularly polarized light as a chiral source
Grant number:17K19153
2017.6 - 2020.3
System name:Grants-in-Aid for Scientific Research
Research category:Grant-in-Aid for Challenging Research (Exploratory)
Awarding organization:Japan Society for the Promotion of Science
AOKI TOSHIKI
Grant amount:\6500000 ( Direct Cost: \5000000 、 Indirect Cost:\1500000 )
Polymerization in an achiral polymerization system that does not contain any chiral source giving a one-handed helical polymer(spontaneousHSSP)was investigated.As the number of trials increase,the ratio of the cumulative number of polymerizations giving the right-handed and the left-handed polymers were closer to1.We successfully prepared a chiral microcrystalline monomer which does not contain any chiral compound by following two step method:1)Crystallization of the monomer in the presence of a chiral amine;2)Complete removal of the chiral amine under a high vacuum condition.The obtained microcrystalline monomer gave a one-handed helical polymer by using an achiral catalyst system.Therefore,it was suggested that crystal structure with asymmetric alignment accidentally induced may be the cause of spontaneous HSSP.
Further,the helix-sense-selective degradation(HSSD)of racemic helical polymer by circularly polarized irradiation,was found for the first time to proceed in a solution state.
Self-supporting gas separation membranes by molecular sieving effects of molecular size pores in 2D macromolecules synthesized by SCAT reaction of helical polymers
Grant number:16H04153
2016.4 - 2021.3
System name:Grants-in-Aid for Scientific Research
Research category:Grant-in-Aid for Scientific Research (B)
Awarding organization:Japan Society for the Promotion of Science
AOKI Toshiki
Grant amount:\18200000 ( Direct Cost: \14000000 、 Indirect Cost:\4200000 )
A thin layer of 2D macromolecules with molecular-sized pores was synthesized by solid-solid interface polycondensation in laminated membranes of two cis-cisoid poly(imino-containing phenylacetylene)s followed by highly selective photocyclic aromatization (SCAT). The precise 2D molecular structure including fraction and size of rings (pores) can be fully estimated. The composite membranes of the 2D macromolecule showed good oxygen permselectivity exceeding the Robeson upper line.
モノマー配列でプログラミングされたらせんキラルポリラジカル高次構造と磁気光学機能
2016.4 - 2020.3
System name:科学研究費補助金
Grant type:Competitive
Synthesis of chiral helical polymers by highly selective photocyclic aromatization(SCAT) using light as asymmetric source, and asymmetric amplification
Grant number:16K05790
2016.4 - 2019.3
System name:Grants-in-Aid for Scientific Research
Research category:Grant-in-Aid for Scientific Research (C)
Awarding organization:Japan Society for the Promotion of Science
TERAGUCHI Masahiro
Grant amount:\5070000 ( Direct Cost: \3900000 、 Indirect Cost:\1170000 )
In this project, at first synthesis of an optically active one-handed helical polymer from a racemic helical polymer using only circularly polarized light(CPL) as an asymmetric source without using an optically active chemical substance was achieved, and then by using the obtained a one-handed helical polymer as chiral cocatalyst which was generated by CPL as an asymmetric source , we achieved helix-sense-selective polymerization(HSSP) of achiral phenylacetylene derivatives. It has been revealed that a racemic helical polymer obtained from a phenylacetylene monomer having a planar substituent such as a diphenylazomethine group is efficiently decomposed in helix-sense-selective manner by CPL irradiation to give a chiral one-handed helical polymer. In addition, using a one-handed helical polymer obtained by HSSP as a chiral cocatalyst (asymmetric source), a new one-handed helical polymer was successfully obtained by HSSP (chiral transfer).
