Updated on 2025/10/09

写真a

 
MATSUOKA Shiro
 
Organization
Academic Assembly Institute of Science and Technology CHIKYU SEIBUTSU KAGAKU KEIRETU Professor
Graduate School of Science and Technology Environmental Science and Technology Professor
Faculty of Science Department of Science Professor
Title
Professor
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Degree

  • 博士(理学) ( 1998.2   九州大学 )

Research Areas

  • Nanotechnology/Materials / Analytical chemistry

Research History (researchmap)

  • Niigata University   Faculty of Science Department of Science   Professor

    2017.4

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  • Niigata University   Graduate School of Science and Technology Environmental Science and Technology   Professor

    2012.4

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  • Niigata University   Faculty of Science Department of Environmental Science   Professor

    2012.4 - 2017.3

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  • Niigata University   Faculty of Science Department of Environmental Science   Associate Professor

    2004.4 - 2012.3

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  • 九州大学高等教育総合開発研究センター   助手

    2003.4 - 2004.3

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  • 米国ユタ大学医学部麻酔科(VAメディカルセンター)   研究員

    2001.4 - 2002.3

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  • 九州大学大学教育研究センター   助手

    1999.4 - 2003.3

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  • 九州大学大学院理学研究科   助手

    1994.4 - 1999.3

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  • 九州大学教養部化学教室   助手

    1989.4 - 1994.3

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Research History

  • Niigata University   Faculty of Science Department of Science   Professor

    2017.4

  • Niigata University   Graduate School of Science and Technology Environmental Science and Technology   Professor

    2012.4

  • Niigata University   Graduate School of Science and Technology Environmental Science and Technology   Professor

    2012.4

  • Niigata University   Faculty of Science Department of Environmental Science   Professor

    2012.4 - 2017.3

  • Niigata University   Faculty of Science Department of Environmental Science   Associate Professor

    2004.4 - 2012.3

Education

  • Kyushu University   Faculty of Science   化学科

    - 1988.3

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    Country: Japan

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Professional Memberships

  • The Japan Society for Analytical Chemistry

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  • The Chemical Society of Japan

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Papers

  • 浄水過程における PAC(ポリ塩化アルミニウム)の 凝集に及ぼすイオン状シリカの影響 Reviewed

    広城吉成, 森山 晃, 井辺弘貴, 重松 藍, 松岡史郎

    水道協会雑誌   87 ( 10 )   11 - 16   2018.10

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

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  • Interaction of borate and phenylboronate with the cross-linked dextran gel matrix Reviewed

    Yoshinobu Miyazaki, Shiro Matsuoka, Kei Asada, Yuma Kawasaki, Kazuhisa Yoshimura

    Polyhedron   151   233 - 242   2018.9

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Elsevier Ltd  

    DOI: 10.1016/j.poly.2018.05.051

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  • Coordination properties of aqueous vanadate complexes with nitrogen- and oxygen-containing multidentate ligands Reviewed

    Yoshinobu Miyazaki, Shiro Matsuoka, Takao Fujimori, Yoshitaka Kai, Kazuhisa Yoshimura

    POLYHEDRON   134   79 - 87   2017.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.poly.2017.05.056

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  • Speciation of dissolved chromium and the mechanisms controlling its concentration in natural water Reviewed

    Sulistyo Saputro, Kazuhisa Yoshimura, Shiro Matsuoka, Ko Takehara, Narsito, Jun Aizawa, Yoshika Tennichi

    CHEMICAL GEOLOGY   364   33 - 41   2014.1

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.chemgeo.2013.11.024

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  • Mineralogical and geomicrobial examination of soil contamination by radioactive Cs due to 2011 Fukushima Daiichi Nuclear Power Plant accident Reviewed

    Junji Akai, Nao Nomura, Shin Matsushita, Hisaaki Kudo, Haruo Fukuhara, Shiro Matsuoka, Jinko Matsumoto

    PHYSICS AND CHEMISTRY OF THE EARTH   58-60   57 - 67   2013

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.pce.2013.04.010

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  • Solid-phase spectrophotometry for on-site analysis of trace elements in natural water Reviewed

    Sarenqiqige, Sulistyo Saputro, Satsuki Kai, Makoto Satoda, Shiro Matsuoka, Kazuhisa Yoshimura

    Analytical Sciences   29 ( 6 )   677 - 680   2013

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/analsci.29.677

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  • Development and Validation of a Sensitive and Fast Solid-phase Spectrophotometric Procedure for Phenol Determination in Pharmaceuticals Reviewed

    Jadranka Vukovic, Shiro Matsuoka, Kazuhisa Yoshimura, Renata Jurisic Grubesic, Dario Kremer, Natasa Santic

    ANALYTICAL SCIENCES   28 ( 4 )   397 - 402   2012.4

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/analsci.28.397

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  • Selective Determination of Trace Iron in Different Oxidation States in Natural Water by Flow Injection-Solid Phase Spectrometry Reviewed

    Shiro Matsuoka, Yoshika Tennichi, Takashi Ito, Kosuke Hori, Kazuhisa Yoshimura

    ANALYTICAL SCIENCES   28 ( 3 )   225 - 230   2012.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/analsci.28.225

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  • Simple spectrophotometer for solid phase spectrometry applicable to on-site analysis of phosphate in natural water Reviewed