Synthesis of Polymer Membranes Having Optically Active Nanopores Arrayed in Helical Manner for Membrane Separation
Grant number:25390002
2013.4 - 2016.3
System name:Grants-in-Aid for Scientific Research
Research category:Grant-in-Aid for Scientific Research (C)
Awarding organization:Japan Society for the Promotion of Science
TERAGUCHI MASAHIRO, AOKI TOSHIKI, KANEKO TAKASHI
Grant amount:\5070000 ( Direct Cost: \3900000 、 Indirect Cost:\1170000 )
Synthesis of stereoregular one-handed helical polymers by polymerization of chiral monomers using a chiral catalyst and achiral monomers using a chiral catalyst in helix-sense-selective manner, or a chiral-helix induction to achiral polymers in chiral solvents was investigated, and their free-standing membranes were fabricated by solvent casting method. By removal of the chiral substituents in the polymer in membrane reaction, synthesis of polymer membranes having chiral nanopores arranged in helical manner was achieved. These membranes showed an enantioselective permeability.
モノマー配列でプログラミングされたらせんキラルポリラジカル磁気秩序と磁気光学機能
2012.4 - 2016.3
System name:科学研究費補助金
Grant type:Competitive
高効率の太陽電池デバイスを目指した共役高分子材料の基礎研究
2011.4 - 2012.3
System name:内田エネルギー科学振興財団試験研究費助成
Awarding organization:民間財団等
Grant type:Competitive
Spin alignment of chiral polyradicals by nano-structure design and their magneto-optical properties
2008.4 - 2012.3
System name:Grant-in-Aid for Scientific Research
Grant type:Competitive
化学磁気メモリー素子のためのらせん主鎖ポリラジカルの開発
2008.4 - 2009.3
System name:科学技術振興機構(JST)重点地域研究開発推進事業「シーズ発掘試験」
Awarding organization:その他省庁等
Grant type:Competitive
Synthesis of Chiral p-Conjugated Polyradicals and Their Magnetic and Magneto-optical Properties
2007.4 - 2009.3
System name:Grant-in-Aid for Scientific Research
Grant type:Competitive
Supramolecular self-supporting membrane having chiral nano-channel from supramolecular ladder chiral double helical polymer
Grant number:19350054
2007 - 2009
System name:Grants-in-Aid for Scientific Research
Research category:Grant-in-Aid for Scientific Research (B)
Awarding organization:Japan Society for the Promotion of Science
AOKI Toshiki, KANEKO Takashi, TERAGUCHI Masahiro, NAMIKOSHI Takeshi, HADANO Shingo
Grant amount:\17290000 ( Direct Cost: \13300000 、 Indirect Cost:\3990000 )
Magnetochemical memory of pai-conjugated polyradical supramolecule / organic radicals inclusion compounds
2006.4 - 2008.3
System name:Grant-in-Aid for Scientific Research
Grant type:Competitive
Nano-scale spin alignment for pai-conjugated polymer materials and development for chiral polyradicals
2005.4 - 2008.3
System name:Grant-in-Aid for Scientific Research
Grant type:Competitive
Synthesis of pai-conjugated polyradical magnetic materials and their magnetochromism
2004.4 - 2006.3
System name:Grant-in-Aid for Scientific Research
Grant type:Competitive
デンドリマー置換フェニルアセチレンの重合とナノ構造制御による分離膜材料への応用
2004.4 - 2005.3
System name:向科学技術振興財団研究助成
Awarding organization:民間財団等
Grant type:Competitive
Supermolecular Ladder Chiral Double Helical Polymer by Helix-sense-selective Polymerization Controlled by Achiral Values
Grant number:16350061
2004 - 2006
System name:Grants-in-Aid for Scientific Research
Research category:Grant-in-Aid for Scientific Research (B)
Awarding organization:Japan Society for the Promotion of Science
AOKI Toshiki, KANEKO Takashi
Grant amount:\14200000 ( Direct Cost: \14200000 )
The investigators of this research project found an induced chirality in the main chain when a phenylacetylene having a bulky chiral substituent was polymerized. We thought this chiral structure did not contain asymmetric centers and was caused only by one-handed helical conformation. However, this chiral polymer contained two kinds of chiral structures and therefore the recognition ability and the precise structure of the chiral main chain itself could not be confirmed.
To clarify it we realized synthesis of a chiral helical polyphenylacetylene which does not have any other chiral moieties by helix-sense-selective polymerization of an achiral monomer with a chiral catalytic system. In addition, we found the helix sense can be controlled by changing not only chiral amounts but also achiral amounts. And the chiral main-chain of the resulting polymer was found to be maintained by intramolecular hydrogen bonds, i.e., this polymer has a supermolecular ladder chiral double helical polymer structure. Therefore this main chain chirality disappeared when a polar solvent was added.
In this study, we studied further the following points on the new synthetic method and the new polymer obtained by the method.
(1) Generalization of the helix-sense-selective polymerization
(2) Discussion of the mechanism of the helix-sense-selective polymerization
(3) Development of new functions of the supermolecular ladder chiral double helical polymer
(4) Discussion of the molecular structure of the supermolecular ladder chiral double helical polymer
Siインプリンテイング法によるキラル分子孔を持つ光学異性体分離膜の創製
Grant number:15655039
2003 - 2004
System name:科学研究費助成事業
Research category:萌芽研究
Awarding organization:日本学術振興会
青木 俊樹, 金子 隆司, 寺口 昌宏
Grant amount:\2200000 ( Direct Cost: \2200000 )
分子インプリンテイング法(MIP法)は分離対象物質を鋳型分子として、これと主として2次結合を生じるモノマーと架橋剤とともに混合し、重合後鋳型分子を除去し、これを認識する空間を材料内に生じさせる方法である。MIP法で得られた高分子はHPLC固定相として分子混合物に対し分離能を示すが、膜としての例はほとんど無い。特に光学異性体分離は従来のMIP法では困難である。そこで本研究では研究代表者らが最近見出した「Siインプリンテイング法」を光学異性体分離膜の創製に有効に用いることを目的とした。「Siインプリンテイング法」は、従来のMIP法が主に2次結合を用いているのに対し、1次結合であるSiCあるいはSiO共有結合を用いている。したがって、より精密にインプリンテイングされたキラル分子孔の創製の可能性が考えられた。
本年度は、ポリフェニルアセチレンのパラ位にSiO共有結合を介して光学活性なピナニル基を持つ高分子を合成し、製膜した。この膜は光学異性体選択透過性を有していた。その後、膜状態で光学活性基を脱シリル化反応で取り除いた。除去は定量的に行うことができ、かつ膜強度を保っていた。得られた高分子膜は主鎖に光学活性を維持していることが分かった。そのため、光学活性基除去後も光学異性体選択透過性を有しており、Siインプリンティングによる光学異性体分離膜の創製が達成できた。また、この脱シリル化膜は脱シリル化前に比べて、透過速度の向上が見られた。さらにこの膜は有機溶媒に不溶なため従来使用できなかった疎水性の透過対象も分離対象として用いることが可能となった。この他に、光学活性基を持つ架橋高分子であるモノリスから光学活性基を脱シリル化反応で取り除いたモノリスが光学異性体の分離能を有することを見出し、Siインプリンティングの有効性の幅広さを示すことができた。
Synthesis and magnetoptical properties of chiral polyradicals
2002.4 - 2004.3
System name:Grant-in-Aid for Scientific Research
Grant type:Competitive
精密な分岐構造を持つデンドリマーを側鎖に有するフェニルアセチレンの重合とその高分子膜の分離機能
2001.4 - 2003.3
System name:旭硝子財団自然科学系研究助成(奨励研究助成)
Awarding organization:民間財団等
Grant type:Competitive
Mechanism and Optimization of Diffusion controlled enantioselective permeable membrane
Grant number:13555213
2001 - 2003
System name:Grants-in-Aid for Scientific Research
Research category:Grant-in-Aid for Scientific Research (B)
Awarding organization:Japan Society for the Promotion of Science
AOKI Toshiki, TACHIBANA Kozo, KANEKO Takashi, TANAKA Takaaki
Grant amount:\7200000 ( Direct Cost: \7200000 )
We have synthesized new well-defined polymers and developed optical resolution membranes which have high enantioselevtivity from these polymers. We proposed the separations occurred in diffusion process. However, the reason and detail were not clear and their permeation rates were low. In this study, several optimizations were carried out in these membrane process. For example, molecular structures, conditions in membrane preparation and permeation were examined.