    Sarenqiqige, M. Koga, M. Satoda, S. Matsuoka, K. Yoshimura

    Kyushu University Global-COE “Science for Future Molecular Systems” Journal   ( 5 )   106 - 109   2012.3

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  • Acidic Polyol-Boric Acid Complex Chemistry and Its Application to Boron Analysis Reviewed

    Chaoying Shao, Yoshinobu Miyazaki, Shiro Matsuoka, Ko Takehara, Takao Fujimori, Kazuhisa Yoshimura

    BUNSEKI KAGAKU   61 ( 3 )   177 - 184   2012.3

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/bunsekikagaku.61.177

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  • Oxidation of Chromium(III) by Free Chlorine in Tap Water during the Chlorination Process Studied by an Improved Solid-Phase Spectrometry Reviewed

    Sulistyo Saputro, Kazuhisa Yoshimura, Ko Takehara, Shiro Matsuoka, Narsito

    ANALYTICAL SCIENCES   27 ( 6 )   649 - 652   2011.6

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/analsci.27.649

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  • Differential Pulse Voltammetric Determination of Free Chlorine for Water Disinfection Process Reviewed

    Sulistyo Saputro, Ko Takehara, Kazuhisa Yoshimura, Shiro Matsuoka, Narsito

    ELECTROANALYSIS   22 ( 23 )   2765 - 2768   2010.12

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1002/elan.201000322

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  • Improved Solid-phase Spectrometry for the Microdetermination of Total and Dissolved Phosphate Reviewed

    Masaaki Koga, Shiro Matsuoka, Kazuhisa Yoshimura

    ANALYTICAL SCIENCES   26 ( 9 )   963 - 968   2010.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/analsci.26.963

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  • Recent trends in solid phase spectrometry: 2003-2009. A Review Invited Reviewed

    Shiro Matsuoka, Kazuhisa Yoshimura

    ANALYTICA CHIMICA ACTA   664 ( 1 )   1 - 18   2010.4

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.aca.2010.01.041

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  • Improved Solid-phase Spectrophotometry for the Microdetermination of Chromium(VI) in Natural Water Reviewed

    Sulistyo Saputro, Kazuhisa Yoshimura, Shiro Matsuoka, Ko Takehara, Narsito

    ANALYTICAL SCIENCES   25 ( 12 )   1445 - 1450   2009.12

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/analsci.25.1445

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  • Interaction of boric acid with salicyl derivatives as an anchor group of boron-selective adsorbents Reviewed

    Yoshinobu Miyazaki, Hidenobu Matsuo, Takao Fujimori, Hiroyuki Takemura, Shiro Matsuoka, Tadashi Okobira, Kazuya Uezu, Kazuhisa Yoshimura

    POLYHEDRON   27 ( 13 )   2785 - 2790   2008.9

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.poly.2008.06.007

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  • Electrochemical control of the bioluminescence by bacterial luciferase using platinum-mesh electrode Reviewed

    Ko Takehara, Shinya Nakashima, Shinya Yamasaki, Shiro Matsuoka

    CHEMISTRY LETTERS   36 ( 11 )   1358 - 1359   2007.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1246/cl.2007.1358

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  • Kinetic study on Cr(VI) reduction in natural water by means of flow injection-solid phase spectrometry (FI-SPS) Reviewed

    T. Tsuruhara, K. Takehara, K. Yoshimura, S. Matsuoka, Sulistyo Saputro, J. Aizawa

    J. Ion Exchange   18 ( 4 )   524 - 528   2007.9

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    DOI: 10.5182/jaie.18.524

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  • Development and prevalidation of a method for phenol determination by solid-phase spectrophotometry Reviewed

    Jadranka Vukovic, Shiro Matsuoka, Kazuhisa Yoshimura, Vladimir Grdinic, Renata Jurisic Grubesic

    MICROCHIMICA ACTA   159 ( 3-4 )   277 - 285   2007.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1007/s00604-007-0748-5

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  • Simultaneous determination of traces of heavy metals by solid-phase spectrophotometry Reviewed

    J. Vukovic, S. Matsuoka, K. Yoshimura, V. Grdinic, R. Jurisic Grubesic, O. Zupanic

    TALANTA   71 ( 5 )   2085 - 2091   2007.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.talanta.2006.09.036

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  • Classification of the binding modes in bovine serum albumin using terminally substituted alkane analogues Reviewed

    Ko Takehara, Yuki Morinaga, Shinya Nakashima, Shiro Matsuoka, Hiroshi Kamaya, Issaku Ueda

    ANALYTICAL SCIENCES   22 ( 12 )   1571 - 1575   2006.12

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/analsci.22.1571

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  • On-line electrochemical oxidation of Cr(III) for the determination of total Cr by flow injection-solid phase spectrophotometry Reviewed

    Shiro Matsuoka, Yu Nakatsu, Ko Takehara, Sulistyo Saputro, Kazuhisa Yoshimura

    ANALYTICAL SCIENCES   22 ( 12 )   1519 - 1524   2006.12

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/analsci.22.1519

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  • Determination of trace amounts of cobalt(II) by flow injection-solid phase spectrometry (FI-SPS) with 5-Br-PADAB Reviewed

    S Matsuoka, N Shiota, K Yoshimura

    ANALYTICAL SCIENCES   22 ( 1 )   177 - 181   2006.1

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/analsci.22.177

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  • Solid-phase spectrometry and its application to flow injection analysis Reviewed