First, several new optically active polymers were synthesized. Especially, we have discovered new polymerization method to obtain chiral helical polymers. In addition, new chiral helical polymers were prepared by condensation polymerization.
Secondly, we confirmed the separation of these membrane process occurred in diffusion process. In addition, chiral helicity was found to be effective for enantioselective permeation. In particular, we found that polymeric membranes whose chiral groups had been removed by reaction in membrane state showed enantioselective permeability.
Lastly, thin membranes such as composite membranes and asymmetric membranes were prepared. High permeation was realized by using these thin membranes. Pervaporation was also tried to make the rate higher.
In conclusion, we attained higher permeability and obtained many findings for practical use.
キラル触媒を用いた置換アセチレンのキラリティー制御不斉重合-機構の解明と得られる高分子の機能開拓-
Grant number:13875181
2001 - 2002
System name:科学研究費助成事業
Research category:萌芽研究
Awarding organization:日本学術振興会
青木 俊樹, 金子 隆司
Grant amount:\2500000 ( Direct Cost: \2500000 )
最近、申請者らは1つの長鎖アルキル基と2つの水酸基をもつ光学不活性アセチレンモノマー(DHPA)からの不斉誘起重合を光学不活性なロジウム錯体とキラルアミンを触媒系に用いることで成功した。しかも得られたキラルらせんは溶液中で十分安定であった。さらに重合条件を検討したところ、『光学不活性なロジウム錯体とキラルアミンのモル比のみを変えることで得られる高分子のキラリティーの正負、すなわち、らせんの巻方向を制御できる』ことを見い出した。本研究では上記の興味深い重合反応の機構と適用範囲の検討と得られた高分子の利用法の開拓を目的とする。
初年度は下記の有益な知見が得られた。
(1)この高分子よりの膜によって光学異性体の膜分離を実現できた。つまり、主鎖不斉そのものが選択透過に有効であることが分かった。
(2)この高分子のキラルらせんの安定な原因が分子内水素結合であることが共重合とIRにより判明した。モノマー単位中に2つの水酸基が必要であることも分かった。
今年度はさらに下記の実験を行った。
(1)新規な高分子不斉配位子をDHPAと配位子含有モノマーと共重合することで合成し、このらせん不斉高分子配位子を触媒に用いて、不斉反応を試みた。
(2)2つの長鎖アルキル基と2つのアミド基をもつ光学不活性アセチレンモノマー(DAPA)を新たに合成し、光学不活性なロジウム錯体とキラルアミンを触媒系に用い、不斉誘起垂合を試みた。
その結果、以下の有意義な結果が得られた。
(1)新規ならせん不斉高分子配位子が不斉反応触媒として効果があることを見出した。
(2)新規なモノマーもDHPA同様、不斉誘起重合されることが分かった。
Synthesis of ferromagnetic pai-conjugated polyradicals in combination with the optical properties
2000.4 - 2002.3
System name:Grant-in-Aid for Scientific Research
Grant type:Competitive
立体構造の制限されたデンドリマー高分子の合成とナノ構造制御による分離膜材料への応用
1999.4 - 2000.3
System name:矢崎科学技術振興財団奨励研究助成
Awarding organization:民間財団等
Grant type:Competitive
Optical Resolution Membrane from Main-chin Chiral Polymer
Grant number:11650906
1999 - 2000
System name:Grants-in-Aid for Scientific Research
Research category:Grant-in-Aid for Scientific Research (C)
Awarding organization:Japan Society for the Promotion of Science
AOKI Toshiki, KANEKO Takashi
Grant amount:\3500000 ( Direct Cost: \3500000 )
1. Synthesis of Main-chain Chiral Polymers
We found main-chain chirality was induced when various kind of acetylene having a bulky chiral substituent. The asymmetric induction was effective when the bulky substituent is close to the main-chain.