    S Matsuoka, K Yoshimura

    BUNSEKI KAGAKU   54 ( 12 )   1137 - 1147   2005.12

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    Language:Japanese   Publishing type:Research paper (scientific journal)  

    DOI: 10.2116/bunsekikagaku.54.1137

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  • Complexation of vanadium(V) oxoanion with ethanolamine derivatives in solution and in a cross-linked polymer Reviewed

    Y Miyazaki, S Matsuoka, Y Miura, H Sakashita, K Yoshimura

    POLYHEDRON   24 ( 9 )   985 - 994   2005.6

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.poly.2004.12.021

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  • B-11 NMR study on the interaction of boric acid with Azomethine H Reviewed

    H Matsuo, Y Miyazaki, H Takemura, S Matsuoka, H Sakashita, K Yoshimura

    POLYHEDRON   23 ( 6 )   955 - 961   2004.3

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/j.poly.2003.12.016

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  • Speciation of Boron Species Adsorbed onto Polysaccharide Gel by 11B NMR Spectroscopy Reviewed

    Y. Miyazaki, C. Shao, S. Matsuoka, K. Yoshimura

    J. Ion Exchange   14 (Supplement)   33 - 36   2003.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.5182/jaie.14.Supplement_33

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  • Fundamental studies on ion-exchanger phase absorptiometry Reviewed

    S. Matsuoka, Y. Tennichi, K. Yoshimura

    J. Ion Exchange   14 (Supplement)   313 - 316   2003.7

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.5182/jaie.14.Supplement_313

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  • Anion exchanger as a reaction/separation medium - absorptiometric determination of trace amounts of boron in waters by on-line complexation with chromotropic acid presorbed on the anion-exchange column Reviewed

    CY Shao, S Matsuoka, Y Miyazaki, K Yoshimura

    ANALYST   127 ( 12 )   1614 - 1620   2002

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/b207869d

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  • Studies on the complexation of boric acid with polyhydroxyl compounds Reviewed

    C. Shao, S. Matsuoka, Y. Miyazaki, K. Yoshimura

    Anal. Sci.   17   i1475 - i1478   2001.8

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  • Simultaneous determination of trace metals by solid phase absorptiometry: application to flow analysis of some rare earths Reviewed

    Y Tennichi, S Matsuoka, K Yoshimura

    FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY   368 ( 5 )   443 - 448   2000.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1007/s002160000515

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  • Complexation of borate with cross-linked polysaccharide anion exchanger: 11B NMR and adsorption properties studies Reviewed

    Chaoying Shao, Yoshinobu Miyazaki, Shiro Matsuoka, Kazuhisa Yoshimura, Hirofumi Sakashita

    Macromolecules   33 ( 1 )   19 - 25   2000.1

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:ACS  

    DOI: 10.1021/ma991257o

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  • Equilibrium and kinetic studies on the complexation of boric acid with chromotropic acid Reviewed

    CY Shao, S Matsuoka, Y Miyazaki, K Yoshimura, TM Suzuki, DAP Tanaka

    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS   18 ( 18 )   3136 - 3142   2000

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/b004399k

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  • Solid-phase spectrometry and its application to the flow analysis of trace elements Reviewed

    S Matsuoka

    BUNSEKI KAGAKU   48 ( 11 )   1027 - 1028   1999.11

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  • Flow analysis of micro amounts of chromium(III) and (VI) in natural water by solid phase spectrophotometry using diphenylcarbazide Reviewed

    S Matsuoka, Y Tennichi, K Takehara, K Yoshimura

    ANALYST   124 ( 5 )   787 - 791   1999.5

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1039/a900493i

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  • Application of solid-phase absorptiometry to microscopic spectroscopy Reviewed

    S Matsuoka, K Yoshimura, A Tateda, Shinno, I

    BUNSEKI KAGAKU   47 ( 6 )   335 - 340   1998.6

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    DOI: 10.2116/bunsekikagaku.47.335

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  • Complexation of boric acid with the N-methyl-D-glucamine group in solution and in crosslinked polymer Reviewed

    Kazuhisa Yoshimura, Yoshinobu Miyazaki, Fumio Ota, Shiro Matsuoka, Hirofumi Sakashita

    Journal of the Chemical Society - Faraday Transactions   94 ( 5 )   683 - 689   1998.3

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    Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    DOI: 10.1039/a707790d

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  • 山口県秋芳洞洞口のトゥファ形成におけるシアノバクテリアの役割 Reviewed

    吉村 和久, 井上 真理, 染谷 孝, 松浦 健太郎, 橋口 美保子, 原 友子, 大坪 久記, 松岡 史郎

    洞窟学雑誌   20   27 - 37   1996.3

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  • Application of ion-exchanger phase visible light absorption to flow analysis. Determination of vanadium in natural water and rock Reviewed

    S Matsuoka, K Yoshimura, A Tateda

    ANALYTICA CHIMICA ACTA   317 ( 1-3 )   207 - 213   1995.12

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/0003-2670(95)00412-2

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  • Application of solid-phase spectromrtry to flow analysis Reviewed

    Shiro Matsuoka, Kazuhisa Yoshimura

    12 ( 1 )   8 - 22   1995.1

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  • Recent Progress in Solid-phase Spectrometry: Its Application to Flow Analysis Invited Reviewed

    K. Yoahimura, S. Matsuoka

    Laboratory Robotics and Automation   5   231 - 244   1993.2

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  • FLOW-ANALYSIS FOR TRACE AMOUNTS OF COPPER BY ION-EXCHANGER PHASE ABSORPTIOMETRY WITH 4,7-DIPHENYL-2,9-DIMETHYL-1,10-PHENANTHROLINE DISULFONATE AND ITS APPLICATION TO THE STUDY OF KARST GROUNDWATER STORM RUNOFF Reviewed

    K YOSHIMURA, S MATSUOKA, Y INOKURA, U HASE

    ANALYTICA CHIMICA ACTA   268 ( 2 )   225 - 233   1992.10

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/0003-2670(92)85216-S

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  • Determination of Aluminium in High Purity Water by Ion-exchanger Phase Spectrofluorometry Combined with Flow Analysis

    S. Matsuoka, K. Yoshimura, A. Tateda

    Mem. Fac. Sci., Ser. C, Kyushu Univ.   18 ( 2 )   169 - 178   1992.9

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  • Application of ion-exchanger phase spectrofluorimetry to the determination of micro-amounts of some rare earth elements by flow analysis Reviewed

    Kazuhisa Yoshimura, Shiro Matsuoka, Toyohisa Tabuchi, Hirohiko Waki

    The Analyst   117 ( 2 )   189 - 193   1992

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    DOI: 10.1039/an9921700189

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  • FLOW-ANALYSIS METHOD FOR TRACE-ELEMENTS BY ION-EXCHANGER PHASE ABSORPTIOMETRY Reviewed

    K YOSHIMURA, S MATSUOKA

    ION EXCHANGE ADVANCES   183 - 190   1992

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  • Flow Injection Analysis of Phosphate Ion with the Liquid Chloranilate Selective Membrane Electrode as a Detector

    S. Matsuoka, A. Tateda

    Mem. Fac. Sci., Kyushu Univ., Ser.C   18 ( 1 )   49 - 54   1991.9

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  • Application of Ion-exchanger Phase Absorptiometry to Flow Analysis-Determination of Vanadium(V) in Natural Water

    S. Matsuoka, J. Yoshimura, H. Waki

    Mem. Fac. Sci., Ser. C, Kyushu Univ.   18 ( 1 )   55 - 62   1991.9

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  • SPECTROPHOTOMETRIC APPLICATION OF ION-EXCHANGER FLOW-ANALYSIS OF CHROMIUM(VI) IN NATURAL-WATERS BY ION-EXCHANGER PHASE ABSORPTIOMETRY Reviewed

    K YOSHIMURA, S MATSUOKA

    NEW DEVELOPMENTS IN ION EXCHANGE   377 - 382   1991

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  • The Property of the Liquid Chloranilate Selective Membrane Electrode Based on Cadmium-(1,10-penanthroline) Ion and the Indirect Determination of Phosphate Ion

    A. Tateda, S. Matsuoka

    Mem. Fac. Sci., Kyushu Univ., Ser. C   17 ( 2 )   207 - 212   1990.9

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  • Determination of molybdenum(VI) in natural water and rock by ion-exchange absorptiometry combined with flow analysis Reviewed

    Kazuhisa Yoshimura, Shiro Matsuoka, Hirohiko Waki

    Analytica Chimica Acta   225 ( C )   313 - 321   1989

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: 10.1016/S0003-2670(00)84620-6

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Books

  • 製品中に含まれる (超)微量成分・不純物の同定・定量ノウハウ

    松岡史郎, Sarenqiqige, 吉村和久( Role: Joint author ,  第1章第7節 固相分光法による超微量成分分析 -水中の溶存微量成分の簡易高感度分析法、溶存クロムなどの分析事例)

    株式会社 技術情報協会  2014.2 

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    Language:Japanese Book type:Scholarly book

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  • Chlorine: Properties, Applications and Health Effects, Chapter 8: "Analytical methods of chlorine and the substances produced by the chlorine treatments"

    S. Saputro, K. Yoshimura, K. Takehara, S. Matsuoka, Narsito (Roger Mangione, Dana Carlile( Role: Joint author)

    Nova Science Publishers Inc.  2011.10 

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    Language:English Book type:Scholarly book

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  • 分析化学便覧(改訂第6版)

    日本分析化学会編( Role: Joint author ,  吸光光度法(8.4.3 項),イオン交換(8.7.1))

    丸善出版  2011.9  ( ISBN:4621084097

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    Language:Japanese Book type:Dictionary, encyclopedia

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  • Handbook of Inorganic Chemistry Research, Chapter 8: "Complexation of Boric Acid with Polyhydroxy Compounds and its Relevance to Practical Aspects "

    K. Yoshimura, Y. Miyazaki, S. Matsuoka, K. Takehara, T. Fujimori, Desiree A. Morrison( Role: Joint author)

    Nova Science Pub Inc,  2010.9 

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  • 理系のための基礎化学

    増田芳男, 澤田 清, 編著, 増田芳男, 徳江郁雄, 島倉紀之, 工藤久昭, 佐藤敬一, 丸山健二, 湯川靖彦, 松岡史郎, 澤田 清, 後藤真一( Role: Joint author ,  6・1節,6.2節)

    化学同人  2006.4  ( ISBN:4759810552

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MISC

  • Chemistry of the boric acid-Azomethine H system and its application to voltammetric determination of boric acid in water

    Kô Takehara, Yoshinobu Miyazaki, Takao Fujimori, Shiro Matsuoka, Kazuhisa Yoshimura