2. Syntheses of Chiral Polymers that have the chirality only in the main-chain
To clarify the effect on the enantioselective permeation, we examined synthetic methods of chiral polymers having the chirality only in the main-chain. We were able to synthesize such polymers by polymerization of a hydroxyphenylacetylene with rhodium-chiral amine catalytic system. The resulting polymers had a membrane-forming ability.
3. Optical Resolution by Membranes of Main-chain Chiral Polymers
Membranes from the polymers obtained in 1 showed high enantioselectivity in permeation. The content of the chiral substituent was also found to be important.
4. Optical Resolution by Membranes of Chiral Polymers that have the chirality only in the main-chain
Since membranes from the polymers obtained in 2 showed enantioselectivity in permeation, it was confirmed that time main-chain chirality was effective for the separation. We examined the relationship between the strength of CD signal and the selectivity.
5. Effect of the main-chain chirality on enantioselective permeation
From the results of 3 and 4, The main-chain chiralities were very effective for enantioselective permeation.
エネルギー資源を分離精製する精密高分子膜の設計に関する基礎的合成研究
1998.4 - 1999.3
System name:内田エネルギー科学振興財団試験研究費助成
Awarding organization:民間財団等
Grant type:Competitive
シリル基を含有するフェニルアセチレンデンドリマーの合成と重合および酸素選択透過膜素材としての性能
1998.4 - 1999.3
System name:山口育英奨学会学術研究助成
Awarding organization:民間財団等
Grant type:Competitive
環境保全のための精密高分子膜の設計に関する基礎的合成研究
1998.4 - 1999.3
System name:佐々木環境技術振興財団試験研究費助成
Awarding organization:民間財団等
Grant type:Competitive
Synthesis of pai-conjugated polymers containing ladder-structure bearing stable radicals and their through-bond pseudo-2D-ferromagnetic interaction
1997.4 - 1999.3
System name:Grant-in-Aid for Scientific Research
Grant type:Competitive
Polymerization of dendritic macromonomers and molecular recognition property of the polydendrons as permselective membranes
1996.4 - 1999.3
System name:Grant-in-Aid for Scientific Research
Eizo OIKAWA
Grant type:Competitive
高分子化学B
高分子化学A
機能性高分子材料化学
自然科学総論II
機能性高分子設計
技術文献リサーチA
技術文献リサーチC
技術文献リサーチB
技術文献リサーチD
工学リテラシー入門(化学材料分野)
プロジェクト研究特別概説
中間発表
外国語論文解説・討論Ⅲ
外国語論文解説・討論Ⅱ
材料生産システム博士セミナーⅡ
材料生産システム博士特定研究Ⅲ
材料生産システム博士セミナーⅢ
材料生産システム博士特定研究Ⅱ
工学リテラシー入門(化学システム工学科)
技術英語入門
素材生産科学文献詳読Ⅱ
素材生産科学特別演習
材料生産システム特定研究Ⅰ
素材生産科学文献詳読Ⅰ
素材生産科学セミナーⅠ
材料生産システム特定研究Ⅱ
研究発表演習・発表
素材生産科学セミナーⅡ
素材生産科学コース演習
材料生産システム博士特定研究Ⅰ
材料生産システム博士セミナーⅠ
外国語論文解説・討論Ⅰ
自然科学総論Ⅱ
大型機器分析技術
卒業研修
最先端技術を支える化学 I
化学技術英語
高分子化学III
高分子化学I
高分子化学実験
応用化学演習V
卒業研究
機能性高分子材料化学
機能性高分子設計
論文輪講I
論文輪講II
卒業基礎研究
応用化学実習