    REPORT OF THE CENTER OF ADVANCED INSTRUMENTAL ANALYSIS KYUSHU UNIVERSITY   ( 30 )   10 - 20   2012

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (other)   Publisher:THE CENTER OF ADVANCED INSTRUMENTAL ANALYSIS KYUSHU UNIVERSITY  

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  • Complexation of boric acid with polyhydroxy compounds and its relevance to practical aspects

    K. Yoshimura, Y. Miyazaki, S. Matsuoka, K. Takehara, T. Fujimori

    Handbook of Inorganic Chemistry Research   174 - 209   2011.12

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  • Solid Phase Spectrometry and Its Application to Speciation Analysis of Trace Components in Water

    Shiro Matsuoka, Sarenqiqige, Kazuhisa Yoshimura

    Bunseki   444 ( 12 )   713 - 719   2011.12

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (other)   Publisher:The Japan Society for Analytical Chemistry  

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  • 化学発光を用いたCrの酸化状態別分析法

    松岡史郎

    ぶんせき   369 ( 12 )   671 - 671   2007.12

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  • Chemical Speciation of Trace Elements in Natural Water: Specific determination of Trace Inorganic Ions Present in Different Oxidation States

    S. Matsuoka, K. Yoshimura

    Bunseki   2 ( 386 )   87 - 93   2007.2

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  • 11B NMR study on the complexation of borate with boron-selective polymers

    Kazuhisa Yoshimura, Chaoying Shao, Shiro Matsuoka, Yoshinobu Miyazaki, Hirofumi Sakashita

    Report of the Center of Advanced Instrumental Analysis Kyushu University   20   2 - 11   2002.12

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  • ミニファイル 分離 イオン交換

    松岡史郎, 吉村和久

    ぶんせき   317 ( 5 )   247 - 248   2001.5

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  • イオン交換分離:無機成分の分離・濃縮を中心に

    吉村 和久, 松岡 史郎, 天日 美薫

    ぶんせき   282 ( 6 )   430 - 436   1998.6

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  • Fundamentals of Separation: Ion Exchange.

    Shiro Matsuoka, Kazuhisa Yoshimura

    BUNSEKI   275 ( 11 )   28 - 36   1997.11

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  • イオン交換体相吸光光度流れ分析法による微量成分定量法の開発

    松岡史郎, 吉村和久

    九州大学中央分析センターセンターニュース   12 ( 3 )   6 - 9   1995.1

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (other)   Publisher:九州大学中央分析センター  

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  • ミニファイル ベリリウム、カルシウム

    松岡史郎, 吉村和久

    ぶんせき   254 ( 12 )   964 - 965   1993.12

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Research Projects

  • ブルーカーボン生態系の拡大を目的とした藻場に対する鉄の供給メカニズムの解明

    Grant number:23K04817

    2023.4 - 2026.3

    System name:科学研究費助成事業

    Research category:基盤研究(C)

    Awarding organization:日本学術振興会

    松岡 史郎, 吉村 和久, 宮崎 義信

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    Grant amount:\4420000 ( Direct Cost: \3400000 、 Indirect Cost:\1020000 )

    本研究では、水試料中の溶存Feの酸化状態に関する正確な情報を取得する必要がある。この目的のためにFe(II)-フェナントロリン(phen)錯生成系を適用した固相分光法をこれまで用いてきたが、同法の正確さを評価するために、試料溶液中の溶存Fe分析を行う過程で生じる可能性があるFeの酸化状態の変化について検討した。
    実試料中においてFeは有機錯体として存在している可能性が高い。したがってモデル配位子としてエチレンジアミン四酢酸(EDTA)を共存させた場合のFe-phen錯生成系で、溶存Feの酸化状態について検討した。Fe(II)-phen錯生成における至適pHであるpH 5において、EDTA濃度が1.0×10-5 mol dm-3以下ではFe(II)-phen錯生成が完全に進行し、溶存酸素の存在下でもFe(III)に酸化されることなく錯体は安定に存在することが確認できた。しかしながらpHを海水とほぼ同じ8としたところ、わずか3分程度で95 %以上のFe(II)が溶存酸素によってFe(III)に酸化された。またFeの酸化が生じたこの溶液にphenを添加すると、溶存酸素によって酸化されたFe(III)からFe(II)への還元が徐々に起こり、1時間後で10 %程度、4時間後では25 %程度のFe(II)が検出された。本研究では、試料採水時にCO2 を溶解させてpH を6 以下に下げた後に酸処理した試料を定量に供し、さらに定量操作は0.5時間程度で終了するが、上述の結果よりこの試料採取法と定量法で、Feの酸化状態を変化させることなく正確さの高い定量が行えていることが確認された。

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  • Thermodynamics, structure and dynamics of ultra-concentrated electrolyte solutions and solvate ionic liqudis

    Grant number:18H01994

    2018.4 - 2021.3

    System name:Grants-in-Aid for Scientific Research

    Research category:Grant-in-Aid for Scientific Research (B)

    Awarding organization:Japan Society for the Promotion of Science

    Umebayashi Yasuhiro

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    Grant amount:\17420000 ( Direct Cost: \13400000 、 Indirect Cost:\4020000 )

    Super-concentrated electrolyte solutions and solvate ionic liquids exhibit ionic conduction and electrode reactions not found in conventional dilute electrolyte solutions. They are hardly explained in the framework of conventional electrolyte solution theory based on continuous dielectric models such as Walden's law and Stokes' law. In addition to macroscopic thermodynamics and transport theory, we approached from structure and dynamics at the molecular level in order to reveal the ion transport and electrode reaction in super-concentrated electrolyte solutions and solvate ionic liquids.

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  • 河川水中に存在するマンガンの溶存状態

    2015.4 - 2017.3

    System name:科学研究費助成事業

    Research category:基盤研究(C)

    Awarding organization:日本学術振興会

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    Grant type:Competitive

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  • Important role of the storm runoff Fe(II) flux in the supply of the dissolved iron in coastal seawater

    Grant number:24651012

    2012.4 - 2015.3

    System name:Grants-in-Aid for Scientific Research

    Research category:Grant-in-Aid for Challenging Exploratory Research

    Awarding organization:Japan Society for the Promotion of Science

    YOSHIMURA Kazuhisa, MATSUOKA Shiro, SATODA Makoto, AIMOTO Michihiro, KATO Toshiaki, TENNICHI Yoshika, SAREN Qiqige, KAI Satsuki, BANNO Yu, MATSUMOTO Megumi, UEHARA Wataru

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    Grant amount:\3900000 ( Direct Cost: \3000000 、 Indirect Cost:\900000 )

    One of the causes of Isoyake, sea desert, around the Japan coast is attributed to the decline in the supply of the dissolved iron from river. Fe(III) complexes of humic substances in the river water should be coagulated when the river water is mixed with seawater. Our hypothesis is that Fe(II) is mainly supplied to the sea during storm runoff and forms dissolved Fe(III)-organic complexes in the presence of O2. To prove this hypothesis, on-site analysis method was established using solid-phase spectrophotometry to measure the low concentration of Fe(II). The sample collection method was also established by dissolving CO2 in sample solution to decrease pH and the dissolved O2 concentration and then by keeping pH at 2 within 1 hr after the sample collection. The bottom water of high Fe(II) concentration in the river was present in the local reduction environment under anoxic conditions. It was found that the Fe(II) flux at flood runoff was one hundred times more than that at base flow.

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  • 藻場の磯焼けと沿岸海水中に存在する鉄化学種濃度との関連

    2012.4 - 2014.3

    System name:科学研究費助成事業

    Research category:基盤研究(C)

    Awarding organization:日本学術振興会

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    Grant type:Competitive

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  • 磯焼けの原因究明を目的とした沿岸海水中の溶存超微量鉄のスペシエーション

    2006.4 - 2008.3

    System name:科学研究費助成事業

    Research category:基盤研究(C)

    Awarding organization:日本学術振興会

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    Grant type:Competitive

    Grant amount:\1600000 ( Direct Cost: \1600000 )

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  • 陸域炭酸塩堆積物から環境変遷を読む

    Grant number:15651006

    2003 - 2005

    System name:科学研究費助成事業

    Research category:萌芽研究

    Awarding organization:日本学術振興会

    吉村 和久, 松岡 史郎, 松田 博喜, 井倉 洋二

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    Grant amount:\3700000 ( Direct Cost: \3700000 )

    鍾乳石とトゥファから環境情報を取り出すための手法を確立することを目的として、次の項目について検討を行い、それぞれの項目に関して以下の成果を得ることができた。
    1.秋吉台の鍾乳石試料を用いて秋吉台が草原化した時期を明らかにする。
    (1)現在も成長を続ける石筍の絶対年代見積りには、今回確立した顕微蛍光法による年縞の計測が有効であった。
    (2)鍾乳石およびトゥファ中で蛍光を発する成分のキャラクタリゼーションを蛍光スペクトル分析により行い、これらの蛍光にはいずれもフルボ酸の寄与が大きいことを明らかにした。
    (3)草原地域の洞窟の石筍の炭素同位体比の変動を追跡することで、約400年前から継続的な"山焼き"が行われるようになったことがわかった。
    2.平尾台のトゥファを用いて、過去130年間の北九州工業地帯の大気汚染変遷を明らかにする。
    (1)顕微分光法を用いて得られた絶対年代のクロスチェックのために、鍵層を見出すことを試みた。長崎原爆と1960年台初頭の大気圏内核実験に起因する^<137>Csの高濃度部分をトゥファ中で見出すことができた。
    (2)鍾乳石およびトゥファ中の硫酸イオンがイオン交換反応で共沈することを国内および台湾の試料を用いて明らかにした。
    (3)明治以降の北九州工業地帯の大気汚染変遷をトゥファ中の硫酸イオン濃度から読み取ることができた。
    3.大分県稲積水中鍾乳洞の水没鍾乳石から阿蘇火山の大規模活動と鍾乳洞発達史との関連を明らかにする。
    (1)カナダMcMaster大でU-Th法による絶対年代測定を行った大分県稲積水中鍾乳洞の水没鍾乳石について、再検討を行った。水没の原因はAso-4火砕流による谷の埋没にあると考えられていたが、見積もられた絶対年代は17万年前となり、Aso-1とAso-2の間に成長したことが明らかとなった。鍾乳石中の厚さ1mm程度の粘土層の枚数は鍾乳石の水没の回数と一致するものと考えられる。

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  • 受光部に光ファイバ−を装着した分光器を用いた低光量領域における固相の透過光測定

    1998.4 - 2000.3

    System name:科学研究費助成事業

    Research category:奨励研究(A)

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    Grant type:Competitive

    Grant amount:\2100000 ( Direct Cost: \2100000 )

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  • 固相分光法の顕微分光法への応用

    1996.4 - 1997.3

    System name:科学研究費助成事業

    Research category:奨励研究(A)

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    Grant type:Competitive

    Grant amount:\900000 ( Direct Cost: \900000 )

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  • Characterization, Synthesis, and Application of Borate-selective Polymers

    Grant number:06640790

    1994 - 1996

    System name:Grants-in-Aid for Scientific Research

    Research category:Grant-in-Aid for Scientific Research (C)

    Awarding organization:Japan Society for the Promotion of Science

    YOSHIMURA Kazuhisa, MIYAZAKI Yoshinobu, TAKEMURA Hiroyuki, MATSUOKA Shiro

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    Grant amount:\2100000 ( Direct Cost: \2100000 )

    Studies were done using commercially available linear dextran and crosslinked polyols such as Sephadex gel, QAE-Sephadex anion-exchange dextran gel, and Amberlite IRA-743, a boron-selective resin which has a functional group of N-methylglucamine. Together with the distribution measurements of borate on the crosslinked polymers, ^<11>B NMR spectroscopy was employed to elucidate the nature of the complex formation of borate with the polyols. The results obtained were as follows : (1) for the adsorption of borate on a crosslinked dextran. DELTAH values were comparable to those for the complex formation ob borate with monosaccharides and the borate concentration dependence of boron adsorption is a characteristic property of the crosslinked dextran. (2) Well-resolved ^<11>B NMR spectra for the solid gel as well as for a dextran solution were observed. In the dextran system, borate complexes both with alpha, beta-diols and alpha, gamma-diols of glucopyranoside residues were present. This crosslinking of dextran caused the effective concentration of alpha, beta-diol moieties in the crosslinked polymer ligand to become higher than the practical concentrarion, so that the 1 : 2 complexation became more fovorable accoding to the increase in the degree of crosslinking. (3) The borate concentration dependence of boron adsorption on crosslinked dextran gel may be caused by the exclusion of borate anions from the gel phase due to electrostatic repulsion between borate and the fixed anion sites of borate complexes in the gel phase. The stability constant of each complex is similar to that for the Sephadex system : the presence of the fixed cation group in the QAE-Sephadex gel phase did not promote the boron adsorption. (4) The pH of the N-methylglucamine resin phase remains constant in the range of 10 to 11 when the equilibrated bulk solution is pH 6-11. The strong adsorbability of borate on the resin in a wide pH range is due to this phenomenon. From the ^<11>B MAS-NMR measurements, the active species in the resin were proved to be borate complexes of alpha, beta-diols in the functional groups.
    On the basis of the results obtained, a novel boron-selective polymer was synthesized by introducing tris (hydroxymethyl) groups into chloromethylated polystirene. The properties of this resin are now being investigated.

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  • クロラニル酸の難溶性塩を用いたリン酸塩類の分別定量法の開発

    1992.4 - 1993.3

    System name:科学研究費助成事業

    Research category:奨励研究(A)

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    Grant type:Competitive

    Grant amount:\9000000 ( Direct Cost: \9000000 )

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  • Study on the Chemical Evolution of Groundwater in the Hydrological Cycle of a Limestone Area

    Grant number:03640497

    1991 - 1992

    System name:Grants-in-Aid for Scientific Research

    Research category:Grant-in-Aid for General Scientific Research (C)

    Awarding organization:Japan Society for the Promotion of Science

    YOSHIMURA Kazuhisa, MATSUOKA Shiro, INOKURA Youji

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    Grant amount:\400000 ( Direct Cost: \400000 )

    On the basis of the topographic divide and the existence of two groundwater systems, the catchment basins in the Akiyoshi-dai Plateau limestone area(Yamaguchi Prefecture, Western Japan)are divided into six areas:Hirotani(where Akiyoshi-do Cave is located),Kanoide,Kuroiwa,Ono,Narutaki and Sowa. In this limestone area,groundwater flows out from 4 springs and 5 caves at the foot of the plateau. The origin of the dissolved components in the groundwater was estimated by using the self-consistent least squares method proposed by Tsurumi(1982). The contents of the dissolved components for all spring waters could be explained by the mixing of only three sources: one rich in limestone components,another in non-carbonate rock components,and the other in calcium sulfate probably originating from fallout and sulfur-oxidation in the soil in the plateau.
    With an area of 18.5km^2, the catchment basin of Akiyoshi-do Cave occupies about half of the Akiyoshi-dai Plateau, where the annual mean precipitation is 1,974mm,and the average run-off from Akiyoshi-do Cave is estimated to be 955 mm. The calcium concentration of the baseflow showed seasonal fluctuations,and followed changes in the soil's CO_2 partial pressure. Measured soil CO_2 in the humus soil varied from 0.15% at a soil temperature of 7.2゚C to1.7% at 19.0 ゚C, whereas in the meadows which cover most of the area,it ranged from 0.08% at 3.8゚C to 1.2% at 20.8゚C. The calcium concentration in groundwater issuing from the Akiyoshi-dai Plateau is controlled by the water-limestone dissolution equilibrium,under open system conditions depending on the meadow's soil CO_2 contents. A yearly average of 2,100tons of limestone was dissolved in groundwater issuing from Akiyoshi-do Cave,about 5% of which,of 110tons, was dissolved by acidic deposition.
    Ion-exchanger phase absorptiometry was applied to the flow analysis of trace amounts of copper. This method permitted a highly sensitive,selective determination of copper in karst groundwater samples without any preconcentration. By measuring the copper concentration response in the water after a storm,the infiltration rate of rain water from the soil zone to the underground river of this karst groundwater system could be evaluated to be about 10-20m day^<-1>. On the other hand,the tritium concentration response suggested that the faily long residence groundwater(about 40years)entered the groundwater system after a big storm.

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Teaching Experience

  • 環境政策論b

    2024
    Institution name:新潟大学

  • 課題研究(自然環境)B

    2024
    Institution name:新潟大学

  • 自然環境科学研究演習

    2023
    Institution name:新潟大学

  • 薬品安全管理技術

    2023
    Institution name:新潟大学

  • 化学とSDGs

    2023
    Institution name:新潟大学

  • 安全工学基礎

    2023
    Institution name:新潟大学

  • 統合化学入門

    2023
    Institution name:新潟大学

  • 理学基礎演習

    2022
    Institution name:新潟大学

  • 卒業論文I

    2022
    Institution name:新潟大学

  • 卒業論文II

    2022
    Institution name:新潟大学

  • 自然環境科学特論B

    2022
    Institution name:新潟大学

  • 分析化学I

    2021
    Institution name:新潟大学

  • 自然科学総論V

    2021
    Institution name:新潟大学

  • 課題研究B

    2021
    Institution name:新潟大学

  • 課題研究C

    2021
    Institution name:新潟大学

  • 専門力アクティブ・ラーニング

    2021
    Institution name:新潟大学

  • 卒業論文

    2020
    Institution name:新潟大学

  • 課題研究(自然環境)A

    2020
    Institution name:新潟大学

  • 課題研究

    2020
    -
    2021
    Institution name:新潟大学

  • 卒業論文Ⅰ

    2020
    Institution name:新潟大学

  • 卒業論文Ⅱ

    2020
    Institution name:新潟大学

  • 安全教育

    2020
    Institution name:新潟大学

  • 環境経済システム論Ⅰ

    2019
    -
    2020
    Institution name:新潟大学

  • 自然環境科学総論

    2018
    Institution name:新潟大学

  • 自然環境科学実験C2

    2017
    Institution name:新潟大学

  • 自然環境科学実験C1

    2017
    Institution name:新潟大学

  • 課題研究B

    2017
    -
    2021
    Institution name:新潟大学

  • 課題研究C

    2017
    -
    2021
    Institution name:新潟大学

  • 専門力アクティブ・ラーニング

    2017
    -
    2021
    Institution name:新潟大学

  • 課題研究A

    2017
    -
    2021
    Institution name:新潟大学

  • 理学スタディ・スキルズ

    2017
    -
    2020
    Institution name:新潟大学

  • 日本事情自然系A

    2016
    Institution name:新潟大学

  • 環境科学スタディスキルズ

    2016
    Institution name:新潟大学

  • 課題研究(自然環境)

    2015
    -
    2016
    Institution name:新潟大学

  • 化学入門

    2014
    -
    2020
    Institution name:新潟大学

  • 自然科学実験法

    2014
    -
    2017
    Institution name:新潟大学

  • 研究発表演習Ⅰ(学外発表)

    2014
    Institution name:新潟大学

  • 環境科学特定演習Ⅰ

    2014
    Institution name:新潟大学

  • 自然科学総論Ⅴ

    2014
    Institution name:新潟大学

  • 化学基礎B

    2013
    Institution name:新潟大学

  • グリーンケミストリー入門

    2013
    -
    2022
    Institution name:新潟大学

  • 研究発表演習Ⅰ(中間発表)

    2012
    -
    2015
    Institution name:新潟大学

  • 環境科学セミナーⅠ

    2012
    -
    2015
    Institution name:新潟大学

  • 環境科学総合演習Ⅰ

    2012
    -
    2015
    Institution name:新潟大学

  • 環境科学特定研究Ⅰ

    2012
    -
    2014
    Institution name:新潟大学

  • チームインターンシップ Ⅰ

    2012
    -
    2013
    Institution name:新潟大学

  • チームインターンシップ Ⅱ

    2012
    -
    2013
    Institution name:新潟大学

  • 環境科学演習Ⅰ

    2012
    Institution name:新潟大学

  • 環境科学特定研究

    2012
    Institution name:新潟大学

  • 地球環境化学

    2011
    Institution name:新潟大学

  • グリーンケミストリー概説

    2010
    -
    2013
    Institution name:新潟大学

  • 環境化学特論Ⅱ

    2008
    Institution name:新潟大学

  • 基礎化学実験

    2008
    -
    2016
    Institution name:新潟大学

  • 環境化学要論I

    2007
    Institution name:新潟大学

  • 環境分析化学

    2007
    -
    2021
    Institution name:新潟大学

  • 自然環境科学実験C

    2007
    -
    2016
    Institution name:新潟大学

  • 自然環境科学概論C

    2007
    -
    2016
    Institution name:新潟大学

  • 地球科学

    2007
    -
    2011
    Institution name:新潟大学

  • 化学実験

    2007
    -
    2010
    Institution name:新潟大学

  • 環境化学特論II

    2007
    Institution name:新潟大学

